High spatial and temporal resolution vehicular emissions in south-east Brazil with traffic data from real-time GPS and travel demand models

Vehicular emissions are one of the most important source of pollution in urban centers, impacting air quality with a deleterious effect on human health and ecosystems. Air quality managers rely on emissions inventories to characterize pollution and sources. In this study we predicted vehicular emissions, using three sources of traffic data: 1) travel demand model outputs consisting of traffic simulations of light-duty vehicles, trucks, 2) and urban buses, and 3) a massive data set of real-time GPS coordinates of light-duty vehicles and trucks. The study area comprises the metropolitan areas of São Paulo, Santos, Vale de Paraíba, Sorocaba, and Campinas, which have a population of more than 30 million inhabitant. Once we generated hourly traffic flows, we used the Vehicular Emissions INventory Model (VEIN) to predict fuel consumption and emissions. Emissions using travel demand model for the metropolitan area of São Paulo are CO 177406 t/y, NOX 73554 t/y, NMHC 33999 t/y and PM2:5 2281 t/y. The emissions using GPS data were higher than using travel demand outputs, because GPS average speeds were lower, producing higher emission factors

Vehicle emissions and PM2.5 mass concentrations in six Brazilian cities

In Brazil, the principal source of air pollution is the combustion of fuels (ethanol, gasohol, and diesel). In this study, we quantify the contributions that vehicle emissions make to the urban fine particulate matter (PM2.5) mass in six state capitals in Brazil, collecting data for use in a larger project evaluating the impact of air pollution on human health. From winter 2007 to winter 2008, we collected 24-h PM2.5 samples, employing gravimetry to determine PM2.5 mass concentrations; reflectance to quantify black carbon concentrations; X-ray fluorescence to characterize elemental composition; and ion chromatography to determine the composition and concentrations of anions and cations. Mean PM2.5 concentrations in the cities of São Paulo, Rio de Janeiro, Belo Horizonte, Curitiba, Porto Alegre, and Recife were 28, 17.2, 14.7, 14.4, 13.4, and 7.3 μg/m3, respectively. In São Paulo and Rio de Janeiro, black carbon explained approximately 30% of the PM2.5 mass. We used receptor models to identify distinct source-related PM2.5 fractions and correlate those fractions with daily mortality rates. Using specific rotation factor analysis, we identified the following principal contributing factors: soil and crustal material; vehicle emissions and biomass burning (black carbon factor); and fuel oil combustion in industries (sulfur factor). In all six cities, vehicle emissions explained at least 40% of the PM2.5 mass. Elemental composition determination with receptor modeling proved an adequate strategy to identify air pollution sources and to evaluate their short- and long-term effects on human health. Our data could inform decisions regarding environmental policies vis-à-vis health care costs

Impact of vehicular emissions on the formation of fine particles in the Sao Paulo Metropolitan Area: a numerical study with the WRF-Chem model

The objective of this work is to evaluate the impact of vehicular emissions on the formation of fine particles (PM2.5;  ≤  2.5 µm in diameter) in the Sao Paulo Metropolitan Area (SPMA) in Brazil, where ethanol is used intensively as a fuel in road vehicles. The Weather Research and Forecasting with Chemistry (WRF-Chem) model, which simulates feedbacks between meteorological variables and chemical species, is used as a photochemical modelling tool to describe the physico-chemical processes leading to the evolution of number and mass size distribution of particles through gas-to-particle conversion. A vehicular emission model based on statistical information of vehicular activity is applied to simulate vehicular emissions over the studied area. The simulation has been performed for a 1-month period (7 August–6 September 2012) to cover the availability of experimental data from the NUANCE-SPS (Narrowing the Uncertainties on Aerosol and Climate Changes in Sao Paulo State) project that aims to characterize emissions of atmospheric aerosols in the SPMA. The availability of experimental measurements of atmospheric aerosols and the application of the WRF-Chem model made it possible to represent some of the most important properties of fine particles in the SPMA such as the mass size distribution and chemical composition, besides allowing us to evaluate its formation potential through the gas-to-particle conversion processes. Results show that the emission of primary gases, mostly from vehicles, led to a production of secondary particles between 20 and 30 % in relation to the total mass concentration of PM2.5 in the downtown SPMA. Each of PM2.5 and primary natural aerosol (dust and sea salt) contributed with 40–50 % of the total PM10 (i.e. those  ≤  10 µm in diameter) concentration. Over 40 % of the formation of fine particles, by mass, was due to the emission of hydrocarbons, mainly aromatics. Furthermore, an increase in the number of small particles impaired the ultraviolet radiation and induced a decrease in ozone formation. The ground-level O3 concentration decreased by about 2 % when the aerosol-radiation feedback is taken into account

