New paleomagnetic constraints for the large-scale displacement of the Hronic nappe system of the Central Western Carpathians

The thin-skinned Hronic nappe system represents the structurally highest tectonic unit in the Late Cretaceous thrust-stack of the Central Western Carpathians. It mostly comprises a Permian volcano-sedimentary sequence and Triassic carbonate sediments which crop out in different parts of the Central Western Carpathians. We carried out a systematic paleomagnetic study on 24 Permian and 20 Triassic localities geographically distributed over 300 km in W-E direction. Several samples from each locality were drilled and oriented in-situ and specimens cut from them subjected to standard paleomagnetic and magnetic mineralogy experiments. The results were evaluated using principal component analysis, statistical evaluation of the characteristic remanences, and applying inclination-only and tilt tests. We documented the pre-tilting age of remanences for the majority of both the Permian and Triassic age groups. However, the latter was interpreted as remagnetized during the Cretaceous Normal Super-Chron in the course of nappe stacking between 90-80 Ma. The Permian group is exhibiting about 70°, the Triassic about 34° clockwise vertical axis rotations with respect to the present north. There is no indication in our data set for oroclinal bending of the Hronic Unit. We interpret the difference in clockwise rotations (about 36°) between Permian and 90-80 Ma as a clockwise block rotation taking place during major extensional and/or compressive events between stable Europe and Africa. Taking into consideration the well-documented counterclockwise rotation observed for the overstep sequences in the Central Western Carpathians and in the Pieniny Klippen Belt, the remagnetization of the Triassic sediments was closely followed by about 94° clockwise rotation. Research in progress will serve to decide if this large clockwise rotation involved the whole Central Carpathian nappe stack or part of this was due to the thin-skinned nappe emplacement of the Hronic Unit

Origin and Age Determination of the Neotethys Meliata Basin Ophiolite Fragments in the Late Jurassic–Early Cretaceous Accretionary Wedge Mélange (Inner Western Carpathians, Slovakia)

This study reports the Neotethyan Meliata Basin ophiolite fragments in the Late Jurassic–Early Cretaceous accretionary wedge mélange in the southern part of the Inner Western Carpathians (IWC). Here we present new lithostratigraphical, petrographical, geochemical, and geochronological data obtained from the mélange blocks used to reconstruct the Meliaticum paleotectonic zones in a tentative evolutionary model of this accretionary wedge. The Dobšiná mélange block continental margin carbonatic and siliciclastic sediments have calc-alkaline basalt intercalations. The basalt Concordia age dated to 245.5 ± 3.3 Ma by U–Pb SIMS on zircon most likely indicates the pre-oceanic advanced early Middle Triassic continental rifting stage. The evolving marginal oceanic crust is composed of Middle to Upper Triassic cherty shales to radiolarites. The detrital zircon U–Pb SIMS Concordia ages of 247 ± 4 Ma and 243 ± 4 Ma from a cherty shale, and the xenocryst zircon population Concordia age of 266 ± 3 Ma from a 0.5 m thick “normal” mid-ocean ridge (N-MOR) basalt layer in this cherty shale reveal the connection of the oceanic basin to the adjacent rifting continental margin. The chertified reddish limestone transition to radiolarite indicates syn-rift basin deepening. Upwards, regular alternating N-MOR basalts and radiolarites are often disturbed by peperite breccia horizons. The Nd isotope values of these basalts (εNd240 = 7–8) are consistent with their chondrite normalized rare earth element (REE) patterns and indicate a depleted mantle source. The Triassic ophiolitic suite also comprises rare ocean island (OI) basalts (εNd240 = 5) and serpentinized subduction unrelated peridotites. The Middle to Late Jurassic shortening and southward intra-oceanic and continental margin subduction at approximately 170–150 Ma enhanced the formation of the trench-like Jurassic flysch succession which preceded the closure of the Meliata Basin. The flysch sediments form a mélange matrix of olistolithic unsubducted, obducted, and MP–HP/LT metamorphosed exhumed blocks of the Triassic to Lower Jurassic successions. Blocks of peridotites, rodingites, blueschists, greenschists, rare amphibolites, deep-water shaly sediments and shallow- to deep-water carbonates are typical members of the mélange. The Meliatic accretionary wedge mélange nappe outliers were incorporated in the IWC orogenic wedge in the late Early Cretaceous according to metamorphic rutile U–Pb SIMS ages of 100 ± 10 Ma determined from a Jaklovce metabasalt

