Stratigraphic architecture of a paleoproterozoic iron formation depositional system : the Gunflint, Mesabi and Cuyuna iron ranges

Understanding iron formation depositional processes has been hindered by the lack of precise modern analogues. However, by combining a regional basin analysis of sedimentary and volcanic rocks surrounding an iron formation with detailed examination of sedimentary structures and lithic associations within an iron formation, the depositional setting and physical processes of sedimentation can be inferred (Fralick and Barrett, 1995). This technique departs significantly from previous methods used for interpreting iron formation sedimentoiogical environments. Instead of focusing on their mineralogy, the description of iron-bearing formations and members, and the erection of stratotypes the basis of this method is the application of Walther's Law and the facies model concept to large scale depositional tracts, up to and including the entire basin (Miall, 1984). Three Paleoprotoerozoic iron formations from the Lake Superior region were investigated using this approach. The Gunflint, Biwabik, and Trommald iron formations are correlative ferruginous units from the Animikie and North Range Groups along the north shore of Lake Superior in Ontario and Minnesota. Two clastic, two volcaniclastic, nine chemical sedimentary, and two cryptalgal facies are present: clast and matrix supported pebble conglomerate, massive quartz sandstone, slate, lapilli tuff, massive and/or cross stratified chert-carbonate grainstone, massive and/or cross stratified hematite-rich grainstone, massive chert-carbonate grainstone with rip up clasts, flaser bedded chert-carbonate grainstone, wavy bedded chert-carbonate grainstone, hummocky cross-stratified chert grainstone, parallel and wavy laminated chemical slate interbedded with chert grainstone, parallel and wavy laminated chemical slate, stromatolites, and oncolites. Chemical sedimentary facies may be grouped into associations comprising seven informal stratigraphic members. Lateral and vertical facies transitions within these members are similar to many Phanerozoic marine shelf systems. Like sediments accumulating along the margins of modern oceans, the chemical sedimentary rocks in Ontario and Minnesota also form a sedimentary wedge which fines and thickens from coarse wave reworked, nearshore deposits of the foreshore and shoreface to parallel laminated mudstones of the outer shelf and slope break. One important difference is the absence of a mud dominated inner shelf. This may be the result of the development of "grainstone factories" below fairweather wave base. Grainstone factories are thought to have formed in proximal offshore areas where iron oxide and silica gel actively precipitated, and where currents could rework these chemical precipitates into rip-up grains. They are broadly similar to modern "subtidal carbonate factories". Stratigraphic data also indicates that iron-bearing members are diachronous and that their deposition was governed by five changes in relative sea level and three pulses of volcanism. The final volcanic episode marks the cessation o f iron formation accumulation as the depositional system was rapidly overwhelmed with volcaniclastics

Middle Ordovician Upwelling-Related Ironstone of North Wales: Coated Grains, Ocean Chemistry, and Biological Evolution

Middle Ordovician phosphatic ironstone of the Welsh Basin provides new insight into the paleoenvironmental significance of ironstone and Ordovician ocean chemistry. Deposition occurred in a back-arc basin along the southern margin of Avalonia as the Rheic Ocean opened to the south. Ironstone is interpreted to have accumulated as part of an aggradational parasequence on a storm-dominated shelf with coastal upwelling. This parasequence has a laminated pyritic mudstone base that grades upward into variably bioturbated mudstone and coated grain-rich, intraclastic ironstone, which is overlain in turn by cross-stratified grainstone composed entirely of coated Fe grains. A coarser clastic parasequence composed of more proximal lithofacies rests conformably above and suggests the contact between the two parasequences is a maximum flooding surface marking the onset of highstand conditions. Lithofacies associations suggest that sustained coastal upwelling created a wedge of nutrient-rich, ferruginous seawater on the middle shelf that stimulated high surface ocean productivities. Large, coated Fe grains (granule size) composed of discontinuous and concentric carbonate fluorapatite, hematite, and chamosite cortical layers record fluctuations in pore water Eh that are interpreted to have been related to changes in upwelling intensity and intermittent storm reworking of the seafloor. Results support an emerging model for Ordovician ironstone underpinned by the development of ferruginous bottom water that was periodically tapped by coastal upwelling. Expanding, semi-restricted seaways such as the Rheic Ocean were ideal locations for the ponding of this anoxic, hydrothermally enriched seawater, especially during the early Paleozoic when the deep ocean was variably and inconsistently oxygenated. The coincidence of ironstone depositional episodes with graptolite diversification events suggests that, in addition to Fe, the sustained supply of upwelling-related P may have driven the radiation of some planktonic ecosystems during the Great Ordovician Biodiversification Event. Concomitant minor extinctions of benthic trilobites occurred as these ferruginous waters impinged on the shelf

Composition of continental crust altered by the emergence of land plants

Acknowledgements This paper benefited greatly from discussions with B. Keller. C.J.S., X.W. and M.S. were supported by the Natural Sciences and Environment Research Council, Discovery Grant RGPIN-2020-05639. T.R.I.M. was supported by the Natural Sciences and Environment Research Council, Undergraduate Student Research Award 551207 – 2020 with additional funding provided by L. Godin. T.M.G. and T.H. were supported by the Turing Institute under the EPSRC grant EP/N510129/1. N.S.D. and W.J.M. were supported by NERC grant NE/T00696X. G.-M.L. acknowledges support from the State Scholarship Fund of China Scholarship Council (202006410023).Peer reviewedPostprin

