28,428 research outputs found
C-Cl Bond Fission, Hcl Elimination, And Secondary Radical Decomposition In The 193 Nm Photodissociation Of Allyl Chloride
The primary photodissociation dynamics of allyl chloride upon excitation at 193 nm is investigated in a crossed laser-molecular beam scattering apparatus. Tunable vacuum ultraviolet (VUV) photoionization of the products provides a unique ability to learn about the secondary reaction products of the nascent photoproducts formed. The data show evidence for four significant primary reaction channels: a previously unidentified low kinetic energy C-Cl bond fission channel producing unstable allyl radicals, an excited state C-Cl bond fission channel producing Cl atoms with high translational energy, an HCl elimination pathway releasing significant energy to product translation to HCl and its momentum-matched mass 40 partner, and an HCl elimination channel producing low kinetic energy HCl products and predominantly unstable mass 40 products. The measured branching of these primary reaction channels of [all C-Cl] : [fast C-Cl] : [slow C-Cl] : [fast HCl] : [slow HCl] : [all HCl] is 1.00: 0.971: 0.029: 0.291: 0.167: 0.458 (where fast refers to the high recoil kinetic energy channels). The high internal energy allyl radicals formed in the slow C-Cl fission pathway of allyl chloride further dissociate/isomerize, as do the unstable mass 40 products formed in the HCl elimination pathways, and these products are investigated. Photoionization efficiency (PIE) curves of the HCl product suggest that a three-centered elimination mechanism contributes significantly to an observed HCl elimination reaction. (C) 2002 American Institute of Physics
Some integral inequalities on time scales
In this paper, some new integral inequalities on time scales are presented by
using elementarily analytic methods in calculus of time scales.Comment: 8 page
Epitaxial graphene on SiC(0001): More than just honeycombs
The potential of graphene to impact the development of the next generation of
electronics has renewed interest in its growth and structure. The
graphitization of hexagonal SiC surfaces provides a viable alternative for the
synthesis of graphene, with wafer-size epitaxial graphene on SiC(0001) now
possible. Despite this recent progress, the exact nature of the graphene-SiC
interface and whether the graphene even has a semiconducting gap remain
controversial. Using scanning tunneling microscopy with functionalized tips and
density functional theory calculations, here we show that the interface is a
warped carbon sheet consisting of three-fold hexagon-pentagon-heptagon
complexes periodically inserted into the honeycomb lattice. These defects
relieve the strain between the graphene layer and the SiC substrate, while
still retaining the three-fold coordination for each carbon atom. Moreover,
these defects break the six-fold symmetry of the honeycomb, thereby naturally
inducing a gap: the calculated band structure of the interface is
semiconducting and there are two localized states near K below the Fermi level,
explaining the photoemission and carbon core-level data. Nonlinear dispersion
and a 33 meV gap are found at the Dirac point for the next layer of graphene,
providing insights into the debate over the origin of the gap in epitaxial
graphene on SiC(0001). These results indicate that the interface of the
epitaxial graphene on SiC(0001) is more than a dead buffer layer, but actively
impacts the physical and electronic properties of the subsequent graphene
layers
Topological aspect of graphene physics
Topological aspects of graphene are reviewed focusing on the massless Dirac
fermions with/without magnetic field. Doubled Dirac cones of graphene are
topologically protected by the chiral symmetry. The quantum Hall effect of the
graphene is described by the Berry connection of a manybody state by the filled
Landau levels which naturally possesses non-Abelian gauge structures. A generic
principle of the topologically non trivial states as the bulk-edge
correspondence is applied for graphene with/without magnetic field and explain
some of the characteristic boundary phenomena of graphene.Comment: 12 pages, 8 figures. Proceedings for HMF-1
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High Density Genetic Maps of Seashore Paspalum Using Genotyping-By-Sequencing and Their Relationship to The Sorghum Bicolor Genome.
As a step towards trait mapping in the halophyte seashore paspalum (Paspalum vaginatum Sw.), we developed an F1 mapping population from a cross between two genetically diverse and heterozygous accessions, 509022 and HI33. Progeny were genotyped using a genotyping-by-sequencing (GBS) approach and sequence reads were analyzed for single nucleotide polymorphisms (SNPs) using the UGbS-Flex pipeline. More markers were identified that segregated in the maternal parent (HA maps) compared to the paternal parent (AH maps), suggesting that 509022 had overall higher levels of heterozygosity than HI33. We also generated maps that consisted of markers that were heterozygous in both parents (HH maps). The AH, HA and HH maps each comprised more than 1000 markers. Markers formed 10 linkage groups, corresponding to the ten seashore paspalum chromosomes. Comparative analyses showed that each seashore paspalum chromosome was syntenic to and highly colinear with a single sorghum chromosome. Four inversions were identified, two of which were sorghum-specific while the other two were likely specific to seashore paspalum. These high-density maps are the first available genetic maps for seashore paspalum. The maps will provide a valuable tool for plant breeders and others in the Paspalum community to identify traits of interest, including salt tolerance
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