Petrogenesis of rare-metal pegmatites in high-grade metamorphic terranes: a case study from the Lewisian Gneiss Complex of north-west Scotland

Many rare metals used today are derived from granitic pegmatites, but debate continues about the origin of these rocks. It is clear that some pegmatites represent the most highly fractionated products of a parental granite body, whilst others have formed by anatexis of local crust. However, the importance of these two processes in the formation of rare-metal pegmatites is not always evident. The Lewisian Gneiss Complex of NW Scotland comprises Archaean meta-igneous gneisses which were highly reworked during accretional and collisional events in the Palaeoproterozoic (Laxfordian orogeny). Crustal thickening and subsequent decompression led to melting and the formation of abundant granitic and pegmatitic sheets in many parts of the Lewisian Gneiss Complex. This paper presents new petrological, geochemical and age data for those pegmatites and shows that, whilst the majority are barren biotite-magnetite granitic pegmatites, a few muscovite-garnet (rare-metal) pegmatites are present. These are mainly intruded into a belt of Palaeoproterozoic metasedimentary and meta-igneous rocks known as the Harris Granulite Belt. The rare-metal pegmatites are distinct in their mineralogy, containing garnet and muscovite, with local tourmaline and a range of accessory minerals including columbite and tantalite. In contrast, the biotite-magnetite pegmatites have biotite and magnetite as their main mafic components. The rare-metal pegmatites are also distinguished by their bulk-rock and mineral chemistry, including a more peraluminous character and enrichments in Rb, Li, Cs, Be, Nb and Ta. New U-Pb ages (c. 1690–1710 Ma) suggest that these rare-metal pegmatites are within the age range of nearby biotite-magnetite pegmatites, indicating that similar genetic processes could have been responsible for their formation. The peraluminous nature of the rare-metal pegmatites strongly points towards a metasedimentary source. Notably, within the Lewisian Gneiss Complex, such pegmatites are only found in areas where a metasedimentary source is available. The evidence thus points towards all the Laxfordian pegmatites being formed by a process of crustal anatexis, with the formation of rare-metal pegmatites being largely controlled by source composition rather than solely by genetic process. This is in keeping with previous studies that have also challenged the widely accepted model that all rare-metal pegmatites are formed by fractionation from a parental granite, and raises questions about the origin of other mineralised pegmatites worldwide

Rapid thermal rejuvenation of high-crystallinity magma linked to porphyry copper deposit formation; evidence from the Koloula Porphyry Prospect, Solomon Islands

Magmas containing the components needed to form porphyry copper deposits are relatively common within arcs, yet mineralising events are uncommon within the long-lived magmatic systems that host them. Understanding what causes the transition from barren to productive intrusions is critical to the development of conceptual deposit models. We have constrained the tempo of pre- and syn-mineralisation magmatic events in relationship to the thermal evolution of the plutonic body that underlies one of the world's youngest exposed plutonic–porphyry systems, the Inamumu Zoned Pluton, Koloula Porphyry Prospect, Solomon Islands. High precision ID-TIMS U–Pb dates of texturally and chemically characterised zircons indicate pluton emplacement over 50% crystals) state, past the point of rheological lock-up. We estimate that thermal rejuvenation of the deeper high-crystallinity magma and generation of a mobile melt fraction may have occurred ≤10 kyr before its transport and emplacement within the porphyry environment. The underlying pluton likely cooled and returned to high-crystallinity states prior to subsequent remobilisation-emplacement events. Titanium-in-zircon geothermometry and whole-rock geochemistry suggest pre-mineralisation intrusions were remobilised by mixing of a silicic magma with a high-temperature, less-evolved melt. In contrast, syn-mineralisation melts were most likely remobilised by the percolation of hot volatiles exsolved from contemporaneous less-evolved intrusions cooling beneath the crystalline silicic magma. The evidence for the rapid thermal rejuvenation and long term storage of highly crystalline silicic magmas is consistent with previous studies that indicate two components of exsolved volatiles contribute to ore forming fluids. We conclude that the liberation of crystal-rich porphyry copper deposit forming magmas, and the addition of the chemical components required for ore formation, are intrinsically linked to the volatiles released during the recharge of less-evolved melt into a highly crystalline silicic magma

The π\pi, K+K^+, and K0K^0 electromagnetic form factors

The rainbow truncation of the quark Dyson-Schwinger equation is combined with the ladder Bethe-Salpeter equation for the meson amplitudes and the dressed quark-photon vertex in a self-consistent Poincar\'e-invariant study of the pion and kaon electromagnetic form factors in impulse approximation. We demonstrate explicitly that the current is conserved in this approach and that the obtained results are independent of the momentum partitioning in the Bethe-Salpeter amplitudes. With model gluon parameters previously fixed by the condensate, the pion mass and decay constant, and the kaon mass, the charge radii and spacelike form factors are found to be in good agreement with the experimental data.Comment: 8 pages, 6 figures, Revte

A gas-accepting ion source for Accelerator Mass Spectrometry : progress and applications

Author Posting. © The Author(s), 2011. This is the author's version of the work. It is posted here by permission of Elsevier B.V. for personal use, not for redistribution. The definitive version was published in Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms 294 (2013): 296-299, doi:10.1016/j.nimb.2011.10.016.The National Ocean Sciences Accelerator Mass Spectrometry (NOSAMS) facility at the Woods Hole Oceanographic Institution has developed an Accelerator Mass Spectrometry (AMS) system designed specifically for the analysis of 14C in a continuously flowing stream of carrier gas. A key part of the system is a gas-accepting microwave ion source. Recently, substantial progress has been made in the development of this source, having achieved ion currents rivaling that of a traditional graphite source (albeit at relatively low efficiency). Details and present performance of the gas source are given. Additionally, representative results obtained from coupling the source to both a gas chromatograph and gas bench are presented.This work is supported by a Cooperative Agreement (OCE- 2310753487) with the US National Science Foundation