Impact of vehicular emissions on the formation of fine particles in the Sao Paulo Metropolitan Area: a numerical study with the WRF-Chem model

The objective of this work is to evaluate the impact of vehicular emissions on the formation of fine particles (PM2.5;  ≤  2.5 µm in diameter) in the Sao Paulo Metropolitan Area (SPMA) in Brazil, where ethanol is used intensively as a fuel in road vehicles. The Weather Research and Forecasting with Chemistry (WRF-Chem) model, which simulates feedbacks between meteorological variables and chemical species, is used as a photochemical modelling tool to describe the physico-chemical processes leading to the evolution of number and mass size distribution of particles through gas-to-particle conversion. A vehicular emission model based on statistical information of vehicular activity is applied to simulate vehicular emissions over the studied area. The simulation has been performed for a 1-month period (7 August–6 September 2012) to cover the availability of experimental data from the NUANCE-SPS (Narrowing the Uncertainties on Aerosol and Climate Changes in Sao Paulo State) project that aims to characterize emissions of atmospheric aerosols in the SPMA. The availability of experimental measurements of atmospheric aerosols and the application of the WRF-Chem model made it possible to represent some of the most important properties of fine particles in the SPMA such as the mass size distribution and chemical composition, besides allowing us to evaluate its formation potential through the gas-to-particle conversion processes. Results show that the emission of primary gases, mostly from vehicles, led to a production of secondary particles between 20 and 30 % in relation to the total mass concentration of PM2.5 in the downtown SPMA. Each of PM2.5 and primary natural aerosol (dust and sea salt) contributed with 40–50 % of the total PM10 (i.e. those  ≤  10 µm in diameter) concentration. Over 40 % of the formation of fine particles, by mass, was due to the emission of hydrocarbons, mainly aromatics. Furthermore, an increase in the number of small particles impaired the ultraviolet radiation and induced a decrease in ozone formation. The ground-level O3 concentration decreased by about 2 % when the aerosol-radiation feedback is taken into account

AMBIENTAL VOLATILE ORGANIC COMPOUNDS IN THE MEGACITY OF SAO PAULO

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)In order to characterize the composition of the main urban air organic compounds in the megacity of Sao Paulo, analysis of samples collected during the winter of 2003 downtown was carried out. The samplings were performed on the roof of a building in the commercial center of Sao Paulo. Hydrocarbons and carbonyls compounds were collected on August 4, 5 and 6. Comparing to previous data, the concentration of hydrocarbons presented no decrease in the concentration, except for the aldehydes, which decreased when compared to previous data. Among the HCs species analyzed, the highest concentrations observed were those of toluene (7.5 +/- 3.4 ppbv), n-decane (3.2 +/- 2.0 ppbv), benzene (2.7 +/- 1.4 ppbv) and 1,3,5-trimethylbenzene (2.2 +/- 1.5 ppbv).31820092013Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)FAPESP [02/09060-1

New directions: From biofuels to wood stoves: The modern and ancient air quality challenges in the megacity of São Paulo

