Thermoelastic study of nanolayered structures using time-resolved x-ray diffraction at high repetition rate

We investigate the thermoelastic response of a nanolayered sample composed of a metallic SrRuO3 (SRO) electrode sandwiched between a ferroelectric Pb(Zr0.2Ti0.8)O3 (PZT) film with negative thermal expansion and a SrTiO3 substrate. SRO is rapidly heated by fs-laser pulses with 208 kHz repetition rate. Diffraction of x-ray pulses derived from a synchrotron measures the transient out-of-plane lattice constant c of all three materials simultaneously from 120 ps to 5 mus with a relative accuracy up to Delta c/c = 10^-6. The in-plane propagation of sound is essential for understanding the delayed out of plane expansion.Comment: 5 pages, 3 figure

Signatures of quantum criticality in the thermopower of Ba(Fe(1-x)Co(x))2As2

We demonstrate that the thermopower (S) can be used to probe the spin fluctuations (SFs) in proximity to the quantum critical point (QCP) in Fe-based superconductors. The sensitivity of S to the entropy of charge carriers allows us to observe an increase of S/T in Ba(Fe(1-x)Co(x))2As2 close to the spin-density-wave (SDW) QCP. This behavior is due to the coupling of low-energy conduction electrons to two-dimensional SFs, similar to heavy-fermion systems. The low-temperature enhancement of S/T in the Co substitution range 0.02 < x < 0.1 is bordered by two Lifshitz transitions, and it corresponds to the superconducting region, where a similarity between the electron and non-reconstructed hole pockets exists. The maximal S/T is observed in proximity to the commensurate-to-incommensurate SDW transition, for critical x_c ~ 0.05, close to the highest superconducting T_c. This analysis indicates that low-T thermopower is influenced by critical spin fluctuations which are important for the superconducting mechanism

Resistive switching in β-SrV6O15

Abstract.: We investigate the pressure and temperature behavior of current-dependent resistivity of β-SrV6O15. We observe a switching between states of different resistivities in the insulating state of β-SrV6O15. In the low pressure phase, the resistive switching appears at temperatures below the semiconductor-insulator transition. In the high pressure phase, under ~1.6GPa, the switching appears in the temperature range of the phase transition. The existence of switching may imply an important role of strontium off-stoichiometry for the electrical transport in β-SrV6O15. No electric-field-induced enhancement of the conductivity is observed. However, the conduction is significantly nonlinear under ~1.6GPa, indicating that the charge order pattern in the high pressure phase is considerably different from that of the low pressure phas

3D printed e-tongue

FAPESP - FUNDAÇÃO DE AMPARO À PESQUISA DO ESTADO DE SÃO PAULOCAPES - COORDENAÇÃO DE APERFEIÇOAMENTO DE PESSOAL E NÍVEL SUPERIORCNPQ - CONSELHO NACIONAL DE DESENVOLVIMENTO CIENTÍFICO E TECNOLÓGICONowadays, one of the biggest issues addressed to electronic sensor fabrication is the build-up of efficient electrodes as an alternative way to the expensive, complex and multistage processes required by traditional techniques. Printed electronics arises as an interesting alternative to fulfill this task due to the simplicity and speed to stamp electrodes on various surfaces. Within this context, the Fused Deposition Modeling 3D printing is an emerging, cost-effective and alternative technology to fabricate complex structures that potentiates several fields with more creative ideas and new materials for a rapid prototyping of devices. We show here the fabrication of interdigitated electrodes using a standard home-made CoreXY 3D printer using transparent and graphene-based PLA filaments. Macro 3D printed electrodes were easily assembled within 6 min with outstanding reproducibility. The electrodes were also functionalized with different nanostructured thin films via dip-coating Layer-by-Layer technique to develop a 3D printed e-tongue setup. As a proof of concept, the printed e-tongue was applied to soil analysis. A control soil sample was enriched with several macro-nutrients to the plants (N, P, K, S, Mg, and Ca) and the discrimination was done by electrical impedance spectroscopy of water solution of the soil samples. The data was analyzed by Principal Component Analysis and the 3D printed sensor distinguished clearly all enriched samples despite the complexity of the soil chemical composition. The 3D printed e-tongue successfully used in soil analysis encourages further investments in developing new sensory tools for precision agriculture and other fields exploiting the simplicity and flexibility offered by the 3D printing techniques.618FAPESP - FUNDAÇÃO DE AMPARO À PESQUISA DO ESTADO DE SÃO PAULOCAPES - COORDENAÇÃO DE APERFEIÇOAMENTO DE PESSOAL E NÍVEL SUPERIORCNPQ - CONSELHO NACIONAL DE DESENVOLVIMENTO CIENTÍFICO E TECNOLÓGICOFAPESP - FUNDAÇÃO DE AMPARO À PESQUISA DO ESTADO DE SÃO PAULOCAPES - COORDENAÇÃO DE APERFEIÇOAMENTO DE PESSOAL E NÍVEL SUPERIORCNPQ - CONSELHO NACIONAL DE DESENVOLVIMENTO CIENTÍFICO E TECNOLÓGICO2014/03691-72015/14836-92015/21616-52017/06985-0sem informaçãosem informaçãoSem informaçã

