Model-Invariant Hybrid RANS-LES Computations on Unstructured Meshes

Hybrid RANS-LES computations combine the bene ts of RANS and LES so that LES is used in regions where the accuracy of RANS deteriorates. The numerous hybrid approaches are limited by the speci cation of the LES-RANS interface, which can cause nonphysical results such as log-layer mismatch and low shear stress. The hybrid RANS-LES approach based on the concept of model invariance, mitigates these problems, enabling seamless blending of the RANS and LES regions while forming the basis for interpreting the results in the interface region. This hybrid formulation was implemented in the NASA FUN3D unstructured code and computations for ow in a channel at Reynolds number of 3300 (based on the channel half width h and the bulk in ow velocity u(infinity) were carried out. An isotropic stochastic turbulence generator was implemented to generate in ow turbulence. The present approach was able to eliminate the log-layer mismatch and predict the shear stress fairly well. Thus, the model-invariant hybrid formulation coupled with the isotropic turbulence in ow generation serves as a physically meaningful way of performing hybrid RANS-LES computations

The local adsorption structure of benzene on Si(001)-(2 × 1): a photoelectron diffraction investigation

Scanned-energy mode C 1s photoelectron diffraction has been used to investigate the local adsorption geometry of benzene on Si(001) at saturation coverage and room temperature. The results show that two different local bonding geometries coexist, namely the 'standard butterfly' (SB) and 'tilted bridge' (TB) forms, with a composition of 58 ± 29% of the SB species. Detailed structural parameter values are presented for both species including Si–C bond lengths. On the basis of published measurements of the rate of conversion of the SB to the TB form on this surface, we estimate that the timescale of our experiment is sufficient for achieving equilibrium, and in this case our results indicate that the difference in the Gibbs free energy of adsorption, ΔG(TB)−ΔG(SB), is in the range −0.023 to +0.049 eV. We suggest, however, that the relative concentration of the two species may also be influenced by a combination of steric effects influencing the kinetics, and a sensitivity of the adsorption energies of the adsorbed SB and TB forms to the nature of the surrounding benzene molecules

The (2√3×3)rect. phase of alkylthiolate self-assembled monolayers on Au(111): a symmetry-constrained structural solution

Low-energy electron-diffraction (LEED) patterns of the Au(111)(2√3×3)rect.-butylthiolate surface phase (a structure also seen in longer alkane chain thiolate self-assembled monolayers) show missing diffracted beams characteristic of glide symmetry, but do not show the larger set of missing beams found in surface x-ray diffraction (SXRD). The difference can be attributed to the greatly enhanced role of multiple scattering in LEED, but the combination of symmetry constraints placed on possible structural models by the observed SXRD and LEED beam extinctions greatly reduces the number of possible structural models. Only three such models are identified, one of which is clearly incompatible with other published experimental data. The relative merits of the remaining models, both involving Au adatom-thiolate moieties, are discussed in the light of the results of previous experimental studies

Profile of Internet Gamblers: Betting on the Future

The commercial casino industry in 2002 provided more jobs, higher wages, and more tax revenues to states and local communities than ever before. At the same time Internet gambling sites operated by offshore companies have seen explosive growth since the introduction of the World Wide Web in 1995 (Rose, 2003). This research developed profiles of current land based casino patrons who have gambled on the Internet, those who have not but are willing to try, and those who have not and would not in the future consider Internet gambling. Two hundred surveys were collected at two Detroit, Michigan casinos, asking questions varying from demographic information to gambling experience, and the willingness to try new things. The conceptual framework for this project was based on Roger\u27s Diffusion of Innovation Theory, and Forsythe and Bailey\u27s Perceived Time Poverty Model. Income, education, marital status, prior Internet purchasing and online banking experiences have a significant impact on past behaviors and future intentions regarding Internet gambling. Hours of Internet usage had more of an impact on behaviors than the issue of accessibility