Hydrogen as a Source of Flux Noise in SQUIDs

Superconducting qubits are hampered by flux noise produced by surface spins from a variety of microscopic sources. Recent experiments indicated that hydrogen (H) atoms may be one of those sources. Using density functional theory calculations, we report that H atoms either embedded in, or adsorbed on, an a-Al2O3(0001) surface have sizeable spin moments ranging from 0.81 to 0.87 uB with energy barriers for spin reorientation as low as ~10 mK. Furthermore, H adatoms on the surface attract gas molecules such as O2, producing new spin sources. We propose coating the surface with graphene to eliminate H-induced surface spins and to protect the surface from other adsorbates.Comment: 12 pages, 4 figure

Plate tectonics: When ancient continents collide

The geological record preserves scant evidence for early plate tectonics. Analysis of eclogites — metamorphic rocks formed in subduction zones — in the Trans-Hudson mountain belt suggests modern-style subduction may have operated 1,800 million years ago

Assessing Integrated Water Management Options for Urban Developments - Canberra case study

Urban water services in the Australian Capital Territory (ACT) are currently provided through conventional centralised systems, involving large scale water distribution, wastewater collection, water and wastewater treatment. A study was conducted to assist Environment ACT in setting broad policies for future water services in Canberra. This paper presents the outcomes of a study examining the effects of various water servicing options on water resources and the environment, for two townships in Canberra, one existing and one greenfield site. Three modelling tools were used to predict the effects of various alternative water servicing scenarios, including demand management options, rainwater tanks, greywater use, on-site detention tanks, gross pollutant traps, swales and ponds. The results show that potable water reductions are best achieved by demand management tools or a combination of greywater and rainwater use for existing suburbs, while 3rd pipe systems are preferred for greenfield sites. For this specific climatic region and end use demands, modelling predicted increased water savings from raintanks compared to greywater systems alone, with raintanks providing the additional benefit of reduced peak stormwater flows at the allotment scale. Rainwater and stormwater reuse from stormwater ponds within the catchments was found to provide the highest reduction in nutrient discharge from the case study areas. Environment ACT amended planning controls to facilitate installation of raintanks and greywater systems, and commenced a Government funded rebate scheme for raintanks as a result of this study

Remotely triggered scaffolds for controlled release of pharmaceuticals

Fe3O4-Au hybrid nanoparticles (HNPs) have shown increasing potential for biomedical applications such as image guided stimuli responsive drug delivery. Incorporation of the unique properties of HNPs into thermally responsive scaffolds holds great potential for future biomedical applications. Here we successfully fabricated smart scaffolds based on thermo-responsive poly(N-isopropylacrylamide) (pNiPAM). Nanoparticles providing localized trigger of heating when irradiated with a short laser burst were found to give rise to remote control of bulk polymer shrinkage. Gold-coated iron oxide nanoparticles were synthesized using wet chemical precipitation methods followed by electrochemical coating. After subsequent functionalization of particles with allyl methyl sulfide, mercaptodecane, cysteamine and poly(ethylene glycol) thiol to enhance stability, detailed biological safety was determined using live/dead staining and cell membrane integrity studies through lactate dehydrogenase (LDH) quantification. The PEG coated HNPs did not show significant cytotoxic effect or adverse cellular response on exposure to 7F2 cells (p < 0.05) and were carried forward for scaffold incorporation. The pNiPAM-HNP composite scaffolds were investigated for their potential as thermally triggered systems using a Q-switched Nd:YAG laser. These studies show that incorporation of HNPs resulted in scaffold deformation after very short irradiation times (seconds) due to internal structural heating. Our data highlights the potential of these hybrid-scaffold constructs for exploitation in drug delivery, using methylene blue as a model drug being released during remote structural change of the scaffold

The physiological cost of wearing the propellant handler's ensemble at the Kennedy Space Center

