Recent Developments in Corrosion resistant non-ferrous metals and Alloys

THE importance of iron and its alloys as materials of construction has prompted the classification for metals and alloys as ferrous and non-ferrous : the latter includes all the metals(and their alloys)other than iron. However, iron is basically a rather reactive metal and, except in the passive state, is not suitable for corrosion resistant applications. The non-ferrous metals and alloys have established themselves for this purpose, both as protective coatings for iron or as primary materials of construction in corrosive envir-onments. However, these metals are widely divergent in their chemical and physical properties and a common discussion of their corrosion characteristics is rather dillicult

Recent Developments in Corrosion Resistant Non-ferrous Metals and Alloys

The imporatance of iron and its alloys has resulted in the classification of all the other metals and their alloys as non-ferrous. The later vary widely in their properties and the mechanism of corrosion resistance. Parameters important for the resistance are : physical, chemical, electrochemical, thermodynamic and metall-urgical. The corrosion reaction is primarily electro-chemical and the basic kinetic principles are now rela-tively well understood. The reaction rates, of course, are difficult to predict, being highly dependent upon the nature of the environment, surface, and metallurgical factors. Corrosion control, therefore, remains largely empirical. High strength and are also costly. Research and development on alloys, consequently, dominate the recent literature. The present paper reviews the significant developments from 1966

Corrosion of Aircraft Aluminium Alloys in Acid Solutions & its Prevention by Inhibitors

THE corrosion of metals is a serious problem confronting the industrially advanced countries of the world. Modern developments and war-time experiences have made it possible to manufacture metals at lower costs than before. Secondly, new sources of minerals have been discovered, thereby enabling each nation to increase its capacity for the production of metals. Iron and steel, aluminium, copper and zinc are amongst the metals in common use. In practice all of them are liable to corrode in various environments : atmosphere, soil and liquid medium. The loss of metal due to corrosion necessitating repair or removal of metal parts is one of fundamental importance affecting the economy of a country. The cost of corrosion control is rather high, the estimated figures per annum for some of the countries being U.S.A.' close to 10 billion dollars, U.K.2 600 million pounds, Canada3 500 million dollars, Australia4 100 million pounds. and India5 154 crore rupees. It becomes incre-asingly important to preserve available metals in use since a time may come when some of them approach exhaus-tion. From the available figures it has been indicated that immediate attention should be given to the non- ferrous metals, and greater attention to ferrous res-ources. In the case of iron the losses due to corrosion are estimated to be about 7.6 per cent a year. Corrosion control methods, therefore, assume great importance6

TECPR1 promotes aggrephagy by direct recruitment of LC3C autophagosomes to lysosomes

The accumulation of protein aggregates is involved in the onset of many neurodegenerative diseases. Aggrephagy is a selective type of autophagy that counteracts neurodegeneration by degrading such aggregates. In this study, we found that LC3C cooperates with lysosomal TECPR1 to promote the degradation of disease-related protein aggregates in neural stem cells. The N-terminal WD-repeat domain of TECPR1 selectively binds LC3C which decorates matured autophagosomes. The interaction of LC3C and TECPR1 promotes the recruitment of autophagosomes to lysosomes for degradation. Augmented expression of TECPR1 in neural stem cells reduces the number of protein aggregates by promoting their autophagic clearance, whereas knockdown of LC3C inhibits aggrephagy. The PH domain of TECPR1 selectively interacts with PtdIns(4)P to target TECPR1 to PtdIns(4)P containing lysosomes. Exchanging the PH against a tandem-FYVE domain targets TECPR1 ectopically to endosomes. This leads to an accumulation of LC3C autophagosomes at endosomes and prevents their delivery to lysosomes. Many neurodegenerative disorders are characterised by the accumulation of protein aggregates in neurons. Here, the authors show that the lysosomal protein TECPR1 selectively recruits mature autophagosomes via an interaction with LC3C to break down protein aggregates in neural stem cells

Dyonic dilaton black holes

The properties of static spherically symmetric black holes, which are both electrically and magnetically charged, and which are coupled to the dilaton in the presence of a cosmological constant, Lambda, are considered. It is shown that apart from the Reissner-Nordstrom-de Sitter solution with constant dilaton, such solutions do not exist if Lambda > 0 (in arbitrary spacetime dimension >=4 ). However, asymptotically anti-de Sitter dyonic black hole solutions with a non-trivial dilaton do exist if Lambda < 0. Both these solutions and the asymptotically flat (Lambda = 0) solutions are studied numerically for arbitrary values of the dilaton coupling parameter, g_0, in four dimensions. The asymptotically flat solutions are found to exhibit two horizons if g_0 = 0, 1, \sqrt{3}, \sqrt{6}, ..., \sqrt{n(n+1)/2},..., and one horizon otherwise. For asymptotically anti-de Sitter solutions the result is similar, but the corresponding values of g_0 are altered in a non-linear fashion which depends on Lambda and the mass and charges of the black holes. All dyonic solutions with Lambda <= 0 are found to have zero Hawking temperature in the extreme limit, however, regardless of the value of g_0.Comment: 24 pages, phyzzx, epsf, 7 in-text figures. Small addition to introduction, and a few extra reference

