Exact zero-point energy shift in the e⊗(n E)e\otimes (n~E), t⊗(n H)t\otimes (n~H) many modes dynamic Jahn-Teller systems at strong coupling

We find the exact semiclassical (strong coupling) zero-point energy shifts applicable to the $e\otimes (n E)$ and $t\otimes (n H)$ dynamic Jahn-Teller problems, for an arbitrary number $n$ of discrete vibrational modes simultaneously coupled to one single electronic level. We also obtain an analytical formula for the frequency of the resulting normal modes, which has an attractive and apparently general Slater-Koster form. The limits of validity of this approach are assessed by comparison with O'Brien's previous effective-mode approach, and with accurate numerical diagonalizations. Numerical values obtained for $t\otimes (n H)$ with $n =8$ and coupling constants appropriate to C$_{60}^-$ are used for this purpose, and are discussed in the context of fullerene.Comment: 20 pages, 4 ps figure

Carbon dioxide (CO2 ) geological storage potential of the Bass Basin

AbstractEvaluation of the Bass Basin’s suitability for CO2 storage has been undertaken by analysing several key basin analysis elements, including seal capacity and integrity, reservoir quality, petroleum systems modelling and CO2 migration and storage modelling.Seal geometry, capacity and integrity of the Demons Bluff Formation has been investigated to evaluate CO2 containment in the basin. The study revealed good to excellent sealing capacity for the Demons Bluff Formation and for the intraformational seals within the Eastern View Group (EVG). Faults traversing the reservoir/regional seal boundary, as well as faults intersecting the top of the regional seal were evaluated for future risk of reactivation. There is some risk of reactivation associated with N-E striking faults, fortunately these faults are mostly confined to the margins of the basin.Reservoirs of the Upper EVG generally have high porosity and permeability. Hydrocarbon migration and accumulation in the basin were simulated, to examine the petroleum potential of specific reservoirs within the basin. Migration models suggest most of the trapped hydrocarbons occur in the reservoir sands of the Middle EVG. Reservoirs of the Upper EVG were have received little hydrocarbon charge, except for the northeastern part of the basin.CO2 migration paths within reservoirs of the Upper EVG were simulated based on a buoyancy driven migration model. Migration pathways within the Upper EVG and CO2 accumulations under the regional seal were identified. In addition, total available pore volumes for CO2 storage associated with structural traps was calculated at >2 billionm3

Testing the standard fireball model of GRBs using late X-ray afterglows measured by Swift

We show that all X-ray decay curves of GRBs measured by Swift can be fitted using one or two components both of which have exactly the same functional form comprised of an early falling exponential phase followed by a power law decay. The 1st component contains the prompt gamma-ray emission and the initial X-ray decay. The 2nd component appears later, has a much longer duration and is present for ~80% of GRBs. It most likely arises from the external shock which eventually develops into the X-ray afterglow. In the remaining ~20% of GRBs the initial X-ray decay of the 1st component fades more slowly than the 2nd and dominates at late times to form an afterglow but it is not clear what the origin of this emission is. The temporal decay parameters and gamma/X-ray spectral indices derived for 107 GRBs are compared to the expectations of the standard fireball model including a search for possible "jet breaks". For ~50% of GRBs the observed afterglow is in accord with the model but for the rest the temporal and spectral indices do not conform to the expected closure relations and are suggestive of continued, late, energy injection. We identify a few possible jet breaks but there are many examples where such breaks are predicted but are absent. The time, T_a, at which the exponential phase of the 2nd component changes to a final powerlaw decay afterglow is correlated with the peak of the gamma-ray spectrum, E_peak. This is analogous to the Ghirlanda relation, indicating that this time is in some way related to optically observed break times measured for pre-Swift bursts.Comment: submitted to Ap

Demonstration of a simple entangling optical gate and its use in Bell-state analysis

