Tailoring optical nonlinearities via the Purcell effect

We predict that the effective nonlinear optical susceptibility can be tailored using the Purcell effect. While this is a general physical principle that applies to a wide variety of nonlinearities, we specifically investigate the Kerr nonlinearity. We show theoretically that using the Purcell effect for frequencies close to an atomic resonance can substantially influence the resultant Kerr nonlinearity for light of all (even highly detuned) frequencies. For example, in realistic physical systems, enhancement of the Kerr coefficient by one to two orders of magnitude could be achieved

Time-resolved kinetic assessment of the role of singlet and triplet excited states in the photocatalytic treatment of pollutants at different concentrations

[EN] A kinetic-based rationale to assess the role of each excited species in thermodynamically favoured photocatalytic processes at different pollutant concentrations, has been developed and illustrated with new experimental data. Specifically, 2,4,6-triphenylthiapyrylium (TPTP+) salt has been chosen as a representative organic compound capable to act as photocatalyst, and the possible involvement of its excited states in the photodegradation of pollutants commonly found in aqueous ecosystems has been investigated using five chemicals, namely acetaminophen, acetamiprid, caffeine, clofibric acid and carbamazepine. First, steady-state photolysis has been carried out under simulated solar irradiation in the presence of TPTP+, and second, photophysical measurements (fluorescence and laser flash photolysis) have been performed in order to obtain reliable fast kinetic data. Thermodynamic considerations allow ruling out energy transfer processes, while the kinetic results are in good agreement with an electron transfer to the triplet excited state of TPTP+. Hence, the higher the intersystem crossing quantum yield the better. Although quenching of the singlet excited state is also observed, the contribution of this reactive species is only minor, due to its shorter lifetime. In general, the efficiency of a photocatalyst should be enhanced at higher pollutant concentrations, at which the intrinsic decay of the triplet excited state is minimized. (C) 2016 Elsevier B.V. All rights reserved.Financial support from Spanish Government (Grants SEV-2012-0267, CTQ2012-38754-C03-03 and CTQ2015-69832-C4-4-R) and Generalitat Valenciana (Prometeo Program) is gratefully acknowledged. R. Martinez-Haya thanks financial support from Spanish Government (Grant SEV-2012-0267). We also thank support from VLC/Campus.Martínez-Haya, R.; Gomis, J.; Arques Sanz, A.; Marín García, ML.; Amat Payá, AM.; Miranda Alonso, MÁ. (2017). Time-resolved kinetic assessment of the role of singlet and triplet excited states in the photocatalytic treatment of pollutants at different concentrations. Applied Catalysis B Environmental. 203:381-388. https://doi.org/10.1016/j.apcatb.2016.10.042S38138820

Data and initial model set-up for the 2022 VPA stock assessment of the eastern Atlantic and Mediterranean bluefin tuna

This document presents the data and initial model set-up for the 2022 Stock Assessment for the Eastern Atlantic and Mediterranean bluefin tuna stock. During the 2017 Data Preparatory meetings, several changes in the data used for previous assessments have been presented, among which the revision of the Task 1 and Task 2 statistics and the selection of the indices of abundance. This led to completely revisiting the catch at age matrix and the model specifications for the 2017 assessment. For the present document, the data over the historical period (1968-2015) were nearly identical, whereas the data for the years 2016-2020 and abundance indices were updated. As agreed in previous meetings, the initial model specifications were kept identical to the 2017 assessment as no change has been agreed on since then

An X-rays-to-radio investigation of the nuclear polarization from the radio-galaxy Centaurus A

Centaurus A is one of the closest radio galaxies to Earth. Its proximity allowed us to extensively study its active galactic nucleus but the core emission mechanism remains elusive because of local strong dust and gas obscuration. The capability of polarimetry to shave-off contaminating emission has been exploited without success in the near-infrared by previous studies but the very recent measurement of the 2–8 keV polarization by the Imaging X-ray Polarimetry Explorer (IXPE) brought the question back to the fore. To determine what is the prevalent photon generation mechanism to the multiwavelength emission from the core of Centaurus A, we retrieved from the archives the panchromatic polarization measurements of the central compact component. We built the total and polarized flux spectral energy distributions of the core and demonstrated that synchrotron self-Compton models nicely fit the polarized flux from the radio to the X-ray band. The linear polarization of the synchrotron continuum is perpendicular to the jet radio axis from the optical to the radio band, and parallel to it at higher energies. The observed smooth rotation of the polarization angle in the ultraviolet band is attributed to synchrotron emission from regions that are getting closer to the particle acceleration site, where the orientation of the jet’s magnetic fields become perpendicular to the jet axis. This phenomenon support the shock acceleration mechanism for particle acceleration in Centaurus A, in line with IXPE observations of several high-synchrotron peak blazars

