Unstable particle's wave-function renormalization prescription

We strictly define two set Wave-function Renormalization Constants (WRC) under the LSZ reduction formula for unstable particles at the first time. Then by introducing antiparticle's WRC and the CPT conservation law we obtain a new wave-function renormalization condition which can be used to totally determine the two set WRC. We calculate two physical processes to manifest the consistence of the present wave-function renormalization prescription with the gauge theory in standard model. We also prove that the conventional wave-function renormalization prescription which discards the imaginary part of unstable particle's WRC leads to physical amplitude gauge dependent.Comment: 10 pages, 3 figure

Preparation, Structure, and Reactivity of Nonstabilized Organoiron Compounds. Implications for Iron-Catalyzed Cross Coupling Reactions

A series of unprecedented organoiron complexes of the formal oxidation states −2, 0, +1, +2, and +3 is presented, which are largely devoid of stabilizing ligands and, in part, also electronically unsaturated (14-, 16-, 17- and 18-electron counts). Specifically, it is shown that nucleophiles unable to undergo β-hydride elimination, such as MeLi, PhLi, or PhMgBr, rapidly reduce Fe(3+) to Fe(2+) and then exhaustively alkylate the metal center. The resulting homoleptic organoferrate complexes [(Me4Fe)(MeLi)][Li(OEt2)]2 (3) and [Ph4Fe][Li(Et2O)2][Li(1,4-dioxane)] (5) could be characterized by X-ray crystal structure analysis. However, these exceptionally sensitive compounds turned out to be only moderately nucleophilic, transferring their organic ligands to activated electrophiles only, while being unable to alkylate (hetero)aryl halides unless they are very electron deficient. In striking contrast, Grignard reagents bearing alkyl residues amenable to β-hydride elimination reduce FeXn (n = 2, 3) to clusters of the formal composition [Fe(MgX)2]n. The behavior of these intermetallic species can be emulated by structurally well-defined lithium ferrate complexes of the type [Fe(C2H4)4][Li(tmeda)]2 (8), [Fe(cod)2][Li(dme)]2 (9), [CpFe(C2H4)2][Li(tmeda)] (7), [CpFe(cod)][Li(dme)] (11), or [Cp*Fe(C2H4)2][Li(tmeda)] (14). Such electron-rich complexes, which are distinguished by short intermetallic Fe−Li bonds, were shown to react with aryl chlorides and allyl halides; the structures and reactivity patterns of the resulting organoiron compounds provide first insights into the elementary steps of low valent iron-catalyzed cross coupling reactions of aryl, alkyl, allyl, benzyl, and propargyl halides with organomagnesium reagents. However, the acquired data suggest that such C−C bond formations can occur, a priori, along different catalytic cycles shuttling between metal centers of the formal oxidation states Fe(+1)/Fe(+3), Fe(0)/Fe(+2), and Fe(−2)/Fe(0). Since these different manifolds are likely interconnected, an unambiguous decision as to which redox cycle dominates in solution remains difficult, even though iron complexes of the lowest accessible formal oxidation states promote the reactions most effectively

Study of non-equilibrium effects and thermal properties of heavy ion collisions using a covariant approach

Non-equilibrium effects are studied using a full Lorentz-invariant formalism. Our analysis shows that in reactions considered here, no global or local equilibrium is reached. The heavier masses are found to be equilibrated more than the lighter systems. The local temperature is extracted using hot Thomas Fermi formalism generalized for the case of two interpenetrating pieces of nuclear matter. The temperature is found to vary linearly with bombarding energy and impact parameter whereas it is nearly independent of the mass of the colliding nuclei. This indicates that the study of temperature with medium size nuclei is also reliable. The maximum temperatures obtained in our approach are in a nice agreement with earlier calculations of other approaches. A simple parametrization of maximal temperature as a function of the bombarding energy is also given.Comment: LaTex-file, 17 pages, 8 figures (available upon request), Journal of Physics G20 (1994) 181

HD 152246 - a new high-mass triple system and its basic properties

Analyses of multi-epoch, high-resolution (R ~ 50.000) optical spectra of the O-type star HD 152246 (O9 IV according to the most recent classification), complemented by a limited number of earlier published radial velocities, led to the finding that the object is a hierarchical triple system, where a close inner pair (Ba-Bb) with a slightly eccentric orbit (e = 0.11) and a period of 6.0049 days revolves in a 470-day highly eccentric orbit (e = 0.865) with another massive and brighter component A. The mass ratio of the inner system must be low since we were unable to find any traces of the secondary spectrum. The mass ratio A/(Ba+Bb) is 0.89. The outer system has recently been resolved using long-baseline interferometry on three occasions. The interferometry confirms the spectroscopic results and specifies elements of the system. Our orbital solutions, including the combined radial-velocity and interferometric solution indicate an orbital inclination of the outer orbit of 112{\deg} and stellar masses of 20.4 and 22.8 solar masses. We also disentangled the spectra of components A and Ba and compare them to synthetic spectra from two independent programmes, TLUSTY and FASTWIND. In either case, the fit was not satisfactory and we postpone a better determination of the system properties for a future study, after obtaining observations during the periastron passage of the outer orbit (the nearest chance being March 2015). For the moment, we can only conclude that component A is an O9 IV star with v*sin(i) = 210 +\- 10 km/s and effective temperature of 33000 +\- 500 K, while component Ba is an O9 V object with v*sin(i) = 65 +/- 3 km/s and T_eff = 33600 +\- 600 K.Comment: 9 pages, 6 figures, accepted for publication in Astronomy and Astrophysic

The oxygen affinity of haemoglobin St. Luke's

Podeu consultar la versió en castellà a:http://hdl.handle.net/11703/8763

Profoundly reduced neovascularization capacity of bone marrow mononuclear cells derived from patients with chronic ischemic heart disease

Background— Cell therapy with bone marrow–derived stem/progenitor cells is a novel option for improving neovascularization and cardiac function in ischemic heart disease. Circulating endothelial progenitor cells in patients with coronary heart disease are impaired with respect to number and functional activity. However, whether this impairment also extends to bone marrow–derived mononuclear cells (BM-MNCs) in patients with chronic ischemic cardiomyopathy (ICMP) is unclea

Gibrat's law for cities: uniformly most powerful unbiased test of the Pareto against the lognormal

We address the general problem of testing a power law distribution versus a log-normal distribution in statistical data. This general problem is illustrated on the distribution of the 2000 US census of city sizes. We provide definitive results to close the debate between Eeckhout (2004, 2009) and Levy (2009) on the validity of Zipf's law, which is the special Pareto law with tail exponent 1, to describe the tail of the distribution of U.S. city sizes. Because the origin of the disagreement between Eeckhout and Levy stems from the limited power of their tests, we perform the {\em uniformly most powerful unbiased test} for the null hypothesis of the Pareto distribution against the lognormal. The $p$-value and Hill's estimator as a function of city size lower threshold confirm indubitably that the size distribution of the 1000 largest cities or so, which include more than half of the total U.S. population, is Pareto, but we rule out that the tail exponent, estimated to be $1.4 \pm 0.1$, is equal to 1. For larger ranks, the $p$-value becomes very small and Hill's estimator decays systematically with decreasing ranks, qualifying the lognormal distribution as the better model for the set of smaller cities. These two results reconcile the opposite views of Eeckhout (2004, 2009) and Levy (2009). We explain how Gibrat's law of proportional growth underpins both the Pareto and lognormal distributions and stress the key ingredient at the origin of their difference in standard stochastic growth models of cities \cite{Gabaix99,Eeckhout2004}.Comment: 7 pages + 2 figure