Biomass from winery waste: Evaluation of dust explosion hazards

Food and drink supply chains have significant environmental impacts due to their use of resources, emissions, and waste production. An efficient method to reduce this impact is the valorisation of biomass waste through energy recovery by using it as a source of heat. The European energy system faces several fundamental challenges being currently the largest emitter of greenhouse gases due to its large dependence on fossil fuels (mostly natural gas). Therefore, the energy sector's decarbonization will play a central role in achieving a climateneutral economy in Europe. Identifying the suitable material for biofuel is basically focused on the amount of energy that the material stores, availability, and logistic considerations. Sawdust and wood chips have been extensively used as biofuel in recent years, but other promising raw and waste materials could be adopted (with the positive effect of reducing the impact on forestry soil and the food chain). Novel materials bring consequently novel challenges, also regarding their safe use. As an example, a relevant waste flow is produced from wine manufacturing. A solid with high moisture content is obtained from grapes pressing, and it could be reused to produce distillates. The obtained exhausted pomace could be considered among the materials potentially involved in energy recovery. It is also carrying dust explosion hazard, as solid residues could be present in the form of coarse and fine powders. In this work, grape pomace is examined: its explosion safety-related properties are evaluated to define the severity of events in which this material could be ignited. Minimum Ignition Energy (MIE), explosion pressure peak (Pmax), deflagration severity index (KSt), autoignition temperature (MIT), and Volatile Point (VP) are measured according to standard procedures. This material's thermal susceptibility and ignition sensitivity are studied and compared with biomasses from different sources (ligneo-cellulosic and herbaceous)

Energy recovery from vinery waste: Dust explosion issues

The concern about global warming issues and their consequences is more relevant than ever, and the H2020 objectives promoted by the EU are oriented towards generating climate actions and sustainable development. The energy sector constitutes a difficult challenge as it plays a key role in the global warming impact. Its decarbonization is a crucial factor, and significant efforts are needed to find efficient alternatives to fossil fuels in heating/electricity generation. The biomass energy industry could have a contribution to make in the shift to renewable sources; the quest for a suitable material is basically focused on the energy amount that it stores, its availability, logistical considerations, and safety issues. This work deals with the characterization of a wine-waste dust sample, in terms of its chemical composition, fire behavior, and explosion violence. This material could be efficiently used in energy generation (via direct burning as pellets), but scarce information is present in terms of the fire and explosion hazards when it is pulverized. In the following, the material is analyzed through different techniques in order to clearly understand its ignition sensitivity and fire effects; accelerating aging treatment is also used to simulate the sample storage life and determine the ways in which this affects its flammability and likelihood of explosion

Issues of “Standard” explosion tests for non-spherical dusts

Measurements of the flammability and explosion parameters for non-spherical dusts are performed according to standard procedures in standard explosion equipment developed and tested for spherical dusts. Studies have shown that the standard procedures and equipment applied to spherical particles suffer from many issues: control of the turbulence level, non-uniform dust dispersion, and particle fragmentation due to the injection system. The applicability of the standard procedures and equipment to non-spherical particles is still an open issue. In this work, we have investigated, via CFD simulations, the distribution of turbulence and dust concentration in the standard 20 l spherical vessel for non-spherical particles. Results have shown that a higher turbulence level and a higher amount of dust actually fed into the vessel are reached with respect to spherical particles

3D change detection analysis of a coastal landslide performed by multi-temporal point clouds comparison

