3,753 research outputs found
Time-symmetric fluctuations in nonequilibrium systems
For nonequilibrium steady states, we identify observables whose fluctuations
satisfy a general symmetry and for which a new reciprocity relation can be
shown. Unlike the situation in recently discussed fluctuation theorems, these
observables are time-reversal symmetric. That is essential for exploiting the
fluctuation symmetry beyond linear response theory. Besides time-reversal, a
crucial role is played by the reversal of the driving fields, that further
resolves the space-time action. In particular, the time-symmetric part in the
space-time action determines second order effects of the nonequilibrium
driving.Comment: 4 page
Comet and close-approach asteroid mission study. volume 1- summary report final report
Comet and close-approach asteroid mission stud
A charged particle in a magnetic field - Jarzynski Equality
We describe some solvable models which illustrate the Jarzynski theorem and
related fluctuation theorems. We consider a charged particle in the presence of
magnetic field in a two dimensional harmonic well. In the first case the centre
of the harmonic potential is translated with a uniform velocity, while in the
other case the particle is subjected to an ac force. We show that Jarzynski
identity complements Bohr-van Leeuwen theorem on the absence of diamagnetism in
equilibrium classical system.Comment: 5 pages, minor corrections made and journal reference adde
Anaerobic digestion of soft drink beverage waste and sewage sludge
© 2018 Soft drink beverage waste (BW) was evaluated as a potential substrate for anaerobic co-digestion with sewage sludge to increase biogas production. Results from this study show that the increase in biogas production is proportional to the increase in organic loading rate (OLR) rate due to BW addition. The OLR increase of 86 and 171% corresponding to 10 and 20% BW by volume in the feed resulted in 89 and 191% increase in biogas production, respectively. Under a stable condition, anaerobic co-digestion with BW did not lead to any significant impact on digestate quality (in terms of COD removal and biosolids odour) and biogas composition. The results suggest that existing nutrients in sewage sludge can support an increase in OLR by about 2 kg COD/m3/d from a carbon rich substrate such as soft drink BW without inhibition or excessive impact on subsequent handling of the digestate
A numerical approach to large deviations in continuous-time
We present an algorithm to evaluate the large deviation functions associated
to history-dependent observables. Instead of relying on a time discretisation
procedure to approximate the dynamics, we provide a direct continuous-time
algorithm, valuable for systems with multiple time scales, thus extending the
work of Giardin\`a, Kurchan and Peliti (PRL 96, 120603 (2006)).
The procedure is supplemented with a thermodynamic-integration scheme, which
improves its efficiency. We also show how the method can be used to probe large
deviation functions in systems with a dynamical phase transition -- revealed in
our context through the appearance of a non-analyticity in the large deviation
functions.Comment: Submitted to J. Stat. Mec
Efficiency of Energy Transduction in a Molecular Chemical Engine
A simple model of the two-state ratchet type is proposed for molecular
chemical engines that convert chemical free energy into mechanical work and
vice versa. The engine works by catalyzing a chemical reaction and turning a
rotor. Analytical expressions are obtained for the dependences of rotation and
reaction rates on the concentrations of reactant and product molecules, from
which the performance of the engine is analyzed. In particular, the efficiency
of energy transduction is discussed in some detail.Comment: 4 pages, 4 fugures; title modified, figures 2 and 3 modified, content
changed (pages 1 and 4, mainly), references adde
Impacts of mixing on foaming, methane production, stratification and microbial community in full-scale anaerobic co-digestion process
© 2019 Elsevier Ltd This study investigated the impact of mixing on key factors including foaming, substrate stratification, methane production and microbial community in three full scale anaerobic digesters. Digester foaming was observed at one plant that co-digested sewage sludge and food waste, and was operated without mixing. The lack of mixing led to uneven distribution of total chemical oxygen demand (tCOD) and volatile solid (VS) as well as methane production within the digester. 16S rRNA gene-based community analysis clearly differentiated the microbial community from the top and bottom. By contrast, foaming and substrate stratification were not observed at the other two plants with internal circulation mixing. The abundance of methanogens (Methanomicrobia) at the top was about four times higher than at the bottom, correlating to much higher methane production from the top verified by ex-situ biomethane assay, causing foaming. This result is consistent with foaming potential assessment of digestate samples from the digester
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Patterns of genomic and phenomic diversity in wine and table grapes.
Grapes are one of the most economically and culturally important crops worldwide, and they have been bred for both winemaking and fresh consumption. Here we evaluate patterns of diversity across 33 phenotypes collected over a 17-year period from 580 table and wine grape accessions that belong to one of the world's largest grape gene banks, the grape germplasm collection of the United States Department of Agriculture. We find that phenological events throughout the growing season are correlated, and quantify the marked difference in size between table and wine grapes. By pairing publicly available historical phenotype data with genome-wide polymorphism data, we identify large effect loci controlling traits that have been targeted during domestication and breeding, including hermaphroditism, lighter skin pigmentation and muscat aroma. Breeding for larger berries in table grapes was traditionally concentrated in geographic regions where Islam predominates and alcohol was prohibited, whereas wine grapes retained the ancestral smaller size that is more desirable for winemaking in predominantly Christian regions. We uncover a novel locus with a suggestive association with berry size that harbors a signature of positive selection for larger berries. Our results suggest that religious rules concerning alcohol consumption have had a marked impact on patterns of phenomic and genomic diversity in grapes
Efficiency of Free Energy Transduction in Autonomous Systems
We consider the thermodynamics of chemical coupling from the viewpoint of
free energy transduction efficiency. In contrast to an external
parameter-driven stochastic energetics setup, the dynamic change of the
equilibrium distribution induced by chemical coupling, adopted, for example, in
biological systems, is inevitably an autonomous process. We found that the
efficiency is bounded by the ratio between the non-symmetric and the
symmetrized Kullback-Leibler distance, which is significantly lower than unity.
Consequences of this low efficiency are demonstrated in the simple two-state
case, which serves as an important minimal model for studying the energetics of
biomolecules.Comment: 4 pages, 4 figure
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