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Gravitational duality near de Sitter space

Gravitational instantons ''Lambda-instantons'' are defined here for any given value Lambda of the cosmological constant. A multiple of the Euler characteristic appears as an upper bound for the de Sitter action and as a lower bound for a family of quadratic actions. The de Sitter action itself is found to be equivalent to a simple and natural quadratic action. In this paper we also describe explicitly the reparameterization and duality invariances of gravity (in 4 dimensions) linearized about de Sitter space. A noncovariant doubling of the fields using the Hamiltonian formalism leads to first order time evolution with manifest duality symmetry. As a special case we recover the linear flat space result of Henneaux and Teitelboim by a smooth limiting process.Comment: 13 pages, no figure - v2 contains only small redactional changes (one reference added) and is essentially the published versio

Nanoscale gold pillars strengthened through dislocation starvation

It has been known for more than half a century that crystals can be made stronger by introducing defects into them, i.e., by strain-hardening. As the number of defects increases, their movement and multiplication is impeded, thus strengthening the material. In the present work we show hardening by dislocation starvation, a fundamentally different strengthening mechanism based on the elimination of defects from the crystal. We demonstrate that submicrometer sized gold crystals can be 50 times stronger than their bulk counterparts due to the elimination of defects from the crystal in the course of deformation

Size-dependent mechanical properties of molybdenum nanopillars

We report the deformation behavior of single crystalline molybdenum nanopillars in uniaxial compression, which exhibits a strong size effect called the “smaller is stronger” phenomenon. We show that higher strengths arise from the increase in the yield strength rather than through postyield strain hardening. We find the yield strength at nanoscale to depend strongly on sample size and not on the initial dislocation density, a finding strikingly different from that of the bulk metal

Mechanical characterization of solution-derived nanoparticle silver ink thin films

Mechanical properties of sintered silver nanoparticles are investigated via substrate curvature and nanoindentation methods. Substrate curvature measurements reveal that permanent microstructural changes occur during initial heating while subsequent annealing results in nearly elastic behavior of the thinner films. Thicker films were found to crack upon thermal treatment. The coefficient of thermal expansion was determined from linear slopes of curvature curves to be 1.9±0.097 ppm/°C, with elastic modulus and hardness determined via nanoindentation. Accounting for substrate effects, nanoindentation hardness and modulus remained constant for different film thicknesses and did not appear to be a function of annealing conditions. Hardness of 0.91 GPa and modulus of 110 GPa are somewhat lower than expected for a continuous nanocrystalline silver film, most likely due to porosity

Influence of Homogeneous Interfaces on the Strength of 500 nm Diameter Cu Nanopillars

Interfaces play an important role in crystalline plasticity as they affect strength and often serve as obstacles to dislocation motion. Here we investigate effects of grain and nanotwin boundaries on uniaxial strength of 500 nm diameter Cu nanopillars fabricated by e-beam lithography and electroplating. Uniaxial compression experiments reveal that strength is lowered by introducing grain boundaries and significantly rises when twin boundaries are present. Weakening is likely due to the activation of grain-boundary-mediated processes, while impeding dislocation glide can be responsible for strengthening by twin boundaries

Identification of “Kratom” (Mitragyna speciosa) Alkaloids in Commercially Available Products

“Kratom” is the common name for the botanical mitragyna speciosa. It is a tree native to Southeast Asia in which leaves contain the psychoactive alkaloids mitragynine and 7-hydroxymitragynine. Kratom is often ingested as teas, chewed, or smoked. It acts as a stimulant in small doses and as an opioid in large doses. Overdoses can result in vomiting, seizures, and death. Recently the Drug Enforcement Agency (DEA) placed Kratom on Schedule 1, but, due to public outcry, it was almost immediately removed. Eleven kratom based products were obtained from various tobacco shops, “headshops” and via the internet including: Choice brand capsule and powder, Krave brand capsule, Lucky brand powder, King Kratom and Purple Haze e-liquids with 0 mg nicotine and 12 mg nicotine, Mojo brand capsule, O.P.M.S Liquid Kratom concentrate, and a K. Kratom chocolate bar. These products and methanol extracted samples were analyzed for psychoactive alkaloids and other components using an AccuTOF Direct Analysis in Real Time Mass Spectrometry (DART-MS) and Gas Chromatography-Mass Spectrometry (GC-MS). The psychoactive alkaloids mitragynine and 7-hydroxymitragynine along with four other alkaloids, corynantheidine, corynoxine, paynantheine, and speciofoline, were identified in all 11 products. Unregulated commercial products made from kratom contain psychoactive alkaloids such as mitragynine and 7-hydroxymitragynine. They are readily available in a variety of forms and may be prone to abuse.https://scholarscompass.vcu.edu/uresposters/1246/thumbnail.jp