Experimental investigations on the correlations between the structure and thermal-electrochemical properties of over-discharged ternary/Si-C power batteries

© 2021 John Wiley & Sons Ltd. This is the accepted manuscript version of an article which has been published in final form at https://doi.org/10.1002/er.7274The thermal safety of power lithium-ion batteries（LIBs） has seriously affected the booming development of electric vehicles (EVs). Especially, owing to the requirement of high energy density, thermal runaway (TR) easily occurs in LIBs, resulting in a higher heat generation rate. Over-discharging is recognized as a common cause for TR. In the present research, the correlations between the structure and thermal-electrochemical properties of an over-discharged ternary/Si-C battery at room and high temperatures were investigated. The heat generation mechanisms of the batteries due to the maximum surface temperature and peak temperature difference variations during fast charging and discharging processes were investigated. Moreover, the electrochemical performances parameters of the batteries, such as voltage changing trend, discharge time, discharge capacity, internal resistance, electrochemical impedance spectroscopy (EIS) spectra, were analyzed. When the battery was discharged at 2.0C and 55°C, its maximum temperature and highest temperature difference reached 91.34°C and 13.24°C, respectively, finally resulting in a sharp decline in electrochemical performance. Furthermore, the root reasons for performance degradation and heat generation intensification of the over-discharged battery (ODB) were analyzed by scanning electron microscopy (SEM) and X-ray diffraction (XRD). The cause of the aforementioned phenomenon is due to irreversible damage of the electrode materials. This research not only reveals the relevant relationship between the thermal behavior and the microscopic structure of the over-discharged ternary/Si-C battery under various temperature conditions but also provides valuable insights for improving the safety of LIBs modules even packs.Peer reviewe

Distribution and diversity of twelve <i>Curcuma</i> species in China

<p>Genus <i>Curcuma</i> a wild species presents an important source of valuable characters for improving the cultivated <i>Curcuma</i> varieties. Based on the collected germplasms, herbariums, field surveys and other literatures, the ecogeographical diversity of Genus <i>Curcuma</i> and its potential distributions under the present and future climate are analysed by DIVA-GIS. The results indicate Genus <i>Curcuma</i> is distributed over 17 provinces in China, and particularly abundant in Guangxi and Guangdong provinces. The simulated current distributions are close to the actual distribution regions. In the future climate, the suitable areas for four <i>Curcuma</i> species will be extended, while for other three species the regions will be significantly decreased, and thus these valuable resources need protecting.</p