Evolution of Topological Defects During Inflation

Topological defects can be formed during inflation by phase transitions as well as by quantum nucleation. We study the effect of the expansion of the Universe on the internal structure of the defects. We look for stationary solutions to the field equations, i.e. solutions that depend only on the proper distance from the defect core. In the case of very thin defects, whose core dimensions are much smaller than the de Sitter horizon, we find that the solutions are well approximated by the flat space solutions. However, as the flat space thickness parameter $\delta_0$ increases we notice a deviation from this, an effect that becomes dramatic as $\delta_0$ approaches $(H)^{-1}/{\sqrt 2}$. Beyond this critical value we find no stationary solutions to the field equations. We conclude that only defects that have flat space thicknesses less than the critical value survive, while thicker defects are smeared out by the expansion.Comment: 14 page

Synthesis and photophysical properties of side-chain chlorinated 5,9-diaminobenzo[a]phenoxazinium salts

Fundação para a Ciência e Tecnologia (Portugal). National Program for Scientific Re-equipment, contract REDE/1517/RMN/2005 with funds from POCI 2010 (FEDER) and FCT

Geometric Entropy of Nonrelativistic Fermions and Two Dimensional Strings

We consider the geometric entropy of free nonrelativistic fermions in two dimensions and show that it is ultraviolet finite for finite fermi energies, but divergent in the infrared. In terms of the corresponding collective field theory this is a {\em nonperturbative} effect and is related to the soft behaviour of the usual thermodynamic entropy at high temperatures. We then show that thermodynamic entropy of the singlet sector of the one dimensional matrix model at high temperatures is governed by nonperturbative effects of the underlying string theory. In the high temperature limit the ``exact'' expression for the entropy is regular but leads to a negative specific heat, thus implying an instability. We speculate that in a properly defined two dimensional string theory, the thermodynamic entropy could approach a constant at high temperatures and lead to a geometric entropy which is finite in the ultraviolet.Comment: LaTex, 19 pages, no figures. Some references adde

Augmented Reality for Enhanced Visualization of MOF Adsorbents

Augmented reality (AR) is an emerging technique used to improve visualization and comprehension of complex 3D materials. This approach has been applied not only in the field of chemistry but also in real estate, physics, mechanical engineering, and many other areas. Here, we demonstrate the workflow for an app-free AR technique for visualization of metal–organic frameworks (MOFs) and other porous materials to investigate their crystal structures, topology, and gas adsorption sites. We think this workflow will serve as an additional tool for computational and experimental scientists working in the field for both research and educational purposes

The influence of microbial physiology on biocatalyst activity and efficiency in the terminal hydroxylation of n-octane using Escherichia coli expressing the alkane hydroxylase, CYP153A6

Biocatalyst improvement through molecular and recombinant means should be complemented with efficient process design to facilitate process feasibility and improve process economics. This study focused on understanding the bioprocess limitations to identify factors that impact the expression of the terminal hydroxylase CYP153A6 and also influence the biocatalytic transformation of n–octane to 1-octanol using resting whole cells of recombinant E. coli expressing the CYP153A6 operon which includes the ferredoxin (Fdx) and the ferredoxin reductase (FdR). Results: Specific hydroxylation activity decreased with increasing protein expression showing that the concentration of active biocatalyst is not the sole determinant of optimum process efficiency. Process physiological conditions including the medium composition, temperature, glucose metabolism and product toxicity were investigated. A fed-batch system with intermittent glucose feeding was necessary to ease overflow metabolism and improve process efficiency while the introduction of a product sink (BEHP) was required to alleviate octanol toxicity. Resting cells cultivated on complex LB and glucose-based defined medium with similar CYP level (0.20 μmol gDCW -1) showed different biocatalyst activity and efficiency in the hydroxylation of octane over a period of 120 h. This was influenced by differing glucose uptake rate which is directly coupled to cofactor regeneration and cell energy in whole cell biocatalysis. The maximum activity and biocatalyst efficiency achieved presents a significant improvement in the use of CYP153A6 for alkane activation. This biocatalyst system shows potential to improve productivity if substrate transfer limitation across the cell membrane and enzyme stability can be addressed especially at higher temperature. Conclusion: This study emphasises that the overall process efficiency is primarily dependent on the interaction between the whole cell biocatalyst and bioprocess conditions