853 research outputs found

    An Uncommon Cause of Spontaneous Pneumomediastinum and Subcutaneous Emphysema

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    A 79-year-old gentleman presented with spontaneous pneumomediastinum and subcutaneous emphysema with pneumonia but no pre-existing lung disease. He presented with a 4-day history of increased shortness of breath, pleuritic chest pain, fevers, and non-productive cough. After 4 days of intravenous antibiotics, the patient developed considerable subcutaneous emphysema and pneumomediastinum. Pneumomediastinum presents most commonly with chest pain, shortness of breath, and subcutaneous emphysema. It has previously been associated with cases of pneumonia but often with rare strains such as P. jirovecii pneumonia in immunocompromised patients. This case highlights spontaneous pneumomediastinum as a rare complication of pneumonia. Treatment of pneumomediastinum is typically conservative, and although options may be limited, aggressive management of any causative factor may be essential in selected cases

    TGA studies of metoclopramide complexes of cobalt(II) in the solid state

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    A new series of cobalt(II) complexes with metoclopramide (MCP) ligand have been prepared. The prepared Co(II)-MCP complexes were characterized for various analytical techniques. Conductivity and elemental analysis of complexes have been measured. The thermal stability and degradation kinetics have been measured using thermogravimetric analyser. Kinetic parameter was obtained for each stage of thermal degradation for Co(II)-MCP complexes using Horowitz-Metzger, Coats-Redfern and Broido's methods. The activation energy (Ea) of the complexes for the thermal degradation process lie in the range 31-168, 23-161 and 33-170 kJ mol-1 for Horowitz-Metzger, Coats-Redfern and Broido's methods, respectively. © 2003 Elsevier B.V. All rights reserved

    Debye-Waller Factor and Debye Temperature for Three Metal-Organic Complexes

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    Spectrophotometric Determination of Ru(III) with Trifluoperazine Dihydrochloride

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