A model of large volumetric capacitance in graphene supercapacitors based on ion clustering

Electric double layer supercapacitors are promising devices for high-power energy storage based on the reversible absorption of ions into porous, conducting electrodes. Graphene is a particularly good candidate for the electrode material in supercapacitors due to its high conductivity and large surface area. In this paper we consider supercapacitor electrodes made from a stack of graphene sheets with randomly-inserted "spacer" molecules. We show that the large volumetric capacitances C > 100 F/cm^3 observed experimentally can be understood as a result of collective intercalation of ions into the graphene stack and the accompanying nonlinear screening by graphene electrons that renormalizes the charge of the ion clusters.Comment: 13 pages, 5 figures; additional discussion and supporting calculations adde

Filaments as Possible Signatures of Magnetic Field Structure in Planetary Nebulae

We draw attention to the extreme filamentary structures seen in high-resolution optical images of certain planetary nebulae. We determine the physical properties of the filaments in the nebulae IC 418, NGC 3132, and NGC 6537, and based on their large length-to-width ratios, longitudinal coherence, and morphology, we suggest that they may be signatures of the underlying magnetic field. The fields needed for the coherence of the filaments are probably consistent with those measured in the precursor circumstellar envelopes. The filaments suggest that magnetic fields in planetary nebulae may have a localized and thread-like geometry.Comment: 26 pages with 7 figures. To be published in PASP. For full resolution images see http://physics.nyu.edu/~pjh

The economic and innovation contribution of universities: a regional perspective

Universities and other higher education institutions (HEIs) have come to be regarded as key sources of knowledge utilisable in the pursuit of economic growth. Although there have been numerous studies assessing the economic and innovation impact of HEIs, there has been little systematic analysis of differences in the relative contribution of HEIs across regions. This paper provides an exploration of some of these differences in the context of the UK’s regions. Significant differences are found in the wealth generated by universities according to regional location and type of institution. Universities in more competitive regions are generally more productive than those located in less competitive regions. Also, traditional universities are generally more productive than their newer counterparts, with university productivity positively related to knowledge commercialisation capabilities. Weaker regions tend to be more dependent on their universities for income and innovation, but often these universities under-perform in comparison to counterpart institutions in more competitive regions. It is argued that uncompetitive regions lack the additional knowledge infrastructure, besides universities, that are more commonly a feature of more competitive regions

Risk Analysis of Organic Cropping Systems in Minnesota

When all strategies received conventional market prices, 4-year cropping sequences had greater net returns than 2-year sequences, and the organic input, 4-year strategy had the highest net return. Adding 50% of the estimated organic premium, the 4-year, organic strategy dominated all low- and high-purchased input strategies.Crop Production/Industries, Risk and Uncertainty,

Bottom-up Effects of Substrate on Two Adjacent Shrub Communities and the Distribution of a Rare and Endangered Plant Species, Astragalus jaegerianus Munz.

Edaphic habitats are botanically interesting because of differences in vegetation with neighboring sites and because they tend to harbor rare species. In the central Mojave Desert, there are granite colluvial substrates where creosote bush, the dominant shrub in the area, is sparser and generally smaller than in the neighboring creosote bush communities. It is on these sites that the Lane Mountain milkvetch, a rare and federally endangered species, is restricted. The milkvetch is a nitrogen-fixer and grows under and within the canopy of host shrubs. Our previous studies have demonstrated that the milkvetch has no preference for species of host shrub, except Larrea tridentata, which appears to be an unsuitable host plant for the milkvetch. In this study, we surveyed three transects within milkvetch habitats and three transects in adjacent creosote bush habitats in the year 2000 and again in 2010, a period coincident with long-term drought conditions in the Mojave Desert. Our results show that adjacent milkvetch and creosote bush shrub communities differ significantly in shrub height, shrub volume, and shrub density in the year 2000: the shrubs in milkvetch communities were more numerous but smaller compared to adjacent creosote bush scrub. Species richness also differed between communities in the year 2000: milkvetch communities contained 19 different shrub species and creosote bush communities had only 9 species. Surveys in 2010 show that the drought had significant negative effects on both shrub communities. Total shrub mortality (166 shrubs) was high compared to shrub recruitment (16 shrubs), and the majority of mortality and recruitment occurred in milkvetch communities (131 deaths and 16 recruits). Shrub densities decreased significantly in milkvetch communities in 2010, but were still considerably higher than in creosote bush communities. These results suggest that the restricted distribution of the Lane Mountain milkvetch may be the result of higher shrub densities in milkvetch shrub communities; increased shrub densities increases the proximity of suitable host shrubs, which in turn increase the probability of successful seed dispersal and establishment

The cost of breast cancer recurrences.

