Nanoshearing - Collective carbon nanotube micromechanics

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In situ characterization of vertically oriented carbon nanofibers for three-dimensional nano-electro-mechanical device applications

We have performed mechanical and electrical characterization of individual as-grown, vertically oriented carbon nanofibers (CNFs) using in situ techniques, where such high-aspect-ratio, nanoscale structures are of interest for three-dimensional (3D) electronics, in particular 3D nano-electro-mechanical-systems (NEMS). Nanoindentation and uniaxial compression tests conducted in an in situ nanomechanical instrument, SEMentor, suggest that the CNFs undergo severe bending prior to fracture, which always occurs close to the bottom rather than at the substrate–tube interface, suggesting that the CNFs are well adhered to the substrate. This is also consistent with bending tests on individual tubes which indicated that bending angles as large as ~70° could be accommodated elastically. In situ electrical transport measurements revealed that the CNFs grown on refractory metallic nitride buffer layers were conducting via the sidewalls, whereas those synthesized directly on Si were electrically unsuitable for low-voltage dc NEMS applications. Electrostatic actuation was also demonstrated with a nanoprobe in close proximity to a single CNF and suggests that such structures are attractive for nonvolatile memory applications. Since the magnitude of the actuation voltage is intimately dictated by the physical characteristics of the CNFs, such as diameter and length, we also addressed the ability to tune these parameters, to some extent, by adjusting the plasma-enhanced chemical vapor deposition growth parameters with this bottom-up synthesis approach

Juvenile delinquency, welfare, justice and therapeutic interventions: a global perspective

This review considers juvenile delinquency and justice from an international perspective. Youth crime is a growing concern. Many young offenders are also victims with complex needs, leading to a public health approach that requires a balance of welfare and justice models. However, around the world there are variable and inadequate legal frameworks and a lack of a specialist workforce. The UK and other high-income countries worldwide have established forensic child and adolescent psychiatry, a multifaceted discipline incorporating legal, psychiatric and developmental fields. Its adoption of an evidence-based therapeutic intervention philosophy has been associated with greater reductions in recidivism compared with punitive approaches prevalent in some countries worldwide, and it is therefore a superior approach to dealing with the problem of juvenile delinquency

Five-minute oscillation power within magnetic elements in the solar atmosphere

It has long been known that magnetic plage and sunspots are regions in which the power of acoustic waves is reduced within the photospheric layers. Recent observations now suggest that this suppression of power extends into the low chromosphere and is also present in small magnetic elements far from active regions. In this paper we investigate the observed power suppression in plage and magnetic elements, by modeling each as a collection of vertically aligned magnetic fibrils and presuming that the velocity within each fibril is the response to buffeting by incident p modes in the surrounding field-free atmosphere. We restrict our attention to modeling observations made near the solar disk center, where the line-of-sight velocity is nearly vertical and hence, only the longitudinal component of the motion within the fibril contributes. Therefore, we only consider the excitation of axisymmetric sausage waves and ignore kink oscillations as their motions are primarily horizontal. We compare the vertical motion within the fibril with the vertical motion of the incident p mode by constructing the ratio of their powers. In agreement with observational measurements we find that the total power is suppressed within strong magnetic elements for frequencies below the acoustic cut-off frequency. However, further physical effects need to be examined for understanding the observed power ratios for stronger magnetic field strengths and higher frequencies. We also find that the magnitude of the power deficit increases with the height above the photosphere at which the measurement is made. Furthermore, we argue that the area of the solar disk over which the power suppression extends increases as a function of height

Catastrophic vs Gradual Collapse of Thin-Walled Nanocrystalline Ni Hollow Cylinders As Building Blocks of Microlattice Structures

Lightweight yet stiff and strong lattice structures are attractive for various engineering applications, such as cores of sandwich shells and components designed for impact mitigation. Recent breakthroughs in manufacturing enable efficient fabrication of hierarchically architected microlattices, with dimensional control spanning seven orders of magnitude in length scale. These materials have the potential to exploit desirable nanoscale-size effects in a macroscopic structure, as long as their mechanical behavior at each appropriate scale – nano, micro, and macro levels – is properly understood. In this letter, we report the nanomechanical response of individual microlattice members. We show that hollow nanocrystalline Ni cylinders differing only in wall thicknesses, 500 and 150 nm, exhibit strikingly different collapse modes: the 500 nm sample collapses in a brittle manner, via a single strain burst, while the 150 nm sample shows a gradual collapse, via a series of small and discrete strain bursts. Further, compressive strength in 150 nm sample is 99.2% lower than predicted by shell buckling theory, likely due to localized buckling and fracture events observed during in situ compression experiments. We attribute this difference to the size-induced transition in deformation behavior, unique to nanoscale, and discuss it in the framework of “size effects” in crystalline strength