Petrology and geochemistry of a peridotite body in Central- Carpathian Paleogene sediments (Sedlice, eastern Slovakia)

We studied representative samples from a peridotite body situated NE of Sedlice village within the Central- Carpathian Paleogene sediments in the Central Western Carpathians. The relationship of the peridotite to the surrounding Paleogene sediments is not clear. The fractures of the brecciated peridotite margin are healed with secondary magnesite and calcite. On the basis of the presented bulk-rock and electron microprobe data, the wt. % amounts of mineral phases were calculated. Most of calculated “modal” compositions of this peridotite corresponds to harzburgites composed of olivine (∼70-80 wt. %), orthopyroxene (∼17-24 wt. %), clinopyroxene ( < 5 wt. %) and minor spinel ( < 1 wt. %). Harzburgites could originate from lherzolitic protoliths due to a higher degree of partial melting. Rare lherzolites contain porphyroclastic 1-2 mm across orthopyroxene (up to 25 wt. %), clinopyroxene (∼ 5-8 wt. %) and minor spinel ( < 0.75 wt. %). On the other hand, rare, olivine-rich dunites with scarce orthopyroxene porphyroclasts are associated with harzburgites. Metamorphic mineral assemblage of low-Al clinopyroxene (3), tremolite, chrysotile, andradite, Cr-spinel to chromite and magnetite, and an increase of fayalite component in part of olivine, indicate low-temperature metamorphic overprint. The Primitive Mantle normalized whole-rock REE patterns suggest a depleted mantle rock-suite. An increase in LREE and a positive Eu anomaly may be consequence of interactive metamorphic fluids during serpentinization. Similar rocks have been reported from the Meliatic Bôrka Nappe overlying the Central Western Carpathians orogenic wedge since the Late Cretaceous, and they could be a potential source of these peridotite blocks in the Paleogene sediments

Classifying minerals and their related names in a relational database

Abstract The categorisation of minerals and their related names, such as synonyms, obsolete or historical names, varieties or mixtures, is an asset for designing an interoperable and consistent mineralogical data warehouse. An enormous amount of this data, provided by mindat.org and other resources, was reviewed and analysed during the research. The analysis indicates the existence of several categories of (1) the abstract titles or designations representing the link to the original material or a group of names or substances without actual physical representation, and (2) the unique names representing actual physical material, compounds, or an aggregate of one or more minerals. A revision of the dependency between the categories attributes stored in a database (e.g. chemical properties, physical properties) and their classification status assigned allowed us to design a robust prototype for maintaining database integrity and consistency. The proposed scheme allows standardisation and structuring of officially regulated and maintained species, e.g. IMA-approved, and, in addition, unregulated ones

Metamorphic Conditions of Neotethyan Meliatic Accretionary Wedge Estimated by Thermodynamic Modelling and Geothermobarometry (Inner Western Carpathians)

