Computationally Aided Design of a High-Performance Organic Semiconductor: The Development of a Universal Crystal Engineering Core

Herein, we describe the design and synthesis of a suite of molecules based on a benzodithiophene “universal crystal engineering core”. After computationally screening derivatives, a trialkylsilylethyne-based crystal engineering strategy was employed to tailor the crystal packing for use as the active material in an organic field-effect transistor. Electronic structure calculations were undertaken to reveal derivatives that exhibit exceptional potential for high-efficiency hole transport. The promising theoretical properties are reflected in the preliminary device results, with the computationally optimized material showing simple solution processing, enhanced stability, and a maximum hole mobility of 1.6 cm2 V−1 s−1

A kilometer-scale asteroid inside Venus's orbit

Near-Earth asteroid population models predict the existence of asteroids located inside the orbit of Venus. However, despite searches up to the end of 2019, none have been found. Here we report the discovery by the Zwicky Transient Facility of the first known asteroid located inside of Venus' orbit, 2020 AV₂, possessing an aphelion distance of 0.65 au and ∼2 km in size. While it is possible that 2020 AV₂ is the largest of its kind, we find that its discovery is surprising in the context of population models where the expected count is close to zero. If this discovery is not a statistical fluke, then 2020 AV₂ may come from a yet undiscovered source population of asteroids interior to Venus, and currently favored asteroid population models may need to be adjusted

A kilometer-scale asteroid inside Venus's orbit

Near-Earth asteroid population models predict the existence of asteroids located inside the orbit of Venus. However, despite searches up to the end of 2019, none have been found. Here we report the discovery by the Zwicky Transient Facility of the first known asteroid located inside of Venus' orbit, 2020 AV₂, possessing an aphelion distance of 0.65 au and ∼2 km in size. While it is possible that 2020 AV₂ is the largest of its kind, we find that its discovery is surprising in the context of population models where the expected count is close to zero. If this discovery is not a statistical fluke, then 2020 AV₂ may come from a yet undiscovered source population of asteroids interior to Venus, and currently favored asteroid population models may need to be adjusted

Initial Visible and Mid-IR Characterization of P/2019 LD₂ (ATLAS), an Active Transitioning Centaur Among the Trojans, with Hubble, Spitzer, ZTF, Keck, APO and GROWTH Imaging and Spectroscopy

We present visible and mid-infrared imagery and photometry of Jovian co-orbital comet P/2019 LD₂ (ATLAS) taken with Hubble Space Telescope/WFC3 on 2020 April 1, Spitzer Space Telescope/IRAC on 2020 January 25, Zwicky Transient Facility between 2019 April 9 and 2019 Nov 8 and the GROWTH telescope network from 2020 May to July, as well as visible spectroscopy from Keck/LRIS on 2020 August 19. Our observations indicate that LD₂ has a nucleus with radius 0.2-1.8 km assuming a 0.08 albedo and that the coma is dominated by ∼100 μ m-scale dust ejected at ∼1 m/s speeds with a ∼1" jet pointing in the SW direction. LD₂ experienced a total dust mass loss of ∼10⁸ kg and dust mass loss rate of ∼6 kg/s with Afρ/cross-section varying between ∼85 cm/125 km² and ∼200 cm/310 km² between 2019 April 9 and 2019 Nov 8. If the Afρ/cross-section increase remained constant, it implies that LD₂ has remained active since ∼2018 November when it came within 4.8 au of the Sun, a typical distance for comets to begin sublimation of H₂O. From our 4.5 μm Spitzer observations, we set a limit on CO/CO₂ gas production of ∼10²⁷/∼10²⁶ mol/s. Multiple bandpass photometry of LD₂ taken by the GROWTH network measured in a 10,000 km aperture provide color measurements of g-r = 0.59±0.03, r-i = 0.18±0.05, and i-z = 0.01±0.07, colors typical of comets. We set a spectroscopic upper limit to the production of H₂O gas of ∼80 kg/s. Improving the orbital solution for LD₂ with our observations, we determine that the long-term orbit of LD₂ is that of a typical Jupiter Family Comet having close encounters with Jupiter coming within ∼0.5 Hill radius in the last ∼3 y to within 0.8 Hill radius in ∼9 y and has a 95% chance of being ejected from the Solar System in < 10 Myr

The tidal disruption event AT2021ehb: evidence of relativistic disk reflection, and rapid evolution of the disk-corona system

High Energy Astrophysic

Spectroscopic observations of progenitor activity 100 days before a Type Ibn supernova ⋆

Obtaining spectroscopic observations of the progenitors of core-collapse supernovae is often unfeasible, due to an inherent lack of knowledge as to what stars experience supernovae and when they will explode. In this Letter we present photometric and spectroscopic observations of the progenitor activity of SN 2023fyq before the He-rich progenitor explodes as a Type Ibn supernova. The progenitor of SN 2023fyq shows an exponential rise in flux prior to core collapse. Complex He i emission line features are observed in the progenitor spectra, with a P Cygni-like profile, as well as an evolving broad base with velocities of the order of 10 000 km s-1. The luminosity and evolution of SN 2023fyq is consistent with a Type Ibn, reaching a peak r-band magnitude of-18:8 mag, although there is some uncertainty regarding the distance to the host, NGC 4388, which is located in the Virgo cluster. We present additional evidence of asymmetric He-rich material being present both prior to and after the explosion of SN 2023fyq, which suggests that this material survived the ejecta interaction. Broad [O i], C i, and the Ca ii triplet lines are observed at late phases, confirming that SN 2023fyq was a genuine supernova, rather than a non-Terminal interacting transient. SN 2023fyq provides insight into the final moments of a massive star's life, demonstrating that the progenitor is likely highly unstable before core collapse