Actors of the common interest? The Brussels offices of the regions.

The absence of a formal place in representative democracy at EU level casts sub-national authorities more as actors of EU participatory democracy. Where they have specific interests to pursue their Brussels offices act in the same way as lobbyists, but public authorities are also capable of acting on broader interest sets. This analysis is geared to understanding variation in the extent to which the diversely constituted Brussels offices of the regions can act on a broad spectrum of civil society interests, and thus have potential as actors of European integration in connecting civil society with EU institutions. Differences in the orientation of offices towards either highly defined or broad agendas can be conceived in qualified principal-agent terms, in which the autonomy of offices to develop activities is the critical explanatory factor. This autonomy can be derived more from the structure of principals and from degrees of purpose they have than from asymmetries of power between principals and agents, which in turn can be drawn from typologies of degrees of devolved authority present in different member states. It predicts that territorial offices from member states with medium degrees of devolved authority have the greatest potential to act on a broad range of civil society oriented interests

Interactions between different selenium compounds and zinc, cadmium and mercury

In this paper, we present a polarographic study of systems containing different inorganic and organic selenium compounds (sodium selenite, sodium selenate, seleno-methionine and seleno-urea) and metal ions (Zn2+, Cd2+ Hg2+) of the 12th group of elements in the periodic table. While zinc is a trace element known to be essential for plants and animals, cadmium and mercury are exogenous elements and are harmful pollutants that accumulate during aging; selenium is also recognized as an important micronutrient and is sometimes added to the diet. Experiments investigating the interactions were carried out using polarographic techniques in unbuffered systems. The three metal cations originated complexes with different strength and solubility in the presence of selenite anions; in the presence of selenate, polarography was not able to detect formation of complexes with these metal ions, at least under the experimental conditions used: a decrease of Hg2+ ion concentration was observed. Seleno-methionine did not react with Cd2+; in the presence of Zn2+, a soluble complex with a co-ordination number 1 was formed, while, again, the concentration of Hg2+ decreased in the presence of increasing concentrations of the selenium derivative. Seleno-urea did not react with Zn2+, but formed a complex with Cd2+ with limited solubility. Finally, this ligand could not be studied with Hg2+ because of the overlapping of the reduction potentials of both the ligand and the metal cation. Overall equilibrium constants for complex formation (Kf) and the solubility product (Ksp) for poorly soluble species are also reported