An MDP decomposition approach for traffic control at isolated signalized intersections

This article presents a novel approach for the dynamic control of a signalized intersection. At the intersection, there is a number of arrival flows of cars, each having a single queue (lane). The set of all flows is partitioned into disjoint combinations of nonconflicting flows that will receive green together. The dynamic control of the traffic lights is based on the numbers of cars waiting in the queues. The problem concerning when to switch (and which combination to serve next) is modeled as a Markovian decision process in discrete time. For large intersections (i.e., intersections with a large number of flows), the number of states becomes tremendously large, prohibiting straightforward optimization using value iteration or policy iteration. Starting from an optimal (or nearly optimal) fixed-cycle strategy, a one-step policy improvement is proposed that is easy to compute and is shown to give a close to optimal strategy for the dynamic proble

Theory of membrane capacitive deionization including the effect of the electrode pore space

Membrane capacitive deionization (MCDI) is a technology for water desalination based on applying an electrical field between two oppositely placed porous electrodes. Ions are removed from the water flowing through a channel in between the electrodes and are stored inside the electrodes. Ion-exchange membranes are placed in front of the electrodes allowing for counterion transfer from the channel into the electrode, while retaining the coions inside the electrode structure. We set up an extended theory for MCDI which includes in the description for the porous electrodes not only the electrostatic double layers (EDLs) formed inside the porous (carbon) particles, but also incorporates the role of the transport pathways in the electrode, i.e., the interparticle pore space. Because in MCDI the coions are inhibited from leaving the electrode region, the interparticle porosity becomes available as a reservoir to store salt, thereby increasing the total salt storage capacity of the porous electrode. A second advantage of MCDI is that during ion desorption (ion release) the voltage can be reversed. In that case the interparticle porosity can be depleted of counterions, thereby increasing the salt uptake capacity and rate in the next cycle. In this work, we compare both experimentally and theoretically adsorption/desorption cycles of MCDI for desorption at zero voltage as well as for reversed voltage, and compare with results for CDI. To describe the EDL-structure a novel modified Donnan model is proposed valid for small pores relative to the Debye length

Anarchism and non-domination

This is the final version. Available on open access from Taylor & Francis via the DOI in this record.In this article we recover the classical anarchist deployment of republican tropes of non-domination, tyranny and slavery, to expose the conservative limits of the contemporary neo-Roman republican revival. For the anarchists, the modern nation state and the institution of private property are antithetical to freedom as non-domination, acting as structural constraints to freedom rather than the means for its realisation. We re-examine the grounds of this critique to advance two arguments. First, that a commitment to either the state or private property represents an unwarranted positive moral and ethical commitment that skews the negative theory of freedom contemporary republicans seek to develop. Second, the prior moral commitment to the state renders neo-Roman republicanism fundamentally conservative. Anarchist theories of freedom as non-domination push much further than the contemporary republican revival seems to permit, opening new possibilities for institutional and constitutional innovation while remaining consistent with the core republican normative value of non-domination

All-optical coherent population trapping with defect spin ensembles in silicon carbide

Divacancy defects in silicon carbide have long-lived electronic spin states and sharp optical transitions, with properties that are similar to the nitrogen-vacancy defect in diamond. We report experiments on 4H-SiC that investigate all-optical addressing of spin states with the zero-phonon-line transitions. Our magneto-spectroscopy results identify the spin $S=1$ structure of the ground and excited state, and a role for decay via intersystem crossing. We use these results for demonstrating coherent population trapping of spin states with divacancy ensembles that have particular orientations in the SiC crystal.Comment: 28 page document: Pages 1-14 main text (with 3 figures); pages 15-28 supplementary information (with 5 figues). v2 has minor correction

Supply of Online Environmental Information to Unknown Demand : The Importance of Interpretation and Liability Related to a National Network of River Level Data

The research described here is supported by the award made by the RCUK Digital Economy programme to the dot.rural Digital Economy Hub; award reference: EP/G066051/1. It has been ethically considered within the University of Aberdeen's Framework for Research Ethics and Governance.Peer reviewedPublisher PD