We demonstrate a new architecture for an optical entangling gate that is significantly simpler than previous realisations, using partially-polarising beamsplitters so that only a single optical mode-matching condition is required. We demonstrate operation of a controlled-Z gate in both continuous-wave and pulsed regimes of operation, fully characterising it in each case using quantum process tomography. We also demonstrate a fully-resolving, nondeterministic optical Bell-state analyser based on this controlled-Z gate. This new architecture is ideally suited to guided optics implementations of optical gates.Comment: 4 pages, 3 figures. v2: additional author, improved data and figures (low res), some other minor changes. Accepted for publication in PR

The first Swift X-ray Flash: The faint afterglow of XRF 050215B

We present the discovery of XRF 050215B and its afterglow. The burst was detected by the Swift BAT during the check-out phase and observations with the X-ray telescope began approximately 30 minutes after the burst. These observations found a faint, slowly fading X-ray afterglow near the centre of the error box as reported by the BAT. Infrared data, obtained at UKIRT after 10 hours also revealed a very faint K-band afterglow. The afterglow appear unusual since it is very faint, especially in the infrared with K>20 only 9 hours post burst. The X-ray and infrared lightcurves exhibit a slow, monotonic decay with alpha=0.8 and no evidence for steepening associated with the jet break to 10 days post burst. We discuss possible explanations for the faintness and slow decay in the context of present models for the production of X-ray Flashes.Comment: 8 pages, 5 figures, accepted for publication in Ap

High-Resolution Keck Spectra of the Associated Absorption Lines in 3C 191

Associated absorption lines (AALs) are valuable probes of the gaseous environments near quasars. Here we discuss high-resolution (6.7 km/s) spectra of the AALs in the radio-loud quasar 3C 191 (redshift z=1.956). The measured AALs have ionizations ranging from Mg I to N V, and multi-component profiles that are blueshifted by ~400 to ~1400 km/s relative to the quasar's broad emission lines. These data yield the following new results. 1) The density based on Si II*/Si II lines is ~300 cm-3, implying a distance of ~28 kpc from the quasar if the gas is photoionized. 2) The characteristic flow time is thus \~3 x 10^7 yr. 3) Strong Mg I AALs identify neutral gas with very low ionization parameter and high density. We estimate n_H > 5 x 10^4 cm-3 in this region, compared to ~15 cm-3 where the N V lines form. 4) The total column density is N_H < 4 x 10^18 cm-2 in the neutral gas and N_H ~ 2 x 10^20 cm-2 in the moderately ionized regions. 5) The total mass in the AAL outflow is M ~ 2 x 10^9 Mo, assuming a global covering factor (as viewed from the quasar) of ~10% >. 6) The absorbing gas only partially covers the background light source(s) along our line(s) of sight, requiring absorption in small clouds or filaments <0.01 pc across. The ratio N_H/n_H implies that the clouds have radial (line- of-sight) thicknesses <0.2 pc. These properties might characterize a sub-class of AALs that are physically related to quasars but form at large distances. We propose a model for the absorber in which pockets of dense neutral gas are surrounded by larger clouds of generally lower density and higher ionization. This outflowing material might be leftover from a blowout associated with a nuclear starburst, the onset of quasar activity or a past broad absorption line (BAL) wind phase.Comment: 15 pages text plus 6 figures, in press with Ap

Swift observations of the 2006 outburst of the recurrent nova RS Ophiuchi: I. Early X-ray emission from the shocked ejecta and red giant wind