An X-rays-to-radio investigation of the nuclear polarization from the radio-galaxy Centaurus A

Centaurus A is one of the closest radio-galaxies to Earth. Its proximity allowed us to extensively study its active galactic nucleus but the core emission mechanism remains elusive because of local strong dust and gas obscuration. The capability of polarimetry to shave-off contaminating emission has been exploited without success in the near-infrared by previous studies but the very recent measurement of the 2 - 8 keV polarization by the Imaging X-ray Polarimetry Explorer (IXPE) brought the question back to the fore. To determine what is the prevalent photon generation mechanism to the multi-wavelength emission from the core of Centaurus A, we retrieved from the archives the panchromatic polarization measurements of the central compact component. We built the total and polarized flux spectral energy distributions of the core and demonstrated that synchrotron self-Compton models nicely fit the polarized flux from the radio to the X-ray band. The linear polarization of the synchrotron continuum is perpendicular to the jet radio axis from the optical to the radio band, and parallel to it at higher energies. The observed smooth rotation of the polarization angle in the ultraviolet band is attributed to synchrotron emission from regions that are getting closer to the particle acceleration site, where the orientation of the jet's magnetic fields become perpendicular to the jet axis. This phenomenon support the shock acceleration mechanism for particle acceleration in Centaurus A, in line with IXPE observations of several high-synchrotron peak blazars.Comment: 10 pages, 6 figures, accepted for publication in MNRA

Final data, explorations, model set-up and diagnostics for the 2022 VPA stock assessment of the eastern and Mediterranean Atlantic bluefin tuna stock

This document presents the modeling work done for the 2022 stock assessment for the Eastern and Mediterranean Bluefin tuna stock, during informal modeling subgroup meetings in June 2022. This document presents various runs built upon the base case for the 2017 stock assessment. These runs aim at addressing issues identified in the 2020 update assessment and aspects discussed during the informal meetings held in june 2022, regarding the inclusion of updated catch at age data, improvement of model stability in relation to Fratio estimates, the selection of the age for the plus group, inclusion of the WMED_GBYP_AER index. Following several explorations, the present work contains two runs that displayed improved diagnostics compared to previous runs. These models have improved retrospective patterns and no problematic issue was found through jittering the random number generator, jittering the starting values for the terminal F estimate, bootstrapping or through jackknife analysis

Poly(styrene-co-vinylbenzylchloride-co-divinylbenzene) coated iron oxide: Synthesis and effects on size and morphology

Iron oxide nanoparticles were coated with a polymer synthesized from the monomers of styrene, divinylbenzene, and vinylbenzylchloride. The resultant polymer microspheres from synthesis without nanoparticle loading are primarily monodispersed with a diameter of 3.45 μm as measured by scanning electron microscopy. The addition of 1% nanoparticles by mass appears to decrease the size of the microspheres down to 2.04 μm as well as increase the polydispersity. This trend is also seen to continue as you add more nanoparticles to the system going from 3.45 μm with 0% nanoparticles down to below 1 μm for 5% nanoparticles. This indicates that the particles are not just incorporated into the polymer matrix but act as nucleation sites to begin the polymerization process. The polymerization process was found to have no effect on the nanoparticles themselves as the magnetic characterization showed only a mass dilution in saturation when corrected by thermal gravimetric analysis

2022 Proposed base case model for eastern Atlantic and Mediterranean bluefin tuna assessment using stock synthesis.

This document presents the proposed base case for the assessment of Eastern Atlantic and Mediterranean population of bluefin tuna using Stock Synthesis in 2022. The model runs from 1950 to 2020 and was fitted to length composition data, conditional age-at-length (otolith and spines–length-age pairs), 16 fishing fleets and 11 indices of abundance. Growth is modeled by a Richards function with Linf fixed at 271 cm, K fixed at 0.23387, and the shape parameter is estimated by the model. A Beverton-Holt stock recruitment relationship was estimated in the model with the steepness and sigmaR fixed at 0.9 and 0.6, respectively. R0 is freely estimated. Although the diagnostics indicate an acceptable stability of the model, there are important conflicts between the catch information, length composition and index data. The model fits to length compositions were not good, but the model followed most of the indices fairly fine. The model results showed that the SSB decreased since 1950 until 1970s, remaining relatively stable at low values during the 1980-2009 period, and showing a sharp and steady increased since 2010. Model diagnostics indicated that the different source of data provides contradicting information about the stock, resulting in biases in the results