63,017 research outputs found
Out of plane effect on the superconductivity of Sr2-xBaxCuO3+y with Tc up to 98K
A series of new Sr2-xBaxCuO3+y (0 x 0.6) superconductors were prepared using
high-pressure and high-temperature synthesis. A Rietveld refinement based on
powder x-ray diffraction confirms that the superconductors crystallize in the
K2NiF4-type structure of a space group I4/mmm similar to that of La2CuO4 but
with partially occupied apical oxygen sites. It is found that the
superconducting transition temperature Tc of this Ba substituted Sr2CuO3+y
superconductor with constant carrier doping level, i.e., constant d, is
controlled not only by order/disorder of apical-O atoms but also by Ba content.
Tcmax =98 K is achieved in the material with x=0.6 that reaches the record
value of Tc among the single-layer copper oxide superconductors, and is higher
than Tc=95K of Sr2CuO3+y with optimally ordered apical-O atoms. There is
Sr-site disorder in Sr2-xBaxCuO3+y which might lead to a reduction of Tc. The
result indicates that another effect surpasses the disorder effect that is
related either to the increased in-plane Cu-O bond length or to elongated
apical-O distance due to Ba substitution with larger cation size. The present
experiment demonstrates that the optimization of local geometry out of the Cu-O
plane can dramatically enhance Tc in the cuprate superconductors.Comment: 23 Pages, 1 Table, 5 Figure
A robot-based burr measurement system for the automotive industry
Burrs are often difficult to detect and measure because of their intrinsic variability in shape and dimension. No automotive standard had been established about their acceptable dimensions and measurement techniques for sheet steel products. For the automotive industry, even burrs of the size of 100 μm are perceived as damaging because of their dramatic impact upon panel corrosion resistance and assembly performance. It is critical to measure burrs during panel manufacture in order to control the process. The characterization of the typical burr produced has been carried out employing 3D measurements with a surface profilometer and a SEM. This analysis has shown a typical triangular burr shape and some characteristic dimensions. A contact method and two laser-triangulation systems have been developed. The instrument accuracy was analyzed, based upon a full factorial experimentation over a set of typical panels edges
Competing Interactions among Supramolecular Structures on Surfaces
A simple model was constructed to describe the polar ordering of
non-centrosymmetric supramolecular aggregates formed by self assembling
triblock rodcoil polymers. The aggregates are modeled as dipoles in a lattice
with an Ising-like penalty associated with reversing the orientation of nearest
neighbor dipoles. The choice of the potentials is based on experimental results
and structural features of the supramolecular objects. For films of finite
thickness, we find a periodic structure along an arbitrary direction
perpendicular to the substrate normal, where the repeat unit is composed of two
equal width domains with dipole up and dipole down configuration. When a short
range interaction between the surface and the dipoles is included the balance
between the up and down dipole domains is broken. Our results suggest that due
to surface effects, films of finite thickness have a none zero macroscopic
polarization, and that the polarization per unit volume appears to be a
function of film thickness.Comment: 3 pages, 3 eps figure
A novel approach for the assessment of morphological evolution based on observed water levels in tide-dominated estuaries
Assessing the impacts of both natural (e.g., tidal forcing from the ocean) and human-induced changes (e.g., dredging for navigation, land reclamation) on estuarine morphology is particularly important for the protection and management of the estuarine environment. In this study, a novel analytical approach is proposed for the assessment of estuarine morphological evolution in terms of tidally averaged depth on the basis of the observed water levels along the estuary. The key lies in deriving a relationship between wave celerity and tidal damping or amplification. For given observed water levels at two gauging stations, it is possible to have a first estimation of both wave celerity (distance divided by tidal travelling time) and tidal damping or amplification rate (tidal range difference divided by distance), which can then be used to predict the morphological changes via an inverse analytical model for tidal hydrodynamics. The proposed method is applied to the Lingdingyang Bay of the Pearl River Estuary, located on the southern coast of China, to analyse the historical development of the tidal hydrodynamics and morphological evolution. The analytical results show surprisingly good correspondence with observed water depth and volume in this system. The merit of the proposed method is that it provides a simple approach for understanding the decadal evolution of the estuarine morphology through the use of observed water levels, which are usually available and can be easily measured.National Key R&D of China (Grant No.
