The clumpiness of molecular clouds: HCO+ (3--2) survey near Herbig-Haro objects

Some well-studied Herbig Haro objects have associated with them one or more cold, dense, and quiescent clumps of gas. We propose that such clumps near an HH object can be used as a general measure of clumpiness in the molecular cloud that contains that HH object. Our aim is to make a survey of clumps around a sample of HH objects, and to use the results to make an estimate of the clumpiness in molecular clouds. All known cold, dense, and quiescent clumps near HH objects are anomalously strong HCO+ emitters. Our method is, therefore, to search for strong HCO+ emission as an indicator of a clump near to an HH object. The searches were made using JCMT and SEST in the HCO+ 3-2 and also H13CO+ 1-0 lines, with some additional searches for methanol and sulphur monoxide lines. The sources selected were a sample of 22 HH objects in which no previous HCO+ emission had been detected. We find that half of the HH objects have clumps detected in the HCO+ 3-2 line and that all searches in H13CO$+ 1-0 lines show evidence of clumpiness. All condensations have narrow linewidths and are evidently unaffected dynamically by the HH jet shock. We conclude that the molecular clouds in which these HH objects are found must be highly heterogeneous on scales of less than 0.1 pc. An approximate calculation based on these results suggests that the area filling factor of clumps affected by HH objects is on the order of 10%. These clumps have gas number densities larger than 3e4 cm-2.Comment: 11 pages, 14 figures. Accepted for publication in Astronomy and Astrophysic

Urban form strongly mediates the allometric scaling of airshed pollution concentrations

We present allometric-scaling relationships between non-point-source emissions of air pollutants and settlement population, using 3030 urban settlements in Great Britain (home to ca. 80% of the population of that region). Sub-linear scalings (slope  0.6) were found for the oxides of nitrogen (NO _x ) and microscopic airborne particles (PM _10  and PM _2.5 ). That is, emissions of these pollutants from larger cities are lower per capita than would be expected when compared to the same population dispersed in smaller settlements. The scalings of traffic-related emissions are disaggregated into a component due to under-use of roads in small settlements and a fraction due to congestion in large settlements. We use these scalings of emissions, along with a scaling related to urban form, to explain quantitatively how and why urban airshed-average air pollutant concentrations also scale with population. Our predicted concentration scaling with population is strongly sub-linear, with a slope about half that of the emissions scaling, consistent with satellite measurements of NO _2  columns over large cities across Europe. We demonstrate that the urban form of a particular settlement can result in the airshed-average air pollution of that settlement being much larger or smaller than expected. We extend our analysis to predict that the likelihood of occurrence of local air pollution hotspots will scale super-linearly with population, a testable hypothesis that awaits suitable data. Our analysis suggests that coordinated management of emissions and urban form would strongly reduce the likelihood of local pollutant hotspots occurring whilst also ameliorating the urban heat island effect under climate change

Air Pollution Exposure Assessment for Epidemiologic Studies of Pregnant Women and Children: Lessons Learned from the Centers for Children’s Environmental Health and Disease Prevention Research

The National Children’s Study is considering a wide spectrum of airborne pollutants that are hypothesized to potentially influence pregnancy outcomes, neurodevelopment, asthma, atopy, immune development, obesity, and pubertal development. In this article we summarize six applicable exposure assessment lessons learned from the Centers for Children’s Environmental Health and Disease Prevention Research that may enhance the National Children’s Study: a) Selecting individual study subjects with a wide range of pollution exposure profiles maximizes spatial-scale exposure contrasts for key pollutants of study interest. b) In studies with large sample sizes, long duration, and diverse outcomes and exposures, exposure assessment efforts should rely on modeling to provide estimates for the entire cohort, supported by subject-derived questionnaire data. c) Assessment of some exposures of interest requires individual measurements of exposures using snapshots of personal and microenvironmental exposures over short periods and/or in selected microenvironments. d) Understanding issues of spatial–temporal correlations of air pollutants, the surrogacy of specific pollutants for components of the complex mixture, and the exposure misclassification inherent in exposure estimates is critical in analysis and interpretation. e) “Usual” temporal, spatial, and physical patterns of activity can be used as modifiers of the exposure/outcome relationships. f) Biomarkers of exposure are useful for evaluation of specific exposures that have multiple routes of exposure. If these lessons are applied, the National Children’s Study offers a unique opportunity to assess the adverse effects of air pollution on interrelated health outcomes during the critical early life period