L4Fe2As2Te1-xO4-yFy (L = Pr, Sm, Gd): a layered oxypnictide superconductor with Tc up to 45 K

The synthesis, structural and physical properties of iron lanthanide oxypnictide superconductors, L4Fe2As2Te1-xO4 (L = Pr, Sm, Gd), with transition temperature at ~ 25 K are reported. Single crystals have been grown at high pressure using cubic anvil technique. The crystal structure consists of layers of L2O2 tetrahedra separated by alternating layers of chains of Te and of Fe2As2 tetrahedra: -L2O2-Te-L2O2-Fe2As2-L2O2-Te-L2O2- (space group: I4/mmm, a ~ 4.0, c ~ 29.6 {\AA}). Substitution of oxygen by fluorine increases the critical temperature, e.g. in Gd4Fe2As2Te1-xOyF4-y up to 45 K. Magnetic torque measurements reveal an anisotropy of the penetration depths of ~31.Comment: 8 figures, 4 table

Sex Offender Treatment Project: Literature Review

A comprehensive literature review on recidivism by and the treatment of sex offenders.Alaska Department of CorrectionsAcknowledgements / Introduction / Recidivism / Treatment — Voluntary Vs. Involuntary, Treated Vs. Untreated / Treatment — Types, Levels, Evolution, Relapse Prevention and Cost/Benefit Analysis / Treatment and Recidivism as it Relates to Various Types of Sexual Offenders / Other Factors Possibly Involved in Reoffense Potential / Conclusion / Bibliograph

Phonon anomaly at the charge ordering transition in 1T-TaS2

The infrared reflectance of the transition metal chalcogenide 1T-TaS2 has been measured at temperatures from 30K to 360K over 30-45,000cm^-1 (4meV-5.5eV). The optical conductivity was obtained by Kramers-Kronig analysis. At 360K only modest traces of the phonon lines are noticeable. The phonon modes are followed by a pseudogap-like increase of the optical conductivity, with direct optical transitions observed at frequencies above 1eV. As the temperature decreases, the low frequency conductivity also decreases, phonon modes become more pronounced and pseudogap develops into a gap at 800cm^-1 (100meV). We observe an anomalous frequency dependence of the 208cm^-1 infrared-active phonon mode. This mode demonstrates softening as the temperature decreases below the 180K metal-to-insulator transition. The same mode demonstrates strong hysteresis of the frequency and linewidth changes, similar in its temperature behavior to the hysteresis in the dc-resistivity. We discuss a possible relation of the observed softening of the mode to the structural changes associated with the metal-to-insulator transition.Comment: 7 pages, 4 figures, 1 table; corrected typo