2016YFC0402601), National Natural Science Foundation of China (Grant No. 51979296, 51709287,
41706088, 41476073), Fundamental Research Funds for the Central Universities (No.18lgpy29)
and from the Water Resource Science and Technology Innovation Program of Guangdong Province (Grant
No. 2016-20, 2016-21). The work of the second author was supported by FCT research contracts
IF/00661/2014/CP1234.info:eu-repo/semantics/submittedVersio
Weak anisotropy of the superconducting upper critical field in Fe1.11Te0.6Se0.4 single crystals
We have determined the resistive upper critical field Hc2 for single crystals
of the superconductor Fe1.11Te0.6Se0.4 using pulsed magnetic fields of up to
60T. A rather high zero-temperature upper critical field of mu0Hc2(0) approx
47T is obtained, in spite of the relatively low superconducting transition
temperature (Tc approx 14K). Moreover, Hc2 follows an unusual temperature
dependence, becoming almost independent of the magnetic field orientation as
the temperature T=0. We suggest that the isotropic superconductivity in
Fe1.11Te0.6Se0.4 is a consequence of its three-dimensional Fermi-surface
topology. An analogous result was obtained for (Ba,K)Fe2As2, indicating that
all layered iron-based superconductors exhibit generic behavior that is
significantly different from that of the high-Tc cuprates.Comment: 4 pages, 4 figures, submit to PR
Split Two-Higgs-Doublet Model and Neutrino Condensation
We split the two-Higgs-doublet model by assuming very different vevs for the
two doublets: the vev is at weak scale (174 GeV) for the doublet \Phi_1 and at
neutrino-mass scale (10^{-2} \sim 10^{-3} eV) for the doublet \Phi_2. \Phi_1 is
responsible for giving masses to all fermions except neutrinos; while \Phi_2 is
responsible for giving neutrino masses through its tiny vev without introducing
see-saw mechanism. Among the predicted five physical scalars H, h, A^0 and
H^{\pm}, the CP-even scalar h is as light as 10^{-2} \sim 10^{-3}eV while
others are at weak scale. We identify h as the cosmic dark energy field and the
other CP-even scalar H as the Standard Model Higgs boson; while the CP-odd A^0
and the charged H^{\pm} are the exotic scalars to be discovered at future
colliders. Also we demonstrate a possible dynamical origin for the doublet
\Phi_2 from neutrino condensation caused by some unknown dynamics.Comment: version in Europhys. Lett. (discussions added
Raman spectroscopic determination of the length, strength, compressibility, Debye temperature, elasticity, and force constant of the C-C bond in graphene
From the perspective of bond relaxation and vibration, we have reconciled the
Raman shifts of graphene under the stimuli of the number-of-layer,
uni-axial-strain, pressure, and temperature in terms of the response of the
length and strength of the representative bond of the entire specimen to the
applied stimuli. Theoretical unification of the measurements clarifies that:
(i) the opposite trends of Raman shifts due to number-of-layer reduction
indicate that the G-peak shift is dominated by the vibration of a pair of atoms
while the D- and the 2D-peak shifts involves z-neighbor of a specific atom;
(ii) the tensile strain-induced phonon softening and phonon-band splitting
arise from the asymmetric response of the C3v bond geometry to the C2v
uni-axial bond elongation; (iii) the thermal-softening of the phonons
originates from bond expansion and weakening; and (iv) the pressure- stiffening
of the phonons results from bond compression and work hardening. Reproduction
of the measurements has led to quantitative information about the referential
frequencies from which the Raman frequencies shift, the length, energy, force
constant, Debye temperature, compressibility, elastic modulus of the C-C bond
in graphene, which is of instrumental importance to the understanding of the
unusual behavior of graphene
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