A megacity typically refers to a metropolitan area with more than 10 million people. The number of megacities worldwide has increased from 8 in 1970 to 34 in 2016 with their total population exceeding 650 million (City Population, 2016). Air pollution, a consequence of increased population and urbanisation, is a common concern in megacities. Here we focus on the Metropolitan Area of São Paulo (MASP), which is the 5th most populous urban region in the world and the second most populated region in Latin America (UN, 2014), making up ~10% of the total population of Brazil. With 21 million inhabitants and 8511 km2 area (Fig. 1a), the MASP includes 38 metropolitan areas surrounding the city of São Paulo that has a population of 12 million (IBGE, 2016). What makes São Paulo distinctly different from all other megacities in the world is that its vehicle fleet operates exclusively on biofuel blends (sugarcane ethanol and soya diesel) in diesel, making it a unique biofuel-driven megacity. Yet, São Paulo’s air quality face challenges to meet its national standards, which are relatively relaxed compared with the megacities of Asia (e.g., Delhi) or Europe (e.g., London). While the events of highly elevated concentrations of particulate matter (PM) are similarly common as in other megacities, the underlining factors responsible for them are unique to São Paulo and the questions are: - (i) how can the air quality be improved considering that numerous interventions have already been taken in controlling emissions from vehicular fleet? - (ii) how can the transportation system be transformed to make it emission-neutral? - (iii) how the emissions from the main emitters such as the diesel trucks and buses can be reduced? and; - (iv) how the changes in the content of biofuel in diesel have influenced the exceedances and ozone formation? The aim of this paper is to propose answers to the above questions in the context of distinctness in the vehicle fleet, hitherto overlooked sources, underlining causes for pollution exceedances, and to suggest future directions and research needs to better understand and manage air quality of this unique megacity

Air quality in the megacity of São Paulo: evolution over the last 30 years and future perspectives

We present a comprehensive review of published results from the last 30 years regarding the sources and atmospheric characteristics of particles and ozone in the Metropolitan Area of São Paulo (MASP). During the last 30 years, many efforts have been made to describe the emissions sources and to analyse the primary and secondary formation of pollutants under a process of increasing urbanisation in the metropolitan area. From the occurrence of frequent violations of air quality standards in the 1970s and 1980s (due to the uncontrolled air pollution sources) to a substantial decrease in the concentrations of the primary pollutants, many regulations have been imposed and enforced, although those concentrations do not yet conform to the World Health Organization guidelines. The greatest challenge currently faced by the São Paulo State Environmental Protection Agency and the local community is controlling secondary pollutants such as ozone and fine particles. Understanding the formation of these secondary pollutants, by experimental or modelling approaches, requires the description of the atmospheric chemical processes driven by biofuel, ethanol and biodiesel emissions. Exposure to air pollution is the cause of many injuries to human health, according to many studies performed not only in the region but also worldwide, and affects susceptible populations such as children and the elderly. The MASP is the biggest megacity in the Southern Hemisphere, and its specifics are important for other urban areas that are facing the challenge of intensive growth that puts pressure on natural resources and worsens the living conditions in urban areas. This text discusses how imposing regulations on air quality and emission sources, mainly related to the transportation sector, has affected the evolution of pollutant concentrations in the MASP

Air quality in the megacity of São Paulo: evolution over the last 30 years and future perspectives

We present a comprehensive review of published results from the last 30 years regarding the sources and atmospheric characteristics of particles and ozone in the Metropolitan Area of São Paulo (MASP). During the last 30 years, many efforts have been made to describe the emissions sources and to analyse the primary and secondary formation of pollutants under a process of increasing urbanisation in the metropolitan area. From the occurrence of frequent violations of air quality standards in the 1970s and 1980s (due to the uncontrolled air pollution sources) to a substantial decrease in the concentrations of the primary pollutants, many regulations have been imposed and enforced, although those concentrations do not yet conform to the World Health Organization guidelines. The greatest challenge currently faced by the São Paulo State Environmental Protection Agency and the local community is controlling secondary pollutants such as ozone and fine particles. Understanding the formation of these secondary pollutants, by experimental or modelling approaches, requires the description of the atmospheric chemical processes driven by biofuel, ethanol and biodiesel emissions. Exposure to air pollution is the cause of many injuries to human health, according to many studies performed not only in the region but also worldwide, and affects susceptible populations such as children and the elderly. The MASP is the biggest megacity in the Southern Hemisphere, and its specifics are important for other urban areas that are facing the challenge of intensive growth that puts pressure on natural resources and worsens the living conditions in urban areas. This text discusses how imposing regulations on air quality and emission sources, mainly related to the transportation sector, has affected the evolution of pollutant concentrations in the MASP