1,457 research outputs found
Huge Seebeck coefficients in non-aqueous electrolytes
The Seeebeck coefficients of the non-aqueous electrolytes tetrabutylammonium
nitrate, tetraoctylphosphonium bromide and tetradodecylammonium nitrate in
1-octanol, 1-dodecanol and ethylene-glycol are measured in a temperature range
from T=30 to T=45 C. The Seebeck coefficient is generally of the order of a few
hundreds of microvolts per Kelvin for aqueous solution of inorganic ions. Here
we report huge values of 7 mV/K at 0.1M concentration for tetrabutylammonium
nitrate in 1-dodecanol. These striking results open the question of
unexpectedly large kosmotrope or "structure making" effects of
tetraalkylammonium ions on the structure of alcohols.Comment: Submitted to J. Chem. Phy
Thermodynamic behaviour and structural properties of an aqueous sodium chloride solution upon supercooling
We present the results of a molecular dynamics simulation study of
thermodynamic and structural properties upon supercooling of a low
concentration sodium chloride solution in TIP4P water and the comparison with
the corresponding bulk quantities. We study the isotherms and the isochores for
both the aqueous solution and bulk water. The comparison of the phase diagrams
shows that thermodynamic properties of the solution are not merely shifted with
respect to the bulk. Moreover, from the analysis of the thermodynamic curves,
both the spinodal line and the temperatures of maximum density curve can be
calculated. The spinodal line appears not to be influenced by the presence of
ions at the chosen concentration, while the temperatures of maximum density
curve displays both a mild shift in temperature and a shape modification with
respect to bulk. Signatures of the presence of a liquid-liquid critical point
are found in the aqueous solution. By analysing the water-ion radial
distribution functions of the aqueous solution we observe that upon changing
density, structural modifications appear close to the spinodal. For low
temperatures additional modifications appear also for densities close to that
corresponding to a low density configurational energy minimum.Comment: 10 pages, 13 figures, 2 tables. To be published in J. Chem. Phy
Comment on “Fracture resistance of paper”
Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/44667/1/10853_2004_Article_BF00541421.pd
The information analysis center concept as developed by the Radiation Shielding Information Center in its computer codes activities
Information analysis center concept and computer codes for calculating radiation transport, and shield design
Modified two-potential approach to tunneling problems
One-body quantum tunneling to continuum is treated via the two-potential
approach, dividing the tunneling potential into external and internal parts. We
show that corrections to this approach can be minimized by taking the
separation radius inside the interval determined by simple expressions. The
resulting two-potential approach reproduces the resonance energy and its width,
both for narrow and wide resonances. We also demonstrate that, without losing
its accuracy, the two-potential approach can be modified to a form resembling
the R-matrix theory, yet without any uncertainties of the latter related to the
choice of the matching radius.Comment: 7 two-column pages, 3 figures, extra-explanation added, Phys. Rev. A,
in pres
Spatiotemporal complexity of a ratio-dependent predator-prey system
In this paper, we investigate the emergence of a ratio-dependent
predator-prey system with Michaelis-Menten-type functional response and
reaction-diffusion. We derive the conditions for Hopf, Turing and Wave
bifurcation on a spatial domain. Furthermore, we present a theoretical analysis
of evolutionary processes that involves organisms distribution and their
interaction of spatially distributed population with local diffusion. The
results of numerical simulations reveal that the typical dynamics of population
density variation is the formation of isolated groups, i.e., stripelike or
spotted or coexistence of both. Our study shows that the spatially extended
model has not only more complex dynamic patterns in the space, but also chaos
and spiral waves. It may help us better understand the dynamics of an aquatic
community in a real marine environment.Comment: 6pages, revtex
Critical view of WKB decay widths
A detailed comparison of the expressions for the decay widths obtained within
the semiclassical WKB approximation using different approaches to the tunneling
problem is performed. The differences between the available improved formulae
for tunneling near the top and the bottom of the barrier are investigated.
Though the simple WKB method gives the right order of magnitude of the decay
widths, a small number of parameters are often fitted. The need to perform the
fitting procedure remaining consistently within the WKB framework is emphasized
in the context of the fission model based calculations. Calculations for the
decay widths of some recently found super heavy nuclei using microscopic
alpha-nucleus potentials are presented to demonstrate the importance of a
consistent WKB calculation. The half-lives are found to be sensitive to the
density dependence of the nucleon-nucleon interaction and the implementation of
the Bohr-Sommerfeld quantization condition inherent in the WKB approach.Comment: 18 pages, Late
Chaos induced coherence in two independent food chains
Coherence evolution of two food web models can be obtained under the stirring
effect of chaotic advection. Each food web model sustains a three--level
trophic system composed of interacting predators, consumers and vegetation.
These populations compete for a common limiting resource in open flows with
chaotic advection dynamics. Here we show that two species (the top--predators)
of different colonies chaotically advected by a jet--like flow can synchronize
their evolution even without migration interaction. The evolution is
charaterized as a phase synchronization. The phase differences (determined
through the Hilbert transform) of the variables representing those species show
a coherent evolution.Comment: 5 pages, 5 eps figures. Accepted for publication in Phys. Rev.
Stochastic models in population biology and their deterministic analogs
In this paper we introduce a class of stochastic population models based on
"patch dynamics". The size of the patch may be varied, and this allows one to
quantify the departures of these stochastic models from various mean field
theories, which are generally valid as the patch size becomes very large. These
models may be used to formulate a broad range of biological processes in both
spatial and non-spatial contexts. Here, we concentrate on two-species
competition. We present both a mathematical analysis of the patch model, in
which we derive the precise form of the competition mean field equations (and
their first order corrections in the non-spatial case), and simulation results.
These mean field equations differ, in some important ways, from those which are
normally written down on phenomenological grounds. Our general conclusion is
that mean field theory is more robust for spatial models than for a single
isolated patch. This is due to the dilution of stochastic effects in a spatial
setting resulting from repeated rescue events mediated by inter-patch
diffusion. However, discrete effects due to modest patch sizes lead to striking
deviations from mean field theory even in a spatial setting.Comment: 47 pages, 9 figure
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