Quantum lost property: a possible operational meaning for the Hilbert-Schmidt product

Minimum error state discrimination between two mixed states \rho and \sigma can be aided by the receipt of "classical side information" specifying which states from some convex decompositions of \rho and \sigma apply in each run. We quantify this phenomena by the average trace distance, and give lower and upper bounds on this quantity as functions of \rho and \sigma. The lower bound is simply the trace distance between \rho and \sigma, trivially seen to be tight. The upper bound is \sqrt{1 - tr(\rho\sigma)}, and we conjecture that this is also tight. We reformulate this conjecture in terms of the existence of a pair of "unbiased decompositions", which may be of independent interest, and prove it for a few special cases. Finally, we point towards a link with a notion of non-classicality known as preparation contextuality.Comment: 3 pages, 1 figure. v2: Less typos in text and less punctuation in titl

Crystal Nucleation of Colloidal Suspensions under Shear

We use Brownian Dynamics simulations in combination with the umbrella sampling technique to study the effect of shear flow on homogeneous crystal nucleation. We find that a homogeneous shear rate leads to a significant suppression of the crystal nucleation rate and to an increase of the size of the critical nucleus. A simple, phenomenological extension of classical nucleation theory accounts for these observations. The orientation of the crystal nucleus is tilted with respect to the shear direction.Comment: 4 pages, 3 figures, Submitted to Phys. Rev. Let

Detection and Estimation Theory

Contains reports on one research projects.Joint Services Electronics Program (Contract DAAB07-71-C-0300)National Science Foundation (Grant GX-36331

Are quantum states real?

In this paper we consider theories in which reality is described by some underlying variables. Each value these variables can take represents an ontic state (a particular state of reality). The preparation of a quantum state corresponds to a distribution over the ontic states. If we make three basic assumptions, we can show that the distributions over ontic states corresponding to distinct pure states are non-overlapping. This means that we can deduce the quantum state from a knowledge of the ontic state. Hence, if these assumptions are correct, we can claim that the quantum state is a real thing (it is written into the underlying variables that describe reality). The key assumption we use in this proof is ontic indifference - that quantum transformations that do not affect a given pure quantum state can be implemented in such a way that they do not affect the ontic states in the support of that state. In fact this assumption is violated in the Spekkens toy model (which captures many aspects of quantum theory and in which different pure states of the model have overlapping distributions over ontic states). This paper proves that ontic indifference must be violated in any model reproducing quantum theory in which the quantum state is not a real thing. The argument presented in this paper is different from that given in a recent paper by Pusey, Barrett, and Rudolph. It uses a different key assumption and it pertains to a single copy of the system in question.Comment: 19 pages, 4 figures. Remarks added concerning fact that ontic indifference assumption is violated in Spekkens toy mode

Crystallization Mechanism of Hard Sphere Glasses

In supercooled liquids, vitrification generally suppresses crystallization. Yet some glasses can still crystallize despite the arrest of diffusive motion. This ill-understood process may limit the stability of glasses, but its microscopic mechanism is not yet known. Here we present extensive computer simulations addressing the crystallization of monodisperse hard-sphere glasses at constant volume (as in a colloid experiment). Multiple crystalline patches appear without particles having to diffuse more than one diameter. As these patches grow, the mobility in neighbouring areas is enhanced, creating dynamic heterogeneity with positive feedback. The future crystallization pattern cannot be predicted from the coordinates alone: crystallization proceeds by a sequence of stochastic micro-nucleation events, correlated in space by emergent dynamic heterogeneity.Comment: 4 pages 4 figures Accepted for publication in Phys. Rev. Lett., April 201

Integration through transients for Brownian particles under steady shear

Starting from the microscopic Smoluchowski equation for interacting Brownian particles under stationary shearing, exact expressions for shear-dependent steady-state averages, correlation and structure functions, and susceptibilities are obtained, which take the form of generalized Green-Kubo relations. They require integration of transient dynamics. Equations of motion with memory effects for transient density fluctuation functions are derived from the same microscopic starting point. We argue that the derived formal expressions provide useful starting points for approximations in order to describe the stationary non-equilibrium state of steadily sheared dense colloidal dispersions.Comment: 17 pages, Submitted to J. Phys.: Condens. Matter; revised version with minor correction

