30 research outputs found
Effect of Aggregate Flakiness on the Compressive Strength of Concrete Cubes
In this paper effects of aggregate flakiness on the compressive strength of concrete cubes have been studied using experiments. Total 30 cubes have been cast using normal, 5% of 8 mm, 10 mm and 12 mm size of flaky aggregates and 10% of 12mm size of flaky aggregate. NDT of the cast cubes using rebound hammer and ultrasonic pulse velocity have been also carried out. Aall the cubes were tested for compressive strength. Based on these data, comparative studies have been carried out to quantify the effect of flakiness and salient conclusions are drawn.
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Residue from vacuum ultraviolet irradiation of benzene ices: Insights into the physical structure of astrophysical dust
We have irradiated benzene ices deposited at 4 K on a cold, interstellar dust analog with vacuum ultraviolet (9 eV) irradiation for periods lasting from several hours to nearly a day, after which the irradiated ice was warmed to room temperature. Vacuum ultraviolet photoabsorption spectra of the aromatic residue left at room temperature were recorded and showed the synthesis of benzene derivatives. The residue was also imaged using an electron microscope and revealed crystals of various sizes and shapes. The result of our experiments suggests such geometrically shaped dust particles may be a key component of interstellar dust
Infrared attenuation due to phase change from amorphous to crystalline observed in astrochemical propargyl ether ices
Astrochemical ices are known to undergo morphological changes, from amorphous to crystalline, upon warming the ice from lower (10 K) to higher temperatures. Phase changes are mostly identified by the observation of significant changes in the InfraRed (IR) spectrum, where the IR bands that are broad in the amorphous phase are narrower and split when the ice turns crystalline. To-date all the molecules that are studied under astrochemical conditions are observed to follow such a behaviour without significant attenuation in the IR wavelength. However, in this paper we report a new observation when propargyl ether () is warmed from the amorphous phase, at 10 K, through the phase transition temperature of 170 K, the crystalline ice being found to strongly attenuate IR photons at the mid-IR wavelengths
Ozone Production in Electron Irradiated CO2:O2 Ices
The detection of ozone (O3) in the surface ices of Ganymede, Jupiter's largest moon, and of the Saturnian moons Rhea and Dione, has motivated several studies on the route of formation of this species. Previous studies have successfully quantified trends in the production of O3 as a result of the irradiation of pure molecular ices using ultraviolet photons and charged particles (i.e., ions and electrons), such as the abundances of O3 formed after irradiation at different temperatures or using different charged particles. In this study, we extend such results by quantifying the abundance of O3 as a result of the 1 keV electron irradiation of a series of 14 stoichiometrically distinct CO2:O2 astrophysical ice analogues at 20 K. By using mid-infrared spectroscopy as our primary analytical tool, we have also been able to perform a spectral analysis of the asymmetric stretching mode of solid O3 and the variation in its observed shape and profile among the investigated ice mixtures. Our results are important in the context of better understanding the surface composition and chemistry of icy outer Solar System objects, and may thus be of use to future interplanetary space missions such as the ESA Jupiter Icy Moons Explorer and the NASA Europa Clipper missions, as well as the recently launched NASA James Webb Space Telescope
Energetic Electron Irradiations of Amorphous and Crystalline Sulphur-Bearing Astrochemical Ices
Laboratory experiments have confirmed that the radiolytic decay rate of astrochemical ice analogues is dependent upon the solid phase of the target ice, with some crystalline molecular ices being more radio-resistant than their amorphous counterparts. The degree of radio-resistance exhibited by crystalline ice phases is dependent upon the nature, strength, and extent of the intermolecular interactions that characterise their solid structure. For example, it has been shown that crystalline CH3OH decays at a significantly slower rate when irradiated by 2 keV electrons at 20 K than does the amorphous phase due to the stabilising effect imparted by the presence of an extensive array of strong hydrogen bonds. These results have important consequences for the astrochemistry of interstellar ices and outer Solar System bodies, as they imply that the chemical products arising from the irradiation of amorphous ices (which may include prebiotic molecules relevant to biology) should be more abundant than those arising from similar irradiations of crystalline phases. In this present study, we have extended our work on this subject by performing comparative energetic electron irradiations of the amorphous and crystalline phases of the sulphur-bearing molecules H2S and SO2 at 20 K. We have found evidence for phase-dependent chemistry in both these species, with the radiation-induced exponential decay of amorphous H2S being more rapid than that of the crystalline phase, similar to the effect that has been previously observed for CH3OH. For SO2, two fluence regimes are apparent: a low-fluence regime in which the crystalline ice exhibits a rapid exponential decay while the amorphous ice possibly resists decay, and a high-fluence regime in which both phases undergo slow exponential-like decays. We have discussed our results in the contexts of interstellar and Solar System ice astrochemistry and the formation of sulphur allotropes and residues in these settings