Valence-quark distributions in the pion

We calculate the pion's valence-quark momentum-fraction probability distribution using a Dyson-Schwinger equation model. Valence-quarks with an active mass of 0.30 GeV carry 71% of the pion's momentum at a resolving scale q_0=0.54 GeV = 1/(0.37 fm). The shape of the calculated distribution is characteristic of a strongly bound system and, evolved from q_0 to q=2 GeV, it yields first, second and third moments in agreement with lattice and phenomenological estimates, and valence-quarks carrying 49% of the pion's momentum. However, pointwise there is a discrepancy between our calculated distribution and that hitherto inferred from parametrisations of extant pion-nucleon Drell-Yan data.Comment: 8 pages, 3 figures, REVTEX, aps.sty, epsfig.sty, minor corrections, version to appear in PR

Electromagnetic form factors of light vector mesons

The electromagnetic form factors G_E(q^2), G_M(q^2), and G_Q(q^2), charge radii, magnetic and quadrupole moments, and decay widths of the light vector mesons rho^+, K^{*+} and K^{*0} are calculated in a Lorentz-covariant, Dyson-Schwinger equation based model using algebraic quark propagators that incorporate confinement, asymptotic freedom, and dynamical chiral symmetry breaking, and vector meson Bethe-Salpeter amplitudes closely related to the pseudoscalar amplitudes obtained from phenomenological studies of pi and K mesons. Calculated static properties of vector mesons include the charge radii and magnetic moments: r_{rho+} = 0.61 fm, r_{K*+} = 0.54 fm, and r^2_{K*0} = -0.048 fm^2; mu_{rho+} = 2.69, mu_{K*+} = 2.37, and mu_{K*0} = -0.40. The calculated static limits of the rho-meson form factors are similar to those obtained from light-front quantum mechanical calculations, but begin to differ above q^2 = 1 GeV^2 due to the dynamical evolution of the quark propagators in our approach.Comment: 8 pages of RevTeX, 5 eps figure

Scents and sensibility: Best practice in insect olfactometer bioassays

Olfactometers have been used for more than 100 years and are integral to experimental chemical ecology. Studies utilising olfactometer bioassays form the foundation for understanding the behavioural responses of invertebrates to chemical stimuli under standardised laboratory conditions. Widely used olfactometry apparatuses include two-arm olfactometers for binary responses through to four- and six-arm arenas to evaluate more complex behaviours. Despite its prevalence in chemical ecology studies, there has never been a review of experimental best practice in olfactometry. This review critically evaluates both olfactometry methods and applications as well as experimental design and analysis. We aim to outline a standard of good practice to improve experimental design and reporting for studies involving olfactometry, thereby establishing a reference guide to build a robust experimental workflow for olfactometry bioassays

Analysis of a quenched lattice-QCD dressed-quark propagator

Quenched lattice-QCD data on the dressed-quark Schwinger function can be correlated with dressed-gluon data via a rainbow gap equation so long as that equation's kernel possesses enhancement at infrared momenta above that exhibited by the gluon alone. The required enhancement can be ascribed to a dressing of the quark-gluon vertex. The solutions of the rainbow gap equation exhibit dynamical chiral symmetry breaking and are consistent with confinement. The gap equation and related, symmetry-preserving ladder Bethe-Salpeter equation yield estimates for chiral and physical pion observables that suggest these quantities are materially underestimated in the quenched theory: |<bar-q q>| by a factor of two and f_pi by 30%.Comment: 9 pages, LaTeX2e, REVTEX4, 6 figure

The Quark-Photon Vertex and the Pion Charge Radius

The rainbow truncation of the quark Dyson-Schwinger equation is combined with the ladder Bethe-Salpeter equation for the dressed quark-photon vertex to study the low-momentum behavior of the pion electromagnetic form factor. With model gluon parameters previously fixed by the pion mass and decay constant, the pion charge radius $r_\pi$ is found to be in excellent agreement with the data. When the often-used Ball-Chiu Ansatz is used to construct the quark-photon vertex directly from the quark propagator, less than half of $r_\pi^2$ is generated. The remainder of $r^2_\pi$ is seen to be attributable to the presence of the $\rho$-pole in the solution of the ladder Bethe-Salpeter equation.Comment: 21 pages, 9 figure

Towards a Simple Model of Compressible Alfvenic Turbulence

A simple model collisionless, dissipative, compressible MHD (Alfvenic) turbulence in a magnetized system is investigated. In contrast to more familiar paradigms of turbulence, dissipation arises from Landau damping, enters via nonlinearity, and is distributed over all scales. The theory predicts that two different regimes or phases of turbulence are possible, depending on the ratio of steepening to damping coefficient (m_1/m_2). For strong damping (|m_1/m_2|<1), a regime of smooth, hydrodynamic turbulence is predicted. For |m_1/m_2|>1, steady state turbulence does not exist in the hydrodynamic limit. Rather, spikey, small scale structure is predicted.Comment: 6 pages, one figure, REVTeX; this version to be published in PRE. For related papers, see http://sdphpd.ucsd.edu/~medvedev/papers.htm