76,082 research outputs found

    Scanning tunneling microscopy of adsorbed molecules on metalic surfaces for nearly localized atomic states

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    We consider a Hubbard-Anderson model which describes localized orbitals in five different sites hybridized both among themselves and with a continuum of extended states. A square planar geometry with an atom at the center is used to represent TBrPP-Co molecules. When the renormalized effective hopping between sites is small compared with a Kondo energy scale determined by the sitecontinuum hybridization, the system can be described as a set of independent Kondo resonances, rather than molecular states. We study the crossover between both regimes and analyze the spectral density of conduction electrons as a function of position. The results are in qualitative agreement with measurements of the differential conductance in a system with TBrPP-Co molecules adsorbed on a Cu(111) surface.Comment: 5 pages, 4 figure

    La desregulación de la comercialización de electricidad en Inglaterra y Gales

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    A partir de 1995, las autoridades regulatorias de Reino Unido han comenzado un proceso de introducción de competencia para ventas minoristas de electricidad. Esta política demandó un gran esfuerzo de organización por parte de los agentes de sistema, cuyos costos de lanzamiento se estiman en alrededor de 500 millones de libras. El presente reporte, en primer lugar, describe el programa de apertura llevado a cabo y evalúa los efectos de la apertura sobre el funcionamiento del sector y los niveles de bienestar de distintos estratos sociales de la población. Finalmente, del estudio de la experiencia británica se pueden extraer lecciones para la implementación futura de similares medidas en otros países.desregulación; comercialización de electricidad;

    Quantum interference through gated single-molecule junctions

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    We discuss the general form of the transmission spectrum through a molec- ular junction in terms of the Green function of the isolated molecule. By introducing a tight binding method, we are able to translate the Green func- tion properties into practical graphical rules for assessing beforehand the possible existence of antiresonances in an energy range for a given choice of connecting sites. The analysis is exemplified with a benzene molecule under a hypothetical local gate, which allows one to continuously tune the on-site energy of single atoms, for various connection topologies and gate positions.Comment: 17 pages, 5 figure

    Tricritical wedge filling transitions with short-ranged forces

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    We show that the 3D wedge filling transition in the presence of short-ranged interactions can be first-order or second order depending on the strength of the line tension associated with to the wedge bottom. This fact implies the existence of a tricritical point characterized by a short-distance expansion which differs from the usual continuous filling transition. Our analysis is based on an effective one-dimensional model for the 3D wedge filling which arises from the identification of the breather modes as the only relevant interfacial fluctuations. From such analysis we find a correspondence between continuous 3D filling at bulk coexistence and 2D wetting transitions with random-bond disorder.Comment: 7 pages, 3 figures, 6th Liquid Matter Conference Proceedings (to be published in J. Phys.: Condens. Matter
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