Supplementary material for the article: Rančić, M. P.; Stojiljković, I.; Milošević, M.; Prlainović, N.; Jovanović, M.; Milčić, M. K.; Marinković, A. D. Solvent and Substituent Effect on Intramolecular Charge Transfer in 5-Arylidene-3-Substituted-2,4-Thiazolidinediones: Experimental and Theoretical Study, 2016. https://doi.org/10.1016/j.arabjc.2016.12.013

Supplementary material for: [https://doi.org/10.1016/j.arabjc.2016.12.013]Related to published version: [http://cherry.chem.bg.ac.rs/handle/123456789/305

Supplementary material for the article: Milošević, M. D.; Prlainović, N. Ž.; Milčić, M.; Nikolić, V.; Božić, A.; Bigović, M.; Marinković, A. D. Solvent, Structural, Quantum Chemical Study and Antioxidative Activity of Symmetrical 1-Methyl-2,6-Bis[2-(Substituted Phenyl)Ethenyl]Pyridinium Iodides. Journal of the Iranian Chemical Society 2018, 15 (11), 2483–2501. https://doi.org/10.1007/s13738-018-1437-5

Supplementary material for: [https://doi.org/10.1007/s13738-018-1437-5]Related to published version: [http://cherry.chem.bg.ac.rs/handle/123456789/2216

Supplementary material for the article: Rančić, M. P.; Stojiljković, I.; Milošević, M.; Prlainović, N.; Jovanović, M.; Milčić, M. K.; Marinković, A. D. Solvent and Substituent Effect on Intramolecular Charge Transfer in 5-Arylidene-3-Substituted-2,4-Thiazolidinediones: Experimental and Theoretical Study, 2016. https://doi.org/10.1016/j.arabjc.2016.12.013

Supplementary material for: [https://doi.org/10.1016/j.arabjc.2016.12.013]Related to published version: [http://cherry.chem.bg.ac.rs/handle/123456789/305

Decolorization of anthraquinonic dyes from textile effluent using horseradish peroxidase: Optimization and kinetic study

Two anthraquinonic dyes, C.I. Acid Blue 225 and C.I. Acid Violet 109, were used as models to explore the feasibility of using the horseradish peroxidase enzyme (HRP) in the practical decolorization of anthraquinonic dyes in wastewater. The influence of process parameters such as enzyme concentration, hydrogen peroxide concentration, temperature, dye concentration, and pH was examined. The pH and temperature activity profiles were similar for decolorization of both dyes. Under the optimal conditions, 94.7% of C.I. Acid Violet 109 from aqueous solution was decolorized (treatment time 15 min, enzyme concentration 0.15 IU/mL, hydrogen peroxide concentration 0.4 mM, dye concentration 30 mg/L, pH 4, and temperature 24°C) and 89.36% of C.I. Acid Blue 225 (32 min, enzyme concentration 0.15 IU/mL, hydrogen peroxide concentration 0.04 mM, dye concentration 30 mg/L, pH 5, and temperature 24°C). The mechanism of both reactions has been proven to follow the two substrate ping-pong mechanism with substrate inhibition, revealing the formation of a nonproductive or dead-end complex between dye and HRP or between Hand the oxidized form of the enzyme. Both chemical oxygen demand and total organic carbon values showed that there was a reduction in toxicity after the enzymatic treatment. This study verifies the viability of use of horseradish peroxidase for the wastewaters treatment of similar anthraquinonic dyes

DEVER DE FUNDAMENTAÇÃO NO NOVO CÓDIGO DE PROCESSO CIVIL E OS PRECEDENTES VINCULANTES

O novo CPC instituiu um modelo de precedentes vinculantes, com aproximação do sistema jurídico dos países da common law. O legislador já vinha buscando a transformação do STF e do STJ de cortes superiores em cortes supremas, com a transição do exercício da função de controle do julgamento no caso concreto para a garantia de uniformidade da intepretação do direito. Assume, então, especial importância o dever de fundamentação, que vem disciplinado no seu artigo 489, permitindo o manejo do sistema de vinculação, com a adequada formação e aplicação dos precedentes. Procura-se, pois, lançar luzes sobre conceitos inerentes ao trabalho com precedentes obrigatórios, sobretudo, sobre aqueles incutidos na ordem jurídica pelo novo CPC, que se tratam da ratio decidendi, do distinguishing e do overruling