Metamorphic evolution of an accretionary wedge can be constrained by a reconstructed P&ndash;T conditions of the oceanic and continental margin fragments. This paper deals with the metamorphic overprinting of the Inner Western Carpathians (IWC) Meliatic Triassic&ndash;Jurassic paleotectonic units after the closure of the Neotethyan Meliata Basin. Medium to high-pressure and lower temperature conditions were estimated by Perple_X pseudosection modelling, combined with garnet&ndash;phengite, calcite&ndash;dolomite and chlorite thermometers and chlorite&ndash;phengite and phengite barometers. The Late Jurassic subductional burial to a maximum 50 km depth was estimated from the B&ocirc;rka Unit continental margin fragments at 520 &deg;C and 1.55 GPa. This is compatible with the metamorphic peak garnet&ndash;glaucophane&ndash;phengite assemblage of blueschist facies in metabasites. The Jaklovce Unit oceanic fragments were subducted to maximum 35&ndash;40 km at 390&ndash;420 &deg;C and 1.1&ndash;1.3 GPa. Metabasalts and metadolerites contain winchite, riebeckite, actinolite, chlorite, albite, epidote and phengite. A glaucophane-bearing metabasalt recorded an intra-oceanic subduction in blueschist-facies conditions. Rare amphibolite-facies metabasalts of this unit indicate the base of an inferred oceanic crust sliver obducted onto the continental margin wedge. The Meliata Unit oceanic/continental margin flysch calciclastic and siliciclastic metasediments suggest the burial to approximately 15&ndash;20 km at 250&ndash;350 &deg;C and 0.4&ndash;0.6 GPa. This is indicated by a newly formed albite, K-feldspar, illite&ndash;phengite and chlorite associated with quartz and/or calcite and dolomite in these rocks. Magnesio-hastingsite to magnesio-hornblende bearing metagabbro with newly formed metamorphic magnesio-riebeckite and actinolite is an inferred detached Meliatic block tectonically emplaced in a Permian salinar m&eacute;lange in the Silica Nappe hanging wall. Reconstructed P&ndash;T paths indicate variable metamorphic conditions from the medium-pressure to high-pressure subduction of the B&ocirc;rka and Jaklovce units to the Meliata Unit shallow burial in an accretionary wedge during Late Jurassic to Early Cretaceous Meliaticum evolution. M&eacute;lange blocks of Meliaticum incorporate different juxtaposed Meliatic paleotectonic units exposed in nappe outliers overlying the IWC Gemeric and Veporic superunits

Geochemistry, Lu–Hf garnet ages, and P–T conditions of blueschists from the Meliatic and Fatric nappes, Western Carpathians: Indicators of Neotethyan subduction

Basaltic rocks from ophiolitic mélanges provide information on geodynamic setting, origin, and later tectonometamorphic conditions. This paper resolves the P–T conditions and timing of high-pressure metamorphism in an accretionary wedge that formed during the Late Jurassic closure of the Neotethyan Meliata Basin. Blueschist-facies metabasites of the Meliatic Bôrka Nappe and the Albian conglomerate pebbles of the Fatric Klape Nappe contain rare assemblages of garnet in association with glaucophane, phengite, rutile, and epidote (±albite). Here, we compare a Lu–Hf garnet age from the Meliatic Bôrka Nappe in the southern margin of the Inner Western Carpathians (IWC) with a garnet age from inferred Meliatic blueschists of the Klape Nappe overlying the IWC northern margin. The Hačava type locality of the Bôrka Nappe hosts calc-alkaline type metabasite (∼VAB-C; εNd(245) = +0.9) embedded within Middle to Upper Triassic marbles of the Neotethyan Meliata Basin northern continental margin. The investigated Klape Nappe island arc tholeiite (∼VAB-T; εNd(240) = +5.9) blueschist pebble, and associated deepwater metasedimentary rock pebbles were found in a conglomerate layer of unmetamorphosed Albian flysch. The garnet ages of 153.95±0.69 Ma and 152.1±1.5 Ma correspond to closure of the Meliata Basin during southward intraoceanic and continental margin subduction. This was followed by the exhumation of HP blocks in serpentinite mélange and the formation of an accretionary wedge with included anchimetamorphosed Jurassic flysch. The P–T conditions of the blueschists were constrained by Perple_X modelling to be 520°C and 1.55 GPa for the Bôrka Nappe, and 490–510°C and 1.68–1.72 GPa for a pebble from the Klape Nappe conglomerate. The similarity of garnet dates and metamorphic conditions between the two samples suggest that the blueschists formed during the Late Jurassic Meliatic subduction. The north-vergent Meliatic nappes are the inferred source of the Albian flysch conglomerates deposited in the foreland Fatric Basin. This material was subsequently transported by the Fatric Klape Nappe to the IWC orogenic front during the Turonian, following the closure of the Fatric Basin

Perovskite, reaction product of a harzburgite with Jurassic– Cretaceous accretionary wedge fluids (Western Carpathians, Slovakia): evidence from the whole-rock and mineral trace element data