The potential for exposure to toxins used in the propulsion systems of spacecraft dictates the use of a whole body protective suit, the Propellant Handler's Ensemble (PHE) during preflight preparation and launching. The weight, structure, and operating parameters of the PHE may be expected to have a significant impact upon the metabolic, cardiovascular, and thermal responses of the user, especially during ambient temperature extremes and high workload situations. Four male subjects participated in tests in -7, 23, and 43 C (20, 74, and 110 F) environments in two versions of the PHE, the autonomous backpack (BP) and the hoseline (HL) supplied configuration. Measurements included heart rate (HR) rectal temperature, four skin temperatures, oxygen (O2), and carbon dioxide (CO2) in the helmet area, interior suit temperature, and suit pressure. Exercise metabolism was estimated from HR, PHE weight, and treadmill speed and grade. The HR responses between each PHE configuration were not statistically different. As a percentage of HR maximum, the mean values were 79 percent (COLD), 84 percent (LAB), and 90 percent (HOT). Helmet O2 and CO2 levels were correlated with percent HR max (P less than 0.001). Rectal temperatures were similar for each PHE configuration, except in the HOT exposure where the BP version exceeded the HL configuration (P less than 0.05). In nearly every instance the HR was driven to moderately high levels, the supplied respiratory gases were not optimum, and thermal adversity was a primary stressor. Our findings suggest that medical and physical fitness standards, along with operational restrictions, should be imposed upon PHE users to avoid situations that could adversely affect the worker

Competence, specification and induction of Pax-3 in the trigeminal placode

Placodes are discrete regions of thickened ectoderm that contribute extensively to the peripheral nervous system in the vertebrate head. The paired-domain transcription factor Pax-3 is an early molecular marker for the avian ophthalmic trigeminal (opV) placode, which forms sensory neurons in the ophthalmic lobe of the trigeminal ganglion. Here, we use collagen gel cultures and heterotopic quail-chick grafts to examine the competence, specification and induction of Pax-3 in the opV placode. At the 3-somite stage, the whole head ectoderm rostral to the first somite is competent to express Pax-3 when grafted to the opV placode region, though competence is rapidly lost thereafter in otic-level ectoderm. Pax-3 specification in presumptive opV placode ectoderm occurs by the 8-somite stage, concomitant with robust Pax-3 expression. From the 8-somite stage onwards, significant numbers of cells are committed to express Pax-3. The entire length of the neural tube has the ability to induce Pax-3 expression in competent head ectoderm and the inductive interaction is direct. We propose a detailed model for Pax-3 induction in the opV placode

Off with their heads: Terrorism and electoral support for capital punishment in Australia

Recent terrorist attacks such as the attacks on the World Trade Centre in September 2001 have generated new interest in the debate on capital punishment. It has been suggested that support for the death penalty could be higher in the wake of terrorist activity. Using data from the Australian Election Study we investigate voters' attitudes towards capital punishment. Paradoxically, overall support for the death penalty at the 2001 Federal election was lower than at previous elections. In this paper we utilise both simultaneous binary probit and treatment effects models to model the determinants of those attitudes and to investigate the impact of terrorism on support for the death penalty at the 2001 Federal election. In particular, we address the question of whether voters who felt terrorism was an important issue had higher levels of support for the death penalty than voters who did not feel that terrorism was importantsimultaneous binary probit, treatment effects models

Microstructure and growth of the lenses of schizochroal trilobite eyes

Lenses within the schizochroal eyes of phacopine trilobites are made principally of calcite and characterisation of them using light microscopy and high-resolution electron imaging and diffraction has revealed an array of microstructural arrangements that suggest a common original pattern across the suborder. The low convexity lenses of Odontochile hausmanni and Dalmanites sp. contain calcite fibres termed trabeculae. The c axis of trabecular calcite lies parallel to the lens axis, and adjacent trabeculae are distinguished by small differences in their a axis orientations. Despite the common alignment, the boundaries between trabeculae cross-cut the c axis as they fan out towards the lens base. Trabeculae are absent from the lens immediately beneath the visual surface and instead a radial fringe is present and is composed of micrometre-thick sheets of calcite whose c axes are oriented at a low angle to the visual surface. High convexity lenses are more common than those of lower convexity among the species studied, and they have a much thicker radial fringe. Beneath this fringe all of the lens calcite is oriented with its c axis parallel to the lens axis and it lacks trabeculae. We propose that both the high and low convexity lenses formed by rapid growth of calcite from a surface that migrated inwards from the cornea, and they may have had an amorphous calcium carbonate precursor. The trabeculae and radial fringes are unlikely to have had any beneficial effect on the transmission or focusing of light but rather are the outcomes of an elegant solution to the problem of how to construct a biconvex lens from a crystalline solid