A global perspective on aerosol from low-volatility organic compounds

Global production of organic aerosol from primary emissions of semivolatile (SVOCs) and intermediate (IVOCs) volatility organic compounds is estimated using the global chemical transport model, GEOS-Chem. SVOC oxidation is predicted to be a larger global source of net aerosol production than oxidation of traditional parent hydrocarbons (terpenes, isoprene, and aromatics). Using a prescribed rate constant and reduction in volatility for atmospheric oxidation, the yield of aerosol from SVOCs is predicted to be about 75% on a global, annually-averaged basis. For IVOCs, the use of a naphthalene-like surrogate with different high-NOx and low-NOx parameterizations produces a global aerosol yield of about 30%, or roughly 5 Tg/yr of aerosol. Estimates of the total global organic aerosol source presented here range between 60 and 100 Tg/yr. This range reflects uncertainty in the parameters for SVOC volatility, SVOC oxidation, SVOC emissions, and IVOC emissions, as well as wet deposition. The highest estimates result if SVOC emissions are significantly underestimated (by more than a factor of 2) or if wet deposition of the gas-phase semivolatile species is less effective than previous estimates. A significant increase in SVOC emissions, a reduction of the volatility of the SVOC emissions, or an increase in the enthalpy of vaporization of the organic aerosol all lead to an appreciable reduction of prediction/measurement discrepancy. In addition, if current primary organic aerosol (POA) inventories capture only about one-half of the SVOC emission and the Henrys Law coefficient for oxidized semivolatiles is on the order of 10^3 M/atm, a global estimate of OA production is not inconsistent with the top-down estimate of 140 Tg/yr by (Goldstein and Galbally, 2007). Additional information is needed to constrain the emissions and treatment of SVOCs and IVOCs, which have traditionally not been included in models

A wrong turn for Initial Teacher Education?

In this article the authors present the results of a small-scale quantitative research project examining the assumption that there is a direct causal link between the classification of a student teacher’s first degree and their ability to teach. Evidence presented in the article supports the hypothesis that the assumption is incorrect. There appears to be no correlation, relationship or link between the classification of a student teacher’s first degree and their ability to teach. The article examines what appears to be driving current policy rhetoric in this area and questions the extent to which such rhetoric may lead to a misallocation of limited resources within Initial Teacher Education

Right turn for Gove; wrong turn for Initial Teacher Education?

In this paper the authors will present the results from a small-scale quantitative research project examining the assumption that there is a direct causal link between the classification of a student teachers first degree and their ability to teach. Alongside this, they will extend the study nationally using Teaching Agency data. The evidence presented in the paper indicates that there appears to be no correlation, relationship or link, between the classification of a student teachers first degree and their ability to teach or their NQT outcome. The authors believe that these results are relevant and pertinent to today‟s education landscape and indicate that current government policy on attracting potential teachers into the profession is resulting in the wasting of limited financial resources in Initial Teacher Education

ECONOMICALLY OPTIMAL WILDFIRE INTERVENTION REGIMES

Wildfires in the United States result in total damages and costs that are likely to exceed billions of dollars annually. Land managers and policy makers propose higher rates of prescribed burning and other kinds of vegetation management to reduce amounts of wildfire and the risks of catastrophic losses. A wildfire public welfare maximization function, using a wildfire production function estimated using a time series model of a panel of Florida counties, is employed to simulate the publicly optimal level of prescribed burning in an example county in Florida (Volusia). Evaluation of the production function reveals that prescribed fire is not associated with reduced catastrophic wildfire risks in Volusia County Florida, indicating a short-run elasticity of -0.16 and a long-run elasticity of wildfire with respect to prescribed fire of -0.07. Stochastic dominance is used to evaluate the optimal amount of prescribed fire most likely to maximize a measure of public welfare. Results of that analysis reveal that the optimal amount of annual prescribed fire is about 3 percent (9,000 acres/year) of the total forest area, which is very close to the actual average amount of prescribed burning (12,700 acres/year) between 1994-99.Resource /Energy Economics and Policy,

Suzaku Discovery of the Strong Radiative Recombination Continuum of Iron from the Supernova Remnant W49B

We present a hard X-ray spectrum of unprecedented quality of the Galactic supernova remnant W49B obtained with the Suzaku satellite. The spectrum exhibits an unusual structure consisting of a saw-edged bump above 8 keV. This bump cannot be explained by any combination of high-temperature plasmas in ionization equilibrium. We firmly conclude that this bump is caused by the strong radiative recombination continuum (RRC) of iron, detected for the first time in a supernova remnant. The electron temperature derived from the bremsstrahlung continuum shape and the slope of the RRC is 1.5 keV. On the other hand, the ionization temperature derived from the observed intensity ratios between the RRC and K-alpha lines of iron is 2.7 keV. These results indicate that the plasma is in a highly overionized state. Volume emission measures independently determined from the fluxes of the thermal and RRC components are consistent with each other, suggesting the same origin of these components.Comment: 5 pages,4 figures, accepted for publication in ApJ Lette

A database and tool for boundary conditions for regional air quality modeling: description and evaluation