Square root singularity in the viscosity of neutral colloidal suspensions at large frequencies

The asymptotic frequency $\omega$, dependence of the dynamic viscosity of neutral hard sphere colloidal suspensions is shown to be of the form $\eta_0 A(\phi) (\omega \tau_P)^{-1/2}$, where $A(\phi)$ has been determined as a function of the volume fraction $\phi$, for all concentrations in the fluid range, $\eta_0$ is the solvent viscosity and $\tau_P$ the P\'{e}clet time. For a soft potential it is shown that, to leading order steepness, the asymptotic behavior is the same as that for the hard sphere potential and a condition for the cross-over behavior to $1/\omega \tau_P$ is given. Our result for the hard sphere potential generalizes a result of Cichocki and Felderhof obtained at low concentrations and agrees well with the experiments of van der Werff et al, if the usual Stokes-Einstein diffusion coefficient $D_0$ in the Smoluchowski operator is consistently replaced by the short-time self diffusion coefficient $D_s(\phi)$ for non-dilute colloidal suspensions.Comment: 18 pages LaTeX, 1 postscript figur

Fractionation effects in phase equilibria of polydisperse hard sphere colloids

The equilibrium phase behaviour of hard spheres with size polydispersity is studied theoretically. We solve numerically the exact phase equilibrium equations that result from accurate free energy expressions for the fluid and solid phases, while accounting fully for size fractionation between coexisting phases. Fluids up to the largest polydispersities that we can study (around 14%) can phase separate by splitting off a solid with a much narrower size distribution. This shows that experimentally observed terminal polydispersities above which phase separation no longer occurs must be due to non-equilibrium effects. We find no evidence of re-entrant melting; instead, sufficiently compressed solids phase separate into two or more solid phases. Under appropriate conditions, coexistence of multiple solids with a fluid phase is also predicted. The solids have smaller polydispersities than the parent phase as expected, while the reverse is true for the fluid phase, which contains predominantly smaller particles but also residual amounts of the larger ones. The properties of the coexisting phases are studied in detail; mean diameter, polydispersity and volume fraction of the phases all reveal marked fractionation. We also propose a method for constructing quantities that optimally distinguish between the coexisting phases, using Principal Component Analysis in the space of density distributions. We conclude by comparing our predictions to perturbative theories for near-monodisperse systems and to Monte Carlo simulations at imposed chemical potential distribution, and find excellent agreement.Comment: 21 pages, 23 figures, 2 table

Stabilizer notation for Spekkens' toy theory

Spekkens has introduced a toy theory [Phys. Rev. A, 75, 032110 (2007)] in order to argue for an epistemic view of quantum states. I describe a notation for the theory (excluding certain joint measurements) which makes its similarities and differences with the quantum mechanics of stabilizer states clear. Given an application of the qubit stabilizer formalism, it is often entirely straightforward to construct an analogous application of the notation to the toy theory. This assists calculations within the toy theory, for example of the number of possible states and transformations, and enables superpositions to be defined for composite systems.Comment: 7+4 pages, 5 tables. v2: Clarifications added and typos fixed in response to referee comment

Homogeneous nucleation of colloidal melts under the influence of shearing fields

We study the effect of shear flow on homogeneous crystal nucleation, using Brownian Dynamics simulations in combination with an umbrella sampling like technique. The symmetry breaking due to shear results in anisotropic radial distribution functions. The homogeneous shear rate suppresses crystal nucleation and leads to an increase of the size of the critical nucleus. These observations can be described by a simple, phenomenological extension of classical nucleation theory. In addition, we find that nuclei have a preferential orientation with respect to the direction of shear. On average the longest dimension of a nucleus is along the vorticity direction, while the shortest dimension is preferably perpendicular to that and slightly tilted with respect to the gradient direction.Comment: 10 pages, 8 figures, Submitted to J. Phys.: Condens. Matte