A 2200-year record of Andean Condor diet and nest site usage reflects natural and anthropogenic stressors

Understanding how animals respond to large-scale environmental changes is difficult to achieve because monitoring data are rarely available for more than the past few decades, if at all. Here, we demonstrate how a variety of palaeoecological proxies (e.g. isotopes, geochemistry and DNA) from an Andean Condor (Vultur gryphus) guano deposit from Argentina can be used to explore breeding site fidelity and the impacts of environmental changes on avian behaviour. We found that condors used the nesting site since at least approximately 2200 years ago, with an approximately 1000-year nesting frequency slowdown from ca 1650 to 650 years before the present (yr BP). We provide evidence that the nesting slowdown coincided with a period of increased volcanic activity in the nearby Southern Volcanic Zone, which resulted in decreased availability of carrion and deterred scavenging birds. After returning to the nest site ca 650 yr BP, condor diet shifted from the carrion of native species and beached marine animals to the carrion of livestock (e.g. sheep and cattle) and exotic herbivores (e.g. red deer and European hare) introduced by European settlers. Currently, Andean Condors have elevated lead concentrations in their guano compared to the past, which is associated with human persecution linked to the shift in diet.Fil: Duda, Matthew P.. Queen's University; CanadáFil: Grooms, Christopher. Queen's University; CanadáFil: Sympson, Lorenzo. Sociedad Naturalista Andino Patagonica; ArgentinaFil: Blais, Jules M.. University of Ottawa; CanadáFil: Dagodzo, Daniel. University of Ottawa; CanadáFil: Feng, Wenxi. Queen's University; CanadáFil: Hayward, Kristen M.. Queen's University; CanadáFil: Julius, Matthew L.. St. Cloud State University; Estados UnidosFil: Kimpe, Linda E.. University of Ottawa; CanadáFil: Lambertucci, Sergio Agustin. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte. Instituto de Investigaciones en Biodiversidad y Medioambiente. Universidad Nacional del Comahue. Centro Regional Universidad Bariloche. Instituto de Investigaciones en Biodiversidad y Medioambiente; ArgentinaFil: Layton Matthews, Daniel. Queen's University; CanadáFil: Lougheed, Stephen. Queen's University; CanadáFil: Massaferro, Julieta. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte. Instituto de Investigaciones en Biodiversidad y Medioambiente. Universidad Nacional del Comahue. Centro Regional Universidad Bariloche. Instituto de Investigaciones en Biodiversidad y Medioambiente; ArgentinaFil: Michelutti, Neal. Queen's University; CanadáFil: Pufahl, Peir K.. Queen's University; CanadáFil: Vuletich, April. Queen's University; CanadáFil: Smol, John P.. Queen's University; Canad

The sedimentology and geochemistry of phosphatic and associated strata in Jordan : implications for phosphogenesis and the formation of economic phosphorite

Sedimentary, authigenic, and biological processes are preserved within the Upper Cretaceous (Campanian) Alhisa Phosphorite Formation (AP) in central and northern Jordan. The AP formed near the eastern extremity of the South Tethyan Phosphorite Province (STPP), a carbonate-dominated Upper Cretaceous to Eocene "phosphorite giant" that extends from Colombia, North Africa to the Middle East. Multidisciplinary research of the AP and associated cherts, chalks, and oyster buildups indicate that phosphatic strata formed on a highly productive, storm-dominated, east-west trending epeiric platform along the south Tethyan margin. The onset of phosphogenesis and the accumulation of economic phosphorite coincided with a rise in relative sea level that onlapped peri tidal carbonates of the Ajlun Group. Authigenic precipitation of phosphate occurred in a broad array of sedimentary environments - herein termed a "phosphorite nursery" - that spanned the entire platform. Sedimentologic data indicate that pristine phosphates were concentrated into phosphatic grainstones through storm wave winnowing, and storm-generated, shelf-parallel geostrophic currents. Economic phosphorites formed through the amalgamation of storm-induced event beds. Stratigraphic packaging of phosphatic strata indicates that temporal variations in storm frequency were a prerequisite for the formation of economic phosphorite. Syndepositional phosphogenesis, reworking, and amalgamation to form phosphorites contrasts sharply with the concepts of "Baturin Cycling". A transgressive systems tract coupled with high surface productivity created detritally starved settings for the establishment of a "phosphorite nursery" and amalgamation of storm-generated event beds formed economic phosphorite within a single systems tract. Coated phosphate grains were investigated to elucidate the processes governing phosphogenesis. Stable isotopic data (813Ccarbonate fiuorapatite) indicate that coated grains precipitated in association with the suboxic to anoxic microbial respiration of organic matter. The microstratigraphies of some grains suggest that phosphogenesis is commonly accompanied by changes in pore water redox chemistry. These changes reflect fluctuations in the biological oxygen demand within suboxic pore water environments resulting from variations in the surface productivity and/or ecological dynamics in the overlying water column. Coated phosphate grains record low and/or net negative sediment accumulation rates and are the granular equivalent to condensed beds. The trace element chemistry (Mg and Sr) of skeletal calcite from the Cretaceous oyster, Oscillopha figari was analyzed in sclerochronological profile in order to determine the temperature and salinity regime that prevailed over the Jordanian shelf. Although there is significant uncertainty in interpreting the data, the results provide clear objectives for future research, and support sedimentologic evidence that suggests oysters developed on a productive epeiric platform that experienced periods of intense upwelling.Science, Faculty ofEarth, Ocean and Atmospheric Sciences, Department ofGraduat