Enhanced metal adsorption on solid suspensions by organic molecules

International audienceThis laboratory study mimicked the pollution of a suspension of silica beads, used as a crude model of sand, by naphthalene in mixture with carbofuran at first, and then by this mixture in association with a metal salt, Pb(NO(3))(2). The silica properties and the working conditions were such that they allowed us to only observe physisorption, which is the first and essential step of any adsorption mechanism. Naphthalene and carbofuran were, respectively, chosen as hydrocarbon and pesticide. Naphthalene adsorption from simple solutions is rather large compared to other organic adsorptions, and carbofuran seems to adsorb on a layer of naphthalene when the latter is mixed in solution with carbofuran. Like other organics, naphthalene favours the adsorption of lead ions, but ionic adsorption is considerably increased by the combination of naphthalene and carbofuran. The Wagner-Onsager-Samaras theory shows that the result implies a special organization of organic molecules at the interface. Conclusions about some environmental mechanisms of fixation, or release, of ions on sands in the case of simple physisorption are drawn from the study

Coadsorption at the air/water interface as source of pollutant transfer to the atmosphere: The case study of benzene/cyclohexane traces and lead

cited By 9International audienceThe possible occurrence of polluted aerosols formed by a bubbling mechanism from hydrocarbon-rich aqueous surface layers was investigated in laboratory through the determination of hydrocarbon adsorption from diluted solutions. Benzene and cyclohexane both exhibited positive adsorption. Further to our previous demonstration of lead nitrate coadsorption with benzene near the solubility limit (Sadiki et al., 2003. Atmospheric Environment 37, 3551-3559) the present study revealed a positive coadsorption of lead nitrate with both hydrocarbons, even in diluted solutions. The use of the bubble-column (Wan, Tokunaga, 1998. Environment Science and Technology 32, 3293-3298) as an experimental tool is discussed as well as the physico-chemical mechanisms involved in adsorption and coadsorption processes with their impact on the environment. © 2005 Elsevier Ltd. All rights reserved