Exactly solvable time-dependent models of two interacting two-level systems

Two coupled two-level systems placed under external time-dependent magnetic fields are modeled by a general Hamiltonian endowed with a symmetry that enables us to reduce the total dynamics into two independent two-dimensional sub-dynamics. Each of the sub-dynamics is shown to be brought into an exactly solvable form by appropriately engineering the magnetic fields and thus we obtain an exact time evolution of the compound system. Several physically relevant and interesting quantities are evaluated exactly to disclose intriguing phenomena in such a system.Comment: 15 pages, 13 figure

Influence of hydrogen on paramagnetic defects induced by UV laser exposure in natural silica

Diffusion limited reactions of point defects were investigated in amorphous SiO2 exposed to UV laser light. Electron spin resonance and in situ absorption measurements at room temperature evidenced the annealing of E' centers and the growth of H(II) centers both occurring in the post-irradiation stage and lasting a few hours. These transients are caused by reactions involving molecular hydrogen H2, made available by dimerization of radiolytic H0.Comment: Submitted to Physica Status Solid

Overcharging: The Crucial Role of Excluded Volume

In this Letter we investigate the mechanism for overcharging of a single spherical colloid in the presence of aqueous salts within the framework of the primitive model by molecular dynamics (MD) simulations as well as integral-equation theory. We find that the occurrence and strength of overcharging strongly depends on the salt-ion size, and the available volume in the fluid. To understand the role of the excluded volume of the microions, we first consider an uncharged system. For a fixed bulk concentration we find that upon increasing the fluid particle size one strongly increases the local concentration nearby the colloidal surface and that the particles become laterally ordered. For a charged system the first surface layer is built up predominantly by strongly correlated counterions. We argue that this a key mechanism to produce overcharging with a low electrostatic coupling, and as a more practical consequence, to account for charge inversion with monovalent aqueous salt ions.Comment: 7 pages, 3 figs (4 EPS files). To appear in Europhysics Letter

Behavior of block-polyampholytes near a charged surface

The behavior of polyampholytes near a charged planar surface is studied by means of Monte Carlo simulations. The investigated polyampholytes are overall electrically neutral and made up of oppositely charged units (called blocks) that are highly charged and of the the same length. The influence of block length and substrate's surface-charge-density on the adsorption behavior is addressed. A detailed structural study, including local monomer concentration, monomer mean height, transversal chain size, interface-bond orientation correlation, is provided. It is demonstrated that adsorption is favored for long enough blocks and/or high enough Coulomb interface-ion couplings. By explicitly measuring the chain size in the bulk, it is shown that the charged interface induces either a swelling or a shrinkage of the transversal dimension of the chain depending, in a non trivial manner, on the block length.Comment: 23 pages - 10 eps figs. Submitted for publicatio

Time evolution of a pair of distinguishable interacting spins subjected to controllable and noisy magnetic fields

The quantum dynamics of a $\hat{\mathbf{J}}^2=(\hat{\mathbf{j}}_1+\hat{\mathbf{j}}_2)^2$-conserving Hamiltonian model describing two coupled spins $\hat{\mathbf{j}}_1$ and $\hat{\mathbf{j}}_2$ under controllable and fluctuating time-dependent magnetic fields is investigated. Each eigenspace of $\hat{\mathbf{J}}^2$ is dynamically invariant and the Hamiltonian of the total system restricted to any one of such $(j_1+j_2)-|j_1-j_2|+1$ eigenspaces, possesses the SU(2) structure of the Hamiltonian of a single fictitious spin acted upon by the total magnetic field. We show that such a reducibility holds regardless of the time dependence of the externally applied field as well as of the statistical properties of the noise, here represented as a classical fluctuating magnetic field. The time evolution of the joint transition probabilities of the two spins $\hat{\mathbf{j}}_1$ and $\hat{\mathbf{j}}_2$ between two prefixed factorized states is examined, bringing to light peculiar dynamical properties of the system under scrutiny. When the noise-induced non-unitary dynamics of the two coupled spins is properly taken into account, analytical expressions for the joint Landau-Zener transition probabilities are reported. The possibility of extending the applicability of our results to other time-dependent spin models is pointed out.Comment: 11 pages, 5 figure

N-qubit states as points on the Bloch sphere

We show how the Majorana representation can be used to express the pure states of an N-qubit system as points on the Bloch sphere. We compare this geometrical representation of N-qubit states with an alternative one, proposed recently by the present authors.Comment: 9 pages, 2 figures, contribution to CEWQO 2009 proceedings. v2: Minor changes, published versio

An example of interplay between Physics and Mathematics: Exact resolution of a new class of Riccati Equations

A novel recipe for exactly solving in finite terms a class of special differential Riccati equations is reported. Our procedure is entirely based on a successful resolution strategy quite recently applied to quantum dynamical time-dependent SU(2) problems. The general integral of exemplary differential Riccati equations, not previously considered in the specialized literature, is explicitly determined to illustrate both mathematical usefulness and easiness of applicability of our proposed treatment. The possibility of exploiting the general integral of a given differential Riccati equation to solve an SU(2) quantum dynamical problem, is succinctly pointed out.Comment: 10 page

Polyelectrolyte Multilayering on a Charged Planar Surface

The adsorption of highly \textit{oppositely} charged flexible polyelectrolytes (PEs) on a charged planar substrate is investigated by means of Monte Carlo (MC) simulations. We study in detail the equilibrium structure of the first few PE layers. The influence of the chain length and of a (extra) non-electrostatic short range attraction between the polycations and the negatively charged substrate is considered. We show that the stability as well as the microstructure of the PE layers are especially sensitive to the strength of this latter interaction. Qualitative agreement is reached with some recent experiments.Comment: 28 pages; 11 (main) Figs - Revtex4 - Higher resolution Figs can be obtained upon request. To appear in Macromolecule