Perovskite (Prv) was discovered in an abyssal harzburgite from a “mélange” type blueschist-bearing accretionary wedge of the Western Carpathians (Meliata Unit, Slovakia). Perovskite-1 formation in serpentinized orthopyroxene may be simplified by the mass-balance reaction: Ca2Si2O6 (Ca-pyroxene-member)+2Fe2TiO4 (ulvöspinel molecule in spinel)+2H2O+O2=2CaTiO3 (Prv)+2SiO2+4FeOOH (goethite). Perovskite-2 occurs in a chlorite-rich blackwall zone separating serpentinite and rodingite veins, and in rodingite veins alone. The bulk-rock trace-element patterns suggest negligible differences from visually and microscopically less (“core”) to strongly serpentinized harzburgite due to serpentinization and rodingitization: an enrichment in LREE(La,Ce), Cs, ±Ba, U, Nb, Pb, As, Sb, ±Nd and Li in comparison with HREE, Rb and Sr. The U/Pb perovskite ages at ~135 Ma are interpreted to record the interaction of metamorphic fluids with harzburgite blocks in the Neotethyan Meliatic accretionary wedge. Our LA-ICP-MS mineral study provides a complex view on trace element behaviour during the two stages of rodingitization connected with Prv genesis. The positive anomalies of Cs, U, Ta, Pb, As, Sb, Pr and Nd in Cpx, Opx and Ol are combined with the negative anomalies of Rb, Ba, Th, Nb and Sr in these minerals. The similar positive anomalies of Cs, U, Ta, ±Be, As, Sb found in typical serpentinization and rodingitization minerals, with variable contents of La, Ce and Nd, and negative anomalies of Rb, Ba, Th, Nb and Sr suggest involvement of crustal fluids during MP-LP/LT accretionary wedge metamorphism. LA-ICP-MS study revealed strong depletion in LREE from Prv-1 to Prv-2, and a typically negative Eu (and Ti) anomaly for Prv-1, while a positive Eu (and Ti) anomaly for Prv-2. Our multi-element diagram depicts enrichment in U, Nb, La, Ce, As, Sb, Pr, Nd and decreased Rb, Ba, Th, Ta, Pb, Sr, Zr in both Prv generations. In general, both Prv generations are very close to the end-member composition. In spite of low concentrations of isomorphic constituents, Prv-1 and Prv-2 display the A(La,Ce)3++B(Fe,Cr)3+=ACa2++BTi4+ heterovalent couple substitution. A decrease of ferric iron in Prv-2 indicates increasing reduction conditions during rodingitization

Formation of a Composite Albian–Eocene Orogenic Wedge in the Inner Western Carpathians: P–T Estimates and 40Ar/39Ar Geochronology from Structural Units

The composite Albian–Eocene orogenic wedge of the northern part of the Inner Western Carpathians (IWC) comprises the European Variscan basement with the Upper Carboniferous–Triassic cover and the Jurassic to Upper Cretaceous sedimentary successions of a large oceanic–continental Atlantic (Alpine) Tethys basin system. This paper presents an updated evolutionary model for principal structural units of the orogenic wedge (i.e., Fatricum, Tatricum and Infratatricum) based on new and published white mica 40Ar/39Ar geochronology and P–T estimates by Perple_X modeling and geothermobarometry. The north-directed Cretaceous collision led to closure of the Jurassic–Early Cretaceous basins, and incorporation of their sedimentary infill and a thinned basement into the Albian–Cenomanian/Turonian accretionary wedge. During this compressional D1 stage, the subautochthonous Fatric structural units, including the present-day higher Infratatric nappes, achieved the metamorphic conditions of ca. 250–400 °C and 400–700 MPa. The collapse of the Albian–Cenomanian/Turonian wedge and contemporary southward Penninic oceanic subduction enhanced the extensional exhumation of the low-grade metamorphosed structural complexes (D2 stage) and the opening of a fore-arc basin. This basin hemipelagic Coniacian–Campanian Couches-Rouges type marls (C.R.) spread from the northern Tatric edge, throughout the Infratatric Belice Basin, up to the peri-Pieniny Klippen Belt Kysuca Basin, thus tracing the south-Penninic subduction. The ceasing subduction switched to the compressional regime recorded in the trench-like Belice “flysch” trough formation and the lower anchi-metamorphism of the C.R. at ca. 75–65 Ma (D3 stage). The Belice trough closure was followed by the thrusting of the exhumed low-grade metamorphosed higher Infratatric complexes and the anchi-metamorphosed C.R. over the frontal unmetamorphosed to lowest anchi-metamorphosed Upper Campanian–Maastrichtian “flysch” sediments at ca. 65–50 Ma (D4 stage). Phengite from the Infratatric marble sample SRB-1 and meta-marl sample HC-12 produced apparent 40Ar/39Ar step ages clustered around 90 Ma. A mixture interpretation of this age is consistent with the presence of an older metamorphic Ph1 related to the burial (D1) within the Albian–Cenomanian/Turonian accretionary wedge. On the contrary, a younger Ph2 is closely related to the late- to post-Campanian (D3) thrust fault formation over the C.R. Celadonite-enriched muscovite from the subautochthonous Fatric Zobor Nappe meta-quartzite sample ZI-3 yielded a mini-plateau age of 62.21 ± 0.31 Ma which coincides with the closing of the Infratatric foreland Belice “flysch” trough, the accretion of the Infratatricum to the Tatricum, and the formation of the rear subautochthonous Fatricum bivergent structure in the Eocene orogenic wedge