The structure from motion (SfM) photogrammetric technique (FONSTAD et al., 2013) has become a suitable method to obtain high resolution topography data in a wide range of geomorphic environments (PASSALACQUA et al., 2015). SfM is designed to reconstruct the three-dimensional geometry of buildings and objects from randomly acquired images, and represents a low cost option respect to traditional photogrammetric and lidar techniques (FONSTAD et al., 2013). In this way, also the 3D geometry of complex natural surfaces can be achieved with a horizontal and vertical accuracy which depend on the choice of sensor for images acquisition, platform (e.g., UAV, boat, vehicle), and method of assignment of geodetic coordinates to the digital data. In advanced geomorphic applications, repeated photogrammetric surveys at different times allow to detect topographic changes in order to map or monitor erosion, deposition and develop sediment budgets. In this work we present a 3D change detection analysis related to a coastal landslide occurred on 27th October 2013 along the coastal sector of the Campi Flegrei volcanic district, Southern Italy (ESPOSITO et al., 2015). A total of four photogrammetric surveys have been carried out in about two years (Fig. 1), by using a UAV platform for one survey and boats for the other three. In order to accurately define the exterior orientation of images, a topographic survey was also carried out, measuring a series of natural and artificial ground control points external to the landslide area with a long-range Total Station. Images were processed using Agisoft PhotoScan® (http://www.agisoft.com), and 3D point clouds were compared through the "Multiscale Model to Model Cloud Comparison (M3C2)" plugin (LAGUE et al., 2013) included in CloudCompare open source software (http://www.danielgm.net/cc/). The plugin allowed us to estimate orthogonal distances between multitemporal point clouds as well as uncertainty related to each distance measurement. SfM processing of each survey resulted in dense point clouds and high-resolution orthophotos. An average coregistration error between clouds was estimated as 11 cm. As output of the M3C2 distance computation we obtained three new clouds in which each point was characterized by distance and uncertainty attributes (Fig. 2). Points corresponding to statistically significant changes were exported and interpolated in ESRI ArcGis® for volume calculation. Volumetric data show that the landslide deposit at cliff toe was progressively eroded by the sea, while landslide scar was affected by a moderate erosion in the first three months after the 2013 landslide event, as well as by a deep erosion between the second and third surveys. Nevertheless, a negligible eroded volume between 2015 and 2016 surveys was estimated in this area. Deposited sediments decreased through time in the whole landslide area so that, generally, a geomorphic evolution moving towards an equilibrium condition seems to be taking place. The study here described highlights a high potentiality of the SfM and cloud-to-cloud distance computation techniques in geomorphology, both for accurate qualitative and quantitative analysis and for hazard and risk assessment. The studied landslide threats indeed a series of residential buildings located close to the retreating cliff edge

Economic and technical feasibility of betanin and pectin extraction from opuntia ficus-indica peel via microwave-assisted hydrodiffusion

Investigating the feasibility of betanin and pectin extraction from Opuntia ficus-indica peel via microwave-assisted hydrodiffusion and gravity, this study identifies selected important economic and technical aspects associated with this innovative production route starting from prickly pear fruit discards. Which benefits would be derived from this process? Would production be limited to Opuntia-growing countries or, likewise to what happens with dried lemon peel chiefly imported from Argentina, would production take place abroad also? Can distributed manufacturing based on clean extraction technology compete with centralized production using conventional chemical processes

The Latest Trends in Electric Vehicles Batteries

Global energy demand is rapidly increasing due to population and economic growth, especially in large emerging countries, which will account for 90% of energy demand growth to 2035. Electric vehicles (EVs) play a paramount role in the electrification revolution towards the reduction of the carbon footprint. Here, we review all the major trends in Li-ion batteries technologies used in EVs. We conclude that only five types of cathodes are used and that most of the EV companies use Nickel Manganese Cobalt oxide (NMC). Most of the Li-ion batteries anodes are graphite-based. Positive and negative electrodes are reviewed in detail as well as future trends such as the effort to reduce the Cobalt content. The electrolyte is a liquid/gel flammable solvent usually containing a LiFeP6 salt. The electrolyte makes the battery and battery pack unsafe, which drives the research and development to replace the flammable liquid by a solid electrolyte

A new device to seal large coronary aneurysms: a case report

<p>Abstract</p> <p>Introduction</p> <p>Coronary artery aneurysm is an uncommon disease. It is defined as a coronary artery dilatation, exceeding the diameter of the normal adjacent segment or the diameter of the patient's largest coronary vessel by 1.5 to 2 times. Coronary artery aneurysms are typically diagnosed by coronary angiography. The prognosis of coronary artery aneurysm is not well known and the management is challenging.</p> <p>Case presentation</p> <p>A 68-year-old Italian-Caucasian man presented to our hospital with angina. Coronary angiography revealed a large coronary aneurysm of the right coronary artery, which was successfully treated by the percutaneous implantation of an MGuard™stent.</p> <p>Conclusion</p> <p>This case report provides evidence that coronary artery aneurysms, even if very large, can be safely treated by MGuard™stent implantation. We strongly emphasize the high flexibility and good deliverability of this device, which leads to the complete exclusion of the aneurysm mediated by the process of endothelization of its thin mesh sleeves.</p