Sulfur Ion Implantations Into Condensed CO2: Implications for Europa
The ubiquity of sulfur ions within the Jovian magnetosphere has led to suggestions that the implantation of these ions into the surface of Europa may lead to the formation of SO2. However, previous studies on the implantation of sulfur ions into H2O ice (the dominant species on the Europan surface) have failed to detect SO2 formation. Other studies concerned with similar implantations into CO2 ice, which is also known to exist on Europa, have offered seemingly conflicting results. In this letter, we describe the results of a study on the implantation of 290 keV S+ ions into condensed CO2 at 20 and 70 K. Our results demonstrate that SO2 is observed after implantation at 20 K, but not at the Europa-relevant temperature of 70 K. We conclude that this process is likely not a reasonable mechanism for SO2 formation on Europa, and that other mechanisms should be explored instead
Evaluation of Rice Varieties against Multiple Diseases Under Middle IGP of Bihar
An investigation was carried out to evaluate the susceptibility of rice cultivation to major field diseases like brown spot, sheath blight and bacterial leaf blight under middle Indo Gangetic Plain. The disease incidence and disease severity were observed at three different growth stages namely flowering, milk and maturity in boro seasons during 2015-16. The incidence of brown spot ranged from 8.93 to 17.83%, 16.67 to 25.67% and 18.33 to 28.33% at flowering, milk and maturity stages, respectively. The severity of brown spot in grade (0-9 scale) ranged from 5.13 to 10.33, 9.33 to 20.00 and 11.57 to 22.67, respectively at flowering, milk and maturity stages. The incidence of sheath blight of paddy ranged from 7. 03 to 16.50%, 13.13 to 22.67% and 19.67 to 35.67% at flowering, milk and maturity stages, respectively. The severity of sheath blight in grade (0-9 scale) ranged from 4.00 to 8.60, 8.33 to 13.93 and 18.33 to 34.33, respectively at flowering, milk and maturity stages. The incidence of bacterial leaf blight ranged from 5.00 to 14.00%, 11.43 to 21.00% and 17.00 to 34.00% at flowering, milk and maturity stages, respectively. The severity of bacterial leaf blight in grade (0-9 scale) ranged from 2.00 to 8.00%, 6.33 to 12.05% and 14.47 to 20.17%, respectively at flowering, milk and maturity stages. Among the varieties, the highest incidence and severity of Brown spot was recorded on Rajendra Bhagawati whereas it was lowest on 27P31 at all growth stages. In the case of Sheath blight, highest incidence and severity was recorded on Sambha Mahsuri whereas it was the lowest on CRL 193. Beside this in the case of Bacterial leaf blight, the highest incidence and severity was recorded on Kranti whereas the lowest was recorded on CRL 193. In general, it was observed that the incidence and severity of diseases increased gradually from flowering to maturity stage and the genotypes with the minimum incidence and severity of diseases gave the maximum yield
Mid-IR and VUV spectroscopic characterisation of thermally processed and electron irradiated CO2 astrophysical ice analogues
The astrochemistry of CO2 ice analogues has been a topic of intensive investigation due to the prevalence of CO2 throughout the interstellar medium and the Solar System, as well as the possibility of it acting as a carbon feedstock for the synthesis of larger, more complex organic molecules. In order to accurately discern the physico-chemical processes in which CO2 plays a role, it is necessary to have laboratory-generated spectra to compare against observational data acquired by ground- and space-based telescopes. A key factor which is known to influence the appearance of such spectra is temperature, especially when the spectra are acquired in the infrared and ultraviolet. In this present study, we describe the results of a systematic investigation looking into: (i) the influence of thermal annealing on the mid-IR and VUV absorption spectra of pure, unirradiated CO2 astrophysical ice analogues prepared at various temperatures, and (ii) the influence of temperature on the chemical products of electron irradiation of similar ices. Our results indicate that both mid-IR and VUV spectra of pure CO2 ices are sensitive to the structural and chemical changes induced by thermal annealing. Furthermore, using mid-IR spectroscopy, we have successfully identified the production of radiolytic daughter molecules as a result of 1 keV electron irradiation and the influence of temperature over this chemistry. Such results are directly applicable to studies on the chemistry of interstellar ices, comets, and icy lunar objects and may also be useful as reference data for forthcoming observational missions