RS Ophiuchi began its latest outburst on 2006 February 12. Previous outbursts have indicated that high velocity ejecta interact with a pre-existing red giant wind, setting up shock systems analogous to those seen in Supernova Remnants. However, in the previous outburst in 1985, X-ray observations did not commence until 55 days after the initial explosion. Here we report on Swift observations covering the first month of the 2006 outburst with the Burst Alert (BAT) and X-ray Telescope (XRT) instruments. RS Oph was clearly detected in the BAT 14-25 keV band from t=0 to $t\sim6$ days. XRT observationsfrom 0.3-10 keV, started at 3.17 days after outburst. The rapidly evolving XRT spectra clearly show the presence of both line and continuum emission which can be fitted by thermal emission from hot gas whose characteristic temperature, overlying absorbing column, $[N_H]_W$, and resulting unabsorbed total flux decline monotonically after the first few days. Derived shock velocities are in good agreement with those found from observations at other wavelengths. Similarly, $[N_H]_W$ is in accord with that expected from the red giant wind ahead of the forward shock. We confirm the basic models of the 1985 outburst and conclude that standard Phase I remnant evolution terminated by $t\sim10$ days and the remnant then rapidly evolved to display behaviour characteristic of Phase III. Around t=26 days however, a new, luminous and highly variable soft X-ray source began to appear whose origin will be explored in a subsequent paper.Comment: 20 pages, 4 figures (2 updated), accepted by Ap

The SSS phase of RS Ophiuchi observed with Chandra and XMM-Newton I.: Data and preliminary Modeling

The phase of Super-Soft-Source (SSS) emission of the sixth recorded outburst of the recurrent nova RS Oph was observed twice with Chandra and once with XMM-Newton. The observations were taken on days 39.7, 54.0, and 66.9 after outburst. We confirm a 35-sec period on day 54.0 and found that it originates from the SSS emission and not from the shock. We discus the bound-free absorption by neutral elements in the line of sight, resonance absorption lines plus self-absorbed emission line components, collisionally excited emission lines from the shock, He-like intersystem lines, and spectral changes during an episode of high-amplitude variability. We find a decrease of the oxygen K-shell absorption edge that can be explained by photoionization of oxygen. The absorption component has average velocities of -1286+-267 km/s on day 39.7 and of -771+-65 km/s on day 66.9. The wavelengths of the emission line components are consistent with their rest wavelengths as confirmed by measurements of non-self absorbed He-like intersystem lines. We have evidence that these lines originate from the shock rather than the outer layers of the outflow and may be photoexcited in addition to collisional excitations. We found collisionally excited emission lines that are fading at wavelengths shorter than 15A that originate from the radiatively cooling shock. On day 39.5 we find a systematic blue shift of -526+-114 km/s from these lines. We found anomalous He-like f/i ratios which indicates either high densities or significant UV radiation near the plasma where the emission lines are formed. During the phase of strong variability the spectral hardness light curve overlies the total light curve when shifted by 1000sec. This can be explained by photoionization of neutral oxygen in the line of sight if the densities of order 10^{10}-10^{11} cm^{-3}.Comment: 16 pages, 10 figures, 4 tables. Accepted by ApJ; v2: Co-author Woodward adde

STM characterization of the Si-P heterodimer

We use scanning tunneling microscopy (STM) and Auger electron spectroscopy to study the behavior of adsorbed phosphine (PH$_{3}$) on Si(001), as a function of annealing temperature, paying particular attention to the formation of the Si-P heterodimer. Dosing the Si(001) surface with ${\sim}$0.002 Langmuirs of PH$_{3}$ results in the adsorption of PH$_{x}$ (x=2,3) onto the surface and some etching of Si to form individual Si ad-dimers. Annealing to 350$^{\circ}$C results in the incorporation of P into the surface layer to form Si-P heterodimers and the formation of short 1-dimensional Si dimer chains and monohydrides. In filled state STM images, isolated Si-P heterodimers appear as zig-zag features on the surface due to the static dimer buckling induced by the heterodimer. In the presence of a moderate coverage of monohydrides this static buckling is lifted, rending the Si-P heterodimers invisible in filled state images. However, we find that we can image the heterodimer at all H coverages using empty state imaging. The ability to identify single P atoms incorporated into Si(001) will be invaluable in the development of nanoscale electronic devices based on controlled atomic-scale doping of Si.Comment: 6 pages, 4 figures (only 72dpi