Polymorphism in metal complexes of thiazole-4-carboxylic acid

Five new molecular complexes of chemical formula [M(4-tza)₂(H₂O)₂] (M = Co, Ni, and Cu) and a complex of [Cu(4-tza)₂]∙4H₂O using thiazole-4-carboxylic acid (4-tza) as the ligand have been successfully synthesized and structurally characterized by single crystal X-ray diffraction. Two district polymorphs (α and β) are found for both [Co(4-tza)₂(H₂O)₂] and [Ni(4-tza)₂(H₂O)₂]. The effects of solvent composition and temperature on the formation of these polymorphs have been investigated and phase behaviour of the polymorphs was studied through X-ray powder diffraction. Unlike two complexes of Co and Ni, [Cu(4-tza)₂(H₂O)₂] does not display polymorphism but exhibits irreversible structural transformation from [Cu(4-tza)₂(H₂O)₂] to the dehydrated form, [Cu(4-tza)₂], upon heating

Empirical measurements of small unmanned aerial vehicle co-axial rotor systems.

Small unmanned aerial vehicles (SUAV) are beginning to dominate the area of intelligence, surveillance, target acquisition and reconnaissance (ISTAR) in forward operating battlefield scenarios. Of particular interest are vertical take-off and landing (VTOL) variants. Within this category co-axial rotor designs have been adopted due to their inherent advantages of size and power to weight ratio. The inter-rotor spacing attribute of a co-axial rotor system appears to offer insight into the optimum design characteristic. The H/D ratio has been cited as a significant factor in many research papers, but to date has lacked an empirical value or an optimal dimensionless condition. In this paper the H/D ratio of a SUAV has been explored thoroughly, reviewing the performance of these systems at incremental stages, the findings from this study have shown that a range of H/D ratios in the region of (0.41-0.65) is advantageous in the performance of SUAV systems. This finding lends itself to the theory of inter-rotor spacing as a non-dimensionally similar figure, which cannot be applied across a spectrum of systems; this could be attributed to the viscous losses of flight at low Reynolds Numbers (< 50,000)

Microwave-assisted hydrothermal synthesis of carbon monolith via a soft-template method using resorcinol and formaldehyde as carbon precursor and pluronic F127 as template

A new microwave-assisted hydrothermal synthesis of carbon monolith is reported in this work. The process uses microwave heating at 100 °C under acidic condition by employing a triblock copolymer F127 as the template, and resorcinol–formaldehyde as the carbon precursor. Scanning electron microscopy, Fourier transform infrared spectroscopy, nitrogen sorption measurements, transmission electron microscopy, X-ray studies and thermogravimetic analysis were used to characterize the synthesized material. The carbon monolith is crack-free, mesoporous and has a high surface area of 697 m²/g. The results demonstrate that the microwave-assisted hydrothermal synthesis is a fast and simple approach to obtain carbon monoliths, as it reduces effectively the synthesis time from hours to a few minutes which could be an advantage in the large scale production of the material

Allostatic load and exposure histories of disadvantage

The stress pathway posits that those in disadvantaged circumstances are exposed to a higher degree of stressful experiences over time resulting in an accumulated biological burden which subsequently relates to poorer health. Trajectories of disadvantage, in the form of neighbourhood deprivation and structural social capital, are evaluated in their relation to allostatic load representing the cumulative “wear and tear” of chronic stress. This paper uses data from the British Household Panel Survey and Understanding Society in a latent class growth analysis. We identify groups of exposure trajectories over time using these classes to predict allostatic load at the final wave. The results show that persistent exposure to higher deprivation is related to worse allostatic load. High structural social capital over time relates to lower allostatic load, in line with a stress buffering effect, though this relationship is not robust to controlling for individual sociodemographic characteristics. By demonstrating a gradient in allostatic load by histories of deprivation, this analysis supports a biological embedding of disadvantage through chronic exposure to stressful environments as an explanation for social health inequalities

Charles Lummis: Spanish Knight-Errant

Charles Lummis was a complicated and contradictory figure in the American Southwest. He was a classmate of Theodore Roosevelt at Harvard, and later an unofficial advisor to the president in the matter of American Indian issues; He took on the Albuquerque Indian School and helped found the Sequoya League, a group that fought for Indian rights and assisted in the purchase of land for a California tribe after they had been evicted from their home. Charles Lummis was also a major force in cultural preservation, working to save the California missions, through his group, the Landmarks Club. He was a controversial figure in all aspects of his life, making as many enemies as friends. Although largely ignored by many historians, his impact upon the American Southwest and California is still felt in the region today. Since his death in 1928, historians have analyzed his life and work, focusing on aspects such as his Indian rights activism, his cultural preservation work, as well as his tenure as Los Angeles City Librarian. While the scholarship has been limited, the majority has focused on his cultural preservation and Indian activism. However, there is a significant intersection where these two aspects of Lummis’s work met and that has not been explored by many researchers. This is especially true when considering Lummis’s favorability of the Spanish over the American Indians. He believed that the scholarship about the Spanish conquest of the New World was incorrect, and sought to revise the story of how the Spanish took control over the Americas and the natives that inhabited it. However, Lummis’s dedication to the positive Spanish heritage of the American Southwest often stood in contradiction against his activism for the rights of American Indians and the celebration of their cultural history. Charles Lummis sought ways to celebrate the Spanish legacy in the American Southwest and return the region to a time of romance, heroism and chivalry, much like the fictional Don Quixote

Distribution of Genotypes Within and Among \u3cem\u3eTaeniatherum caput-medusae\u3c/em\u3e (Poaceae) Populations from Eastern Washington: Assessment of an Invasion at a Local Scale

Multiple introductions from many source populations can increase the chance of introducing preadapted genotypes, increase standing genetic variation, and increase the likelihood of adaptive evolution, all of which might contribute to invasion. Taeniatherum caput-medusae is an annual, highly self-pollinating grass that is invasive in the western United States. Through previous genetic analysis, five multilocus genotypes (MLG) were detected in the relatively small geographic area of eastern Washington, which suggests that multiple introductions have occurred in this region. Fifty-seven populations of T. caput-medusae from eastern Washington were assessed at 23 loci using starch gel electrophoresis. Based on these data, a sixth MLG was detected in the study area. The Steptoe Butte genotype, which was first introduced in 1901, has the largest range of the six genotypes and is creating polymorphic populations where it comes into contact with other genotypes. Founder effects appear to have reduced genetic diversity within and among populations from eastern Washington in comparison to native populations. The results of this study contribute to our understanding of the invasion process at a local spatial scale by reconstructing the introduction and range expansion of T. caput-medusae in eastern Washington