20 research outputs found

    Impregnation of La0.4Ce0.6O1.8–La0.4Sr0.6TiO3 as solid oxide fuel cell anode in H2S-containing fuels

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    Active anodes were fabricated via wet chemical impregnation of optimized amount of La0.4Sr0.6TiO3 (L4ST) into La0.4Ce0.6O1.8 (LDC) pre-infiltrated porous yttria-stabilized zirconia (YSZ) matrix. Impregnations of 10 wt% LDC with 16 wt% L4ST significantly improved the performance of the fuel cell from 48 mW cm 122 for pure L4ST to 161 mW cm 122 for LDC\u2013L4ST at 900 \ub0C in H2. The contribution of the pre-loaded LDC to this improvement was investigated using electrochemical impedance spectroscopy (EIS), scanning electron microscopy (SEM) as well as transmission electron microscopy (TEM). The measurement results indicated that pre-infiltrated LDC increased the activity of the anode more effectively by decreasing the total polarization resistance of the cell from 3.3 \u3a9 cm2 to 1.0 \u3a9 cm2 in humidified H2 at 900 \ub0C. More importantly, the LDC nano-deposits (<20 nm) behaved as an effective \u201cadhesive\u201d that substantially enhanced the wettability of L4ST on YSZ matrix, resulting in finer and more uniform structure of L4ST infiltrates. The LDC\u2013L4ST cells also demonstrated significantly improved performances in 0.5% H2S\u2013H2 and 0.5% H2S\u2013CH4 with higher stability than cells with pure L4ST anode.Peer reviewed: YesNRC publication: Ye
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