4,592 research outputs found
Spelter Pan - Design, Heating Systems and Operations
This is decided by the shape of article to be galvanized. It should be possible to immerse and withdraw articles without much agitation of the bath. The pans for wire, tube, strip, fasteners, have suitable designs to take care of this factor
Probing large distance higher dimensional gravity from lensing data
The modifications induced in the standard weak-lensing formula if Newtonian
gravity differs from inverse square law at large distances are studied. The
possibility of putting bounds on the mass of gravitons from lensing data is
explored. A bound on graviton mass, esitmated to be about 100 Mpc is
obtained from analysis of some recent data on gravitational lensing.Comment: 6 pages, 1 figure, added reference
Study of one-dimensional nature of (Sr,Ba)_2Cu(PO_4)_2 and BaCuP_2O_7 via 31P NMR
The magnetic behavior of the low-dimensional phosphates (Sr,Ba)_2 Cu(PO_4)_2
and BaCuP_2O_7 was investigated by means of magnetic susceptibility and ^{31}P
nuclear magnetic resonance (NMR) measurements. We present here the NMR shift
K(T), the spin-lattice 1/T_1 and spin-spin 1/T_2 relaxation-rate data over a
wide temperature range 0.02 K < T < 300 K. The T-dependence of the NMR K(T) is
well described by the S=1/2 Heisenberg antiferromagnetic chain model with an
intrachain exchange of J/k_B = 165 K, 151 K, and 108 K in Sr_2Cu(PO_4)_2,
Ba_2Cu(PO_4)_2, and BaCuP_2O_7, respectively. Our measurements suggest the
presence of magnetic ordering at 0.8 K in BaCuP_2O_7 (J/k_B = 108 K). For all
the samples, we find that 1/T_1 is nearly T-independent at low-temperatures (1
K < T < 10 K), which is theoretically expected for 1D chains when relaxation is
dominated by fluctuations of the staggered susceptibility. At high
temperatures, 1/T_1 varies nearly linearly with temperature
Detection of early osteogenic commitment in primary cells using Raman spectroscopy
Major challenges in the development of novel implant surfaces for artificial joints include osteoblast heterogeneity and the lack of a simple and sensitive in vitro assay to measure early osteogenic responses. Raman spectroscopy is a label-free, non-invasive and non-destructive vibrational fingerprinting optical technique that is increasingly being applied to detect biochemical changes in cells. In this study Raman spectroscopy has been used to obtain bone cell-specific spectral signatures and to identify any changes therein during osteoblast commitment and differentiation of primary cells in culture. Murine calvarial osteoblasts (COBs) were extracted and cultured and studied by Raman spectroscopy over a 14 day culture period. Distinct osteogenic Raman spectra were identified after 3 days of culture with strong bands detected for mineral: phosphate ν3 (1030 cm−1) and B-type carbonate (1072 cm−1), DNA (782 cm−1) and collagen matrix (CH2 deformation at 1450 cm−1) and weaker phosphate bands (948 and 970 cm−1). Early changes were detected by Raman spectroscopy compared to a standard enzymatic alkaline phosphatase (ALP) assay and gene expression analyses over this period. Proliferation of COBs was confirmed by fluorescence intensity measurements using the Picogreen dsDNA reagent. Changes in ALP levels were evident only after 14 days of culture and mRNA expression levels for ALP, Col1a1 and Sclerostin remained constant during the culture period. Sirius red staining for collagen deposition also revealed little change until day 14. In contrast Raman spectroscopy revealed the presence of amorphous calcium phosphate (945–952 cm−1) and carbonated apatite (957–962 cm−1) after only 3 days in culture and octacalcium phosphate (970 cm−1) considered a transient mineral phase, was detected after 5 days of COBs culture. PCA analysis confirmed clear separation between time-points. This study highlights the potential of Raman spectroscopy to be utilised for the early and specific detection of proliferation and differentiation changes in primary cultures of bone cells
31P NMR study of Na2CuP2O7: a S=1/2 two-dimensional Heisenberg antiferromagnetic system
The magnetic properties of Na2CuP2O7 were investigated by means of 31P
nuclear magnetic resonance (NMR), magnetic susceptibility, and heat capacity
measurements. We report the 31P NMR shift, the spin-lattice 1/T1, and spin-spin
1/T2 relaxation-rate data as a function of temperature T.
The temperature dependence of the NMR shift K(T) is well described by the
S=1/2 square lattice Heisenberg antiferromagnetic (HAF) model with an
intraplanar exchange of J/k_B \simeq 18\pm2 K and a hyperfine coupling A =
(3533\pm185) Oe/mu_B. The 31P NMR spectrum was found to broaden abruptly below
T \sim 10 K signifying some kind of transition. However, no anomaly was noticed
in the bulk susceptibility data down to 1.8 K. The heat capacity appears to
have a weak maximum around 10 K. With decrease in temperatures, the
spin-lattice relaxation rate 1/T1 decreases monotonically and appears to agree
well with the high temperature series expansion expression for a S = 1/2 2D
square lattice.Comment: 12 pages, 8 figures, submitted to J. Phys.: Cond. Ma
Possible spin-orbit driven spin-liquid ground state in the double perovskite phase of Ba3YIr2O9
We report the structural transformation of hexagonal Ba3YIr2O9 to a cubic
double perovskite form (stable in ambient conditions) under an applied pressure
of 8GPa at 1273K. While the ambient pressure (AP) synthesized sample undergoes
long-range magnetic ordering at 4K, the high pressure(HP) synthesized sample
does not order down to 2K as evidenced from our susceptibility, heat capacity
and nuclear magnetic resonance (NMR) measurements. Further, for the HP sample,
our heat capacity data have the form gamma*T+beta*T3 in the temperature (T)
range of 2-10K with the Sommerfeld coefficient gamma=10mJ/mol-Ir K2. The 89Y
NMR shift has no T-dependence in the range of 4-120K and its spin-lattice
relaxation rate varies linearly with T in the range of 8-45K (above which it is
T-independent). Resistance measurements of both the samples confirm that they
are semiconducting. Our data provide evidence for the formation of a 5d based,
gapless, quantum spin-liquid (QSL) in the cubic (HP) phase of Ba3YIr2O9. In
this picture, the T term in the heat capacity and the linear variation of 89Y
1/T1 arises from excitations out of a spinon Fermi surface. Our findings lend
credence to the theoretical suggestion [G. Chen, R. Pereira, and L. Balents,
Phys. Rev. B 82, 174440 (2010)] that strong spin-orbit coupling can enhance
quantum fluctuations and lead to a QSL state in the double perovskite lattice.Comment: 6 pages 5 figure
- …