Prenatal Insecticide Exposures and Birth Weight and Length among an Urban Minority Cohort

We reported previously that insecticide exposures were widespread among minority women in New York City during pregnancy and that levels of the organophosphate chlorpyrifos in umbilical cord plasma were inversely associated with birth weight and length. Here we expand analyses to include additional insecticides (the organophosphate diazinon and the carbamate propoxur), a larger sample size (n = 314 mother–newborn pairs), and insecticide measurements in maternal personal air during pregnancy as well as in umbilical cord plasma at delivery. Controlling for potential confounders, we found no association between maternal personal air insecticide levels and birth weight, length, or head circumference. For each log unit increase in cord plasma chlorpyrifos levels, birth weight decreased by 42.6 g [95% confidence interval (CI), −81.8 to −3.8, p = 0.03] and birth length decreased by 0.24 cm (95% CI, −0.47 to −0.01, p = 0.04). Combined measures of (ln)cord plasma chlorpyrifos and diazinon (adjusted for relative potency) were also inversely associated with birth weight and length (p < 0.05). Birth weight averaged 186.3 g less (95% CI, −375.2 to −45.5) among newborns with the highest compared with lowest 26% of exposure levels (p = 0.01). Further, the associations between birth weight and length and cord plasma chlorpyrifos and diazinon were highly significant (p ≤ 0.007) among newborns born before the 2000–2001 U.S. Environmental Protection Agency’s regulatory actions to phase out residential use of these insecticides. Among newborns born after January 2001, exposure levels were substantially lower, and no association with fetal growth was apparent (p > 0.8). The propoxur metabolite 2-isopropoxyphenol in cord plasma was inversely associated with birth length, a finding of borderline significance (p = 0.05) after controlling for chlorpyrifos and diazinon. Results indicate that prenatal chlorpyrifos exposures have impaired fetal growth among this minority cohort and that diazinon exposures may have contributed to the effects. Findings support recent regulatory action to phase out residential uses of the insecticides

Pesticide exposures in a malarious and predominantly farming area in Central Ghana

In areas where malaria is endemic, pesticides are widely deployed for vector control, which has contributed to reductions in malaria deaths. Pesticide use for agrarian purposes reduces pest populations, thus improving crop production and post-harvest losses. However, adverse health effects have been associated with pesticide exposure, ranging from skin irritation to neurotoxicity and carcinogenicity. Though misuse of these pesticides can lead to widespread potential dangers, the debilitating effects are usually underappreciated in many developing countries. To evaluate the pattern of pesticide usage among rural communities in the Kintampo area of Ghana, a cross-sectional survey was conducted among 1455 heads of households randomly sampled from among 29,073 households in the Kintampo Health and Demographic Surveillance System area of Ghana to estimate the prevalence of pesticide use and indications for use among this rural populace. Seventy-one percent (1040/1455) of household heads reported having used pesticides on either their farms or homes, most commonly for control of weeds (96.4%, 1003/1040) or insects (85.4%, 888/1040). Dichlorodiphenyltrichloroethane (DDT) was used by 22.9% (238/1040) of respondents. The majority of households who reported use of pesticides said women in their households assisted in the spraying efforts (69.3%, 721/1040); of these women, 50.8% (366/721) did so while carrying their babies on their backs. Only 28.9% (301/1040) of the study participants wore protective devices during pesticide applications. Frequent symptoms that were reported after spraying, included cough (32.3%; 336/1040), difficulty in breathing (26.7%; 278/1040) and skin irritation (39.0%; 406/1040). Pesticide use among community members in the Kintampo area of Ghana is common and its potential health impacts warrant further investigation.Key words: Pesticide, malaria, prevalence, Kintampo, dichlorodiphenyltrichloroethane