Transported air pollutants receive increasing attention as regulations tighten and global concentrations increase. The need to represent international transport in regional air quality assessments requires improved representation of boundary concentrations. Currently available observations are too sparse vertically to provide boundary information, particularly for ozone precursors, but global simulations can be used to generate spatially and temporally varying lateral boundary conditions (LBC). This study presents a public database of global simulations designed and evaluated for use as LBC for air quality models (AQMs). The database covers the contiguous United States (CONUS) for the years 2001–2010 and contains hourly varying concentrations of ozone, aerosols, and their precursors. The database is complemented by a tool for configuring the global results as inputs to regional scale models (e.g., Community Multiscale Air Quality or Comprehensive Air quality Model with extensions). This study also presents an example application based on the CONUS domain, which is evaluated against satellite retrieved ozone and carbon monoxide vertical profiles. The results show performance is largely within uncertainty estimates for ozone from the Ozone Monitoring Instrument and carbon monoxide from the Measurements Of Pollution In The Troposphere (MOPITT), but there were some notable biases compared with Tropospheric Emission Spectrometer (TES) ozone. Compared with TES, our ozone predictions are high-biased in the upper troposphere, particularly in the south during January. This publication documents the global simulation database, the tool for conversion to LBC, and the evaluation of concentrations on the boundaries. This documentation is intended to support applications that require representation of long-range transport of air pollutants

Broadband Acoustic Measurement of the Agar-based Tissue Mimicking Material: a Longitudinal Study

Commercially available ultrasound quality assurance test phantoms rely on the long-term acoustic stability of the tissue-mimicking-material (TMM). Measurement of the acoustic properties of the TMM can be technically challenging, and it is important to ensure its stability. The standard technique is to film-wrap samples of TMM and to measure the acoustic properties in a water bath. In this study, a modified technique was proposed whereby the samples of TMM are measured in a preserving fluid that is intended to maintain their characteristics. The acoustic properties were evaluated using a broadband pulse-echo substitution technique over the frequency range 4.5–50 MHz at 0, 6 and 12 months using both techniques. For both techniques, the measured mean values for the speed of sound and attenuation were very similar and within the International Electrotechnical Commission-recommended value. However, the results obtained using the proposed modified technique exhibited greater stability over the 1-y period compared with the results acquired using the standard technique

Thermoplastic cable insulation comprising a blend of isotactic polypropylene and a propylene-ethylene copolymer

There is much interest in the development of replacement materials for crosslinked polyethylene (XLPE) that are both recyclable (i.e. thermoplastic) and capable of high temperature operation. Thermally, polypropylene is the ideal choice, although its stiffness and low electrical breakdown strength make for a challenging materials design problem. We report here on the compositional optimization of a propylene homopolymer/propylene-ethylene copolymer blend in terms of its dynamic mechanical properties and thin film electrical breakdown strength. The extrusion of a trial mini-cable using the optimized blend is also discussed, which is shown to exhibit a significantly improved electrical performance, as gauged by its DC breakdown strength, than an XLPE-insulated reference

Experimental and model estimates of the contributions from biogenic monoterpenes and sesquiterpenes to secondary organic aerosol in the southeastern United States

Atmospheric organic aerosol (OA) has important impacts on climate and human health but its sources remain poorly understood. Biogenic monoterpenes and sesquiterpenes are important precursors of secondary organic aerosol (SOA), but the amounts and pathways of SOA generation from these precursors are not well constrained by observations. We propose that the less-oxidized oxygenated organic aerosol (LO-OOA) factor resolved from positive matrix factorization (PMF) analysis on aerosol mass spectrometry (AMS) data can be used as a surrogate for fresh SOA from monoterpenes and sesquiterpenes in the southeastern US. This hypothesis is supported by multiple lines of evidence, including lab-in-the-field perturbation experiments, extensive ambient ground-level measurements, and state-of-the-art modeling. We performed lab-in-the-field experiments in which the ambient air is perturbed by the injection of selected monoterpenes and sesquiterpenes, and the subsequent SOA formation is investigated. PMF analysis on the perturbation experiments provides an objective link between LO-OOA and fresh SOA from monoterpenes and sesquiterpenes as well as insights into the sources of other OA factors. Further, we use an upgraded atmospheric model and show that modeled SOA concentrations from monoterpenes and sesquiterpenes could reproduce both the magnitude and diurnal variation of LO-OOA at multiple sites in the southeastern US, building confidence in our hypothesis. We estimate the annual average concentration of SOA from monoterpenes and sesquiterpenes in the southeastern US to be roughly 2µgm^(−3)

Unequal relationships in high and low power distance societies: a comparative study of tutor - student role relations in Britain and China

This study investigated people's conceptions of an unequal role relationship in two different types of society: a high power distance society and a low power distance society. The study focuses on the role relationship of tutor and student. British and Chinese tutors and postgraduate students completed a questionnaire that probed their conceptions of degrees of power differential and social distance/closeness in this role relationship. ANOVA results yielded a significant nationality effect for both aspects. Chinese respondents judged the relationship to be closer and to have a greater power differential than did British respondents. Written comments on the questionnaire and interviews with 9 Chinese academics who had experienced both British and Chinese academic environments supported the statistical findings and indicated that there are fundamental ideological differences associated with the differing conceptions. The results are discussed in relation to Western and Asian concepts of leadership and differing perspectives on the compatibility/incompatibility of power and distance/closeness