19 research outputs found

    Considerations on the nature of metaphorical meaning arising from a computational treatment of metaphor interpetation

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    This paper argues that there need not be a full correspondence between source and target domains when interpreting metaphors. Instead, inference is performed in the source domain, and conclusions transferred to the target. A description of a computer system, ATT-Meta, that partially implements these ideas is provided.</p

    Considerations on the nature of metaphorical meaning arising from a computational treatment of metaphor interpetation

    No full text
    This paper argues that there need not be a full correspondence between source and target domains when interpreting metaphors. Instead, inference is performed in the source domain, and conclusions transferred to the target. A description of a computer system, ATT-Meta, that partially implements these ideas is provided.</p

    Role of Steric Hindrance in the Crystal Packing of <i>Z</i>′ = 4 Superstructure of Trimethyltin Hydroxide

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    The room-temperature crystal structure of trimethyltin hydroxide, (CH<sub>3</sub>)<sub>3</sub>SnOH, has been described by Anderson et al. [<i>Cryst. Growth Des.</i> <b>2011</b>, <i>11</i>, 820–826] as a 2<b>a</b> × 2<b>b</b> × 8<b>c</b>, 32-fold superstructure. We report a <b>a</b> × <b>b</b> × 8<b>c</b>, eight-fold superstructure with orthorhombic <i>P</i>2<sub>1</sub><i>cn</i> symmetry and <i>Z</i>′ = 4. Structured diffuse scattering observed at the positions of presumed superlattice reflections along <b>a</b>* and <b>b</b>* might have appeared as Bragg reflections in the experiment by Anderson et al. Alternatively, Anderson et al. and the present work might have studied different polymorphs of (CH<sub>3</sub>)<sub>3</sub>SnOH. Crystalline (CH<sub>3</sub>)<sub>3</sub>SnOH constitutes polymeric chains arranged parallel to <b>c</b>. In the eight-fold superstructure at 220 K, the polymeric chains possess a distorted zigzag arrangement of linked linear O–Sn–O units with bent angle at oxygen of ∼139.2°. This structure is essentially different from the 8<sub>3</sub>-helical arrangement in the published 32-fold superstructure model. The origin of the distorted zigzag structure is explained by steric hindrance between hydrogen atoms of adjacent hydroxy groups and (CH<sub>3</sub>)<sub>3</sub>Sn groups. Frustration in the packing of the chains is determined by steric hindrance between methyl groups of neighboring chains, which prevents the formation of interchain C–H···O hydrogen bonds
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