Information about the costs of recurrent breast cancer is potentially important for targeting cost containment strategies and analysing the cost-effectiveness of breast cancer control programmes. We estimated these costs by abstracting health service and consumable usage data from the medical histories of 128 patients, and valuing each of the resources used. Resource usage and costs were summarised by regarding the recurrence as a series of episodes which were categorised into five anatomical site-based groups according to the following hierarchy: visceral, central nervous system (CNS), bone, local and other. Hospital visits and investigations comprised 78% of total costs for all episodes combined, and there were significant differences between the site-based groups in the frequency of hospital visits and most investigations. Total costs were most accurately described by separate linear regression models for each group, with the natural logarithm of the cost of the episode as the dependent variable, and predictor variables including the duration of the episode, duration squared, duration cubed and a variable indicating whether the episode was fatal. Visceral and CNS episodes were associated with higher costs than the other groups and were more likely to be shorter and fatal. A fatal recurrence of duration 15.7 months (the median for our sample) was predicted to cost $10,575 (Aus + 1988; or 4,877 pounds). Reduction of the substantial costs of recurrent breast cancer is likely to be a sizable economic benefit of adjuvant systemic therapy and mammographic screening. We did not identify any major opportunities for cost containment during the management of recurrences

VLA Observations of H I in the Helix Nebula (NGC 7293)

We report the detection of 21-cm line emission from H I in the planetary nebula NGC 7293 (the Helix). The observations, made with the Very Large Array, show the presence of a ring of atomic hydrogen that is associated with the outer portion of the ionized nebula. This ring is most probably gas ejected in the AGB phase that has been subsequently photodissociated by radiation from the central star. The H I emission spreads over about 50 km/s in radial velocity. The mass in H I is approximately 0.07 solar masses, about three times larger than the mass in molecular hydrogen and comparable with the mass in ionized hydrogen.Comment: 19 pages, 9 figure

Knowledge networks and universities : locational and organisational aspects of knowledge transfer interactions

This paper explores the nature of the significant knowledge networks universities form with external organisations through knowledge transfer activities. Focussing on the UK higher education system, the analysis focuses on examining the extent to which organisational and locational characteristics are associated with the nature of these networks, finding that the nature of the networks universities form through knowledge transfer are related to both characteristics. In particular, we find that the institution’s status is important with more established universities are likely to have a more diverse range of organisations with which they interact, as well as a higher number of non-local interactions. In terms of geographic location, we find that universities within lagging regions tend to have more locally focused networks than universities in more leading regions. Overall, the knowledge transfer networking capacity of universities is found to be associated with the regional business environment within which they are situated, with the results going someway to confirming the importance of the role of universities in regional innovation systems, However, it also the case that more established, research focussed, universities are more likely to form part of wider , and possibly even more globalised, knowledge networks. Therefore, both the flow and stock of knowledge within regions is likely to be influenced by the networks formed by its universities, which has implications for both regional innovation capability and regional competitiveness

Massive expanding torus and fast outflow in planetary nebula NGC 6302

We present interferometric observations of $^{12}$CO and $^{13}$CO $J$=2$-$1 emission from the butterfly-shaped, young planetary nebula NGC 6302. The high angular resolution and high sensitivity achieved in our observations allow us to resolve the nebula into two distinct kinematic components: (1) a massive expanding torus seen almost edge-on and oriented in the North-South direction, roughly perpendicular to the optical nebula axis. The torus exhibits very complex and fragmentated structure; (2) high velocity molecular knots moving at high velocity, higher than 20 \kms, and located in the optical bipolar lobes. These knots show a linear position-velocity gradient (Hubble-like flow), which is characteristic of fast molecular outflow in young planetary nebulae. From the low but variable $^{12}$CO/$^{13}$CO $J$=2$-$1 line intensity ratio we conclude that the $^{12}$CO $J$=2$-$1 emission is optically thick over much of the nebula. Using the optically thinner line $^{13}$CO $J$=2$-$1 we estimate a total molecular gas mass of $\sim$ 0.1 M$_\odot$, comparable to the ionized gas mass; the total gas mass of the NGC 6302 nebula, including the massive ionized gas from photon dominated region, is found to be $\sim$ 0.5 M$_\odot$. From radiative transfer modelling we infer that the torus is seen at inclination angle of 75$^\circ$ with respect to the plane of the sky and expanding at velocity of 15 \kms. Comparison with recent observations of molecular gas in NGC 6302 is also discussed.Comment: 24 pages, 7 figures, accepted for publication in Astrophysical Journa