In situ Mechanical Testing Reveals Periodic Buckle Nucleation and Propagation in Carbon Nanotube Bundles

Uniaxial compression studies are performed on 50-µm-diameter bundles of nominally vertical, intertwined carbon nanotubes grown via chemical vapor deposition from a photolithographically defined catalyst. The inhomogeneous microstructure is examined, demonstrating density and tube orientation gradients, believed to play a role in the unique periodic buckling deformation mechanism. Through in situ uniaxial compression experiments it is discovered that the characteristic bottom-to-top sequential buckling proceeds by first nucleating on the bundle surface and subsequently propagating laterally through the bundle, gradually collapsing the entire structure. The effects of strain rate are explored, and storage and loss stiffnesses are analyzed in the context of energy dissipation

Identification And Characterization Of A Second Encephalitogenic Determinant Of Myelin Proteolipid Protein (Residues 178-191) For SJL Mice

We previously described a synthetic peptide of myelin proteolipid protein (PLP), peptide 139-151, which induces experimental allergic encephalomyelitis in SJL/J (H-2s) mice. We have now identified an additional determinant, PLP residues 178-191, that is also a potent encephalitogen in this strain. When PLP peptide 178-191 was compared with peptide 139-151 on an equimolar basis, the day of onset of disease induced by PLP 178-191 was earlier, but the incidence, severity, and histologic features were indistinguishable. Lymph node cells from animals immunized with the whole PLP molecule responded to both PLP 178-191 and 139-151, suggesting immunologic codominance of the two epitopes. PLP 178-191 elicited stronger proliferative responses and this may relate to the earlier onset of disease induced with this peptide. Two CD4+, peptide-specific, I-A(s)-restricted T cell lines, selected by stimulation of lymph node cells with either PLP 178-191 or 139-151, were each encephalitogenic in naive syngeneic mice. The presence of multiple encephalitogenic codominant PLP epitopes within a single mouse strain emphasizes the complexity of the immune response to PLP and its potential as a target Ag in autoimmune demyelinating diseases

CARMA: A platform for analyzing microarray datasets that incorporate replicate measures

BACKGROUND: The incorporation of statistical models that account for experimental variability provides a necessary framework for the interpretation of microarray data. A robust experimental design coupled with an analysis of variance (ANOVA) incorporating a model that accounts for known sources of experimental variability can significantly improve the determination of differences in gene expression and estimations of their significance. RESULTS: To realize the full benefits of performing analysis of variance on microarray data we have developed CARMA, a microarray analysis platform that reads data files generated by most microarray image processing software packages, performs ANOVA using a user-defined linear model, and produces easily interpretable graphical and numeric results. No pre-processing of the data is required and user-specified parameters control most aspects of the analysis including statistical significance criterion. The software also performs location and intensity dependent lowess normalization, automatic outlier detection and removal, and accommodates missing data. CONCLUSION: CARMA provides a clear quantitative and statistical characterization of each measured gene that can be used to assess marginally acceptable measures and improve confidence in the interpretation of microarray results. Overall, applying CARMA to microarray datasets incorporating repeated measures effectively reduces the number of gene incorrectly identified as differentially expressed and results in a more robust and reliable analysis

Behavioral fingerprinting: Acceleration sensors for identifying changes in livestock health

During disease or toxin challenges, the behavioral activities of grazing animals alter in response to adverse situations, potentially providing an indicator of their welfare status. Behavioral changes such as feeding behavior, rumination and physical behavior as well as expressive behavior, can serve as indicators of animal health and welfare. Sometimes behavioral changes are subtle and occur gradually, often missed by infrequent visual monitoring until the condition becomes acute. There is growing popularity in the use of sensors for monitoring animal health. Acceleration sensors have been designed to attach to ears, jaws, noses, collars and legs to detect the behavioral changes of cattle and sheep. So far, some automated acceleration sensors with high accuracies have been found to have the capacity to remotely monitor the behavioral patterns of cattle and sheep. These acceleration sensors have the potential to identify behavioral patterns of farm animals for monitoring changes in behavior which can indicate a deterioration in health. Here, we review the current automated accelerometer systems and the evidence they can detect behavioral patterns of animals for the application of potential directions and future solutions for automatically monitoring and the early detection of health concerns in grazing animals