Mineralogical-Petrographical Record of Melt-Rock Interaction and P–T Estimates from the Ozren Massif Ophiolites (Bosnia and Herzegovina)

The Dinaride Ophiolite Belt formed from the Jurassic part of the Neotethys. The investigated Ozren ophiolite complex in Bosnia and Herzegovina consists of peridotites, plagioclase peridotites, plagiogranites, troctolites and other gabbroic rocks, and fewer basalts. Lherzolites and harzburgites contain corroded ortho- and clinopyroxene1 porphyroclasts enclosed in the olivine matrix. The boundaries between olivine aggregates and pyroxene1 and spinel1 are infilled by medium-grained undeformed aggregates of clinopyroxene2, less orthopyroxene2, spinel2, and often clinopyroxene3-spinel3 symplectites. These textures indicate the final crystallization of peridotite in subsolidus conditions. Partial dissolution of deformed pyroxene1 porphyroclasts and coarse-grained spinel1 most likely occurred due to their reaction with the rest melt present in the grain boundaries. The Al decrease from pyroxene1 to pyroxene2 and 3, or the Cr decrease and Al increase from spinel1 to spinel2 and 3 is characteristic. Peridotites are associated with inferred remnants of a gabbro-dolerite layer, whereas basalts and radiolarites occur as rare dm-size fragments in an ophiolitic breccia. Troctolites display interstitial crystallization of plagioclase, clinopyroxene, less Na-Ti-rich amphiboles, and phlogopite in the olivine-spinel matrix, indicating the replacive character of impregnating melt within the dunite layers. Clinopyroxene-plagioclase-ilmenite-±amphibole gabbroic and fewer basaltic dykes in peridotites formed due to subridge extension, mantle thinning, and the deeper mantle melting. Iron-enriched olivines occur in the peridotite-dyke interfaces and troctolites. Hydrated ultramafics and mafics contain amphiboles, biotite, phlogopite, clinozoisite, epidote, and chlorite aggregates. Estimated magmatic to subsolidus T from peridotite two-pyroxene thermometry are 1000–850 °C, for the spinel facies. Ca-in-orthopyroxene1 thermometry provided T of 1028–1068 °C, and Ca-in-orthopyroxene2 thermometry gave 909–961 °C at estimated P of 1.1–0.9 GPa. However, the gabbroic dyke magmatic crystallization T was constrained to 1200–1100 °C at P of 0.45–0.15 GPa by single clinopyroxene thermobarometry. The obtained P–T conditions constrained the deeper mantle environment for the formation of peridotites than troctolites and crosscutting dykes. The ophiolitic thrust-sheet hanging wall conditions in an obduction-related accretionary wedge were estimated from amphibolites at 620 °C and 0.85 GPa by Ti-in-amphibole thermometry and amphibole-plagioclase thermobarometry. 300 °C and 0.5 GPa were determined from an exhumation shear zone using a combination of chlorite thermometry and Si-in-phengite barometry