Immunochemical investigation of allergenic residues in experimental and commercially-available wines fined with egg white proteins

Proteinaceous egg whites are widely used as a fining agent during the production of red wines. Residues of egg white in the final wine could present a risk for individuals allergic to eggs. This study investigated the presence of allergenic residues in both red and white wines fined with egg whites. Experimental and commercially available wines fined with egg whites, with or without subsequent bentonite fining, were studied. Unfined wines were used as negative controls. The physicochemical characteristics of each wine were determined to assess their possible role in enhancing or hindering the elimination of allergenic residues from wine. The amount of egg white protein residues was investigated both by a specifically developed/validated ELISA test and by immunoblotting. Both immunochemical tests used the same anti-total egg white protein antibody and were highly sensitive to the allergen. No egg white protein was detected in the wines studied in either immunochemical test, irrespective of the physicochemical characteristics of the wine, the type and dosage of the fining agent and the oenological process used. The risk of adverse reactions in egg-allergic individuals should therefore be considered negligible, but the exemption from labelling should be allowed only when the absence of residues is confirmed by analytical controls. \ua9 2014 Elsevier Ltd. All rights reserved

The role of thyroid hormone nuclear receptors in the heart: evidence from pharmacological approaches

This review evaluates the hypothesis that the cardiac effects of amiodarone can be explained—at least partly—by the induction of a local ‘hypothyroid-like condition’ in the heart. Evidence supporting the hypothesis comprises the observation that amiodarone exerts an inhibitory effect on the binding of T3 to thyroid hormone receptors (TR) alpha-1 and beta-1 in vitro, and on the expression of particular T3-dependent genes in vivo. In the heart, amiodarone decreases heart rate and alpha myosin heavy chain expression (mediated via TR alpha-1), and increases sarcoplasmic reticulum calcium-activated ATPase and beta myosin heavy chain expression (mediated via TR beta-1). Recent data show a significant similarity in expression profiles of 8,435 genes in the heart of hypothyroid and amiodarone-treated animals, although similarities do not always exist in transcripts of ion channel genes. Induction of a hypothyroid cardiac phenotype by amiodarone may be advantageous by decreasing energy demands and increasing energy availability

Optimized testing strategy for the diagnosis of GAA-FGF14 ataxia/spinocerebellar ataxia 27B

Dominantly inherited GAA repeat expansions in FGF14 are a common cause of spinocerebellar ataxia (GAA-FGF14 ataxia; spinocerebellar ataxia 27B). Molecular confirmation of FGF14 GAA repeat expansions has thus far mostly relied on long-read sequencing, a technology that is not yet widely available in clinical laboratories. We developed and validated a strategy to detect FGF14 GAA repeat expansions using long-range PCR, bidirectional repeat-primed PCRs, and Sanger sequencing. We compared this strategy to targeted nanopore sequencing in a cohort of 22 French Canadian patients and next validated it in a cohort of 53 French index patients with unsolved ataxia. Method comparison showed that capillary electrophoresis of long-range PCR amplification products significantly underestimated expansion sizes compared to nanopore sequencing (slope, 0.87 [95% CI, 0.81 to 0.93]; intercept, 14.58 [95% CI, − 2.48 to 31.12]) and gel electrophoresis (slope, 0.84 [95% CI, 0.78 to 0.97]; intercept, 21.34 [95% CI, − 27.66 to 40.22]). The latter techniques yielded similar size estimates. Following calibration with internal controls, expansion size estimates were similar between capillary electrophoresis and nanopore sequencing (slope: 0.98 [95% CI, 0.92 to 1.04]; intercept: 10.62 [95% CI, − 7.49 to 27.71]), and gel electrophoresis (slope: 0.94 [95% CI, 0.88 to 1.09]; intercept: 18.81 [95% CI, − 41.93 to 39.15]). Diagnosis was accurately confirmed for all 22 French Canadian patients using this strategy. We also identified 9 French patients (9/53; 17%) and 2 of their relatives who carried an FGF14 (GAA)≥250 expansion. This novel strategy reliably detected and sized FGF14 GAA expansions, and compared favorably to long-read sequencing