A transient computational fluid dynamic study of a laboratory-sclale fluorine electrolysis cell

Fluorine gas is produced industrially by electrolysing hydrogen fluoride in a potassium acid fluoride electrolyte. Fluorine is produced at the carbon anode, while hydrogen is produced at the mild-steel cathode. The fluorine produced has a wide range of uses, most notably in the nuclear industry where it is used to separate 235U and 238U. The South African Nuclear Energy Corporation (Necsa) is a producer of fluorine and requested an investigation into the hydrodynamics of their electrolysis cells as part of a larger national initiative to beneficiate more of South Africa’s large fluorspar deposits. Due to the extremely corrosive and toxic environment inside a typical fluorine electrolysis reactor, the fluid dynamics in the reactor are not understood well enough. The harsh conditions make detailed experimental investigation of the reactors extremely dangerous. The objective of this project is to construct a model that can accurately predict the physical processes involved in the production of fluorine gas. The results of the simulation will be compared to experimental results from tests done on a lab-scale reactor. A good correlation between reality and the simulacrum would mean engineers and designers can interrogate the inner operation of said reactors safely, effortlessly and economically. This contribution reports a time-dependent simulation of a fluorine-producing electrolysis reactor. COMSOL Multiphysics was used as a tool to construct a two dimensional model where the charge-, heat-, mass- and momentum transfer were fully coupled in one transient simulation. COMSOL is a finite element analysis software package. It enables the user to specify the dimensions of his/her investigation and specify a set of partial differential equations, boundary conditions and starting values. These equations can be coupled to ensure that the complex interaction between the various physical phenomena can be taken into account - an absolute necessity in a model as complex as this one. Results produced include a set of time dependent graphics where the charge-, heat-, mass- and momentum transfer inside the reactor and their development can be visualized clearly. The average liquid velocity in the reactor was also simulated and it was found that this value stabilises after around 90 s. The results of each transfer module are also shown at 100 s, where it is assumed that the simulation has achieved a quasi-steady state. The reactor, on which the model is based, is currently under construction and will be operated under the same conditions as specified in the model. The reactor, constructed of stainless steel, has a transparent side window through which both electrodes can clearly be seen. Thus the bubble formation and flow in the reactor can be studied effectively. Temperature will be measured with a set of thermocouples imbedded in PTFE throughout the reactor. The electric field will similarly be measured using electric induction probes.Dissertation (MEng)--University of Pretoria, 2012.Chemical Engineeringunrestricte

Fluorination of neodymium carbonate monohydrate with anhydrous hydrogen fluoride in a Carberry spinning-basket reactor

Please read abstract in the article.The South African National Research Foundation (NRF) and the Department of Science and Technology (DST) under the Fluorochemical Expansion Initiative (FEI).http://rsc.li/reaction-engineering2020-08-01hj2019Chemical Engineerin

Understanding continent-wide variation in vulture ranging behavior to assess feasibility of Vulture Safe Zones in Africa: Challenges and possibilities

Protected areas are intended as tools in reducing threats to wildlife and preserving habitat for their long-term population persistence. Studies on ranging behavior provide insight into the utility of protected areas. Vultures are one of the fastest declining groups of birds globally and are popular subjects for telemetry studies, but continent-wide studies are lacking. To address how vultures use space and identify the areas and location of possible vulture safe zones, we assess home range size and their overlap with protected areas by species, age, breeding status, season, and region using a large continent-wide telemetry datasets that includes 163 individuals of three species of threatened Gyps vulture. Immature vultures of all three species had larger home ranges and used a greater area outside of protected areas than breeding and non-breeding adults. Cape vultures had the smallest home range sizes and the lowest level of overlap with protected areas. Rüppell\u27s vultures had larger home range sizes in the wet season, when poisoning may increase due to human-carnivore conflict. Overall, our study suggests challenges for the creation of Vulture Safe Zones to protect African vultures. At a minimum, areas of 24,000 km2 would be needed to protect the entire range of an adult African White-backed vulture and areas of more than 75,000 km2 for wider-ranging Rüppell\u27s vultures. Vulture Safe Zones in Africa would generally need to be larger than existing protected areas, which would require widespread conservation activities outside of protected areas to be successful

A multiphysics simulation of a fluorine electrolysis cell

We modelled a laboratory-scale fluorine reactor which employed fully coupled, fundamental electron, heat, mass and momentum transfer (two-phase) equations to deliver a transient simulation. Hydrodynamic quasisteady-state results were produced for the current density, electric field, temperature, reactive species concentration, gas and liquid velocity profiles as well as gas fraction distribution within the reactor. Simulation results were verified by modelling and comparing models from published works on similar reactors, as the laboratory-scale reactor is still in construction phase. Comparisons were favourable

Understanding continent-wide variation in vulture ranging behavior to assess feasibility of Vulture Safe Zones in Africa:challenges and possibilities

Protected areas are intended as tools in reducing threats to wildlife and preserving habitat for their long-term population persistence. Studies on ranging behavior provide insight into the utility of protected areas. Vultures are one of the fastest declining groups of birds globally and are popular subjects for telemetry studies, but continent-wide studies are lacking. To address how vultures use space and identify the areas and location of possible vulture safe zones, we assess home range size and their overlap with protected areas by species, age, breeding status, season, and region using a large continent-wide telemetry datasets that includes 163 individuals of three species of threatened Gyps vulture. Immature vultures of all three species had larger home ranges and used a greater area outside of protected areas than breeding and non-breeding adults. Cape vultures had the smallest home range sizes and the lowest level of overlap with protected areas. Rüppell's vultures had larger home range sizes in the wet season, when poisoning may increase due to human-carnivore conflict. Overall, our study suggests challenges for the creation of Vulture Safe Zones to protect African vultures. At a minimum, areas of 24,000 km2 would be needed to protect the entire range of an adult African White-backed vulture and areas of more than 75,000 km2 for wider-ranging Rüppell's vultures. Vulture Safe Zones in Africa would generally need to be larger than existing protected areas, which would require widespread conservation activities outside of protected areas to be successful

Understanding continent-wide variation in vulture ranging behavior to assess feasibility of vulture safe zones in Africa : challenges and possibilities

Protected areas are intended as tools in reducing threats to wildlife and preserving habitat for their long-term population persistence. Studies on ranging behavior provide insight into the utility of protected areas. Vultures are one of the fastest declining groups of birds globally and are popular subjects for telemetry studies, but continent-wide studies are lacking. To address how vultures use space and identify the areas and location of possible vulture safe zones, we assess home range size and their overlap with protected areas by species, age, breeding status, season, and region using a large continent-wide telemetry datasets that includes 163 individuals of three species of threatened Gyps vulture. Immature vultures of all three species had larger home ranges and used a greater area outside of protected areas than breeding and non-breeding adults. Cape vultures had the smallest home range sizes and the lowest level of overlap with protected areas. Rüppell's vultures had larger home range sizes in the wet season, when poisoning may increase due to human-carnivore conflict. Overall, our study suggests challenges for the creation of Vulture Safe Zones to protect African vultures. At a minimum, areas of 24,000 km2 would be needed to protect the entire range of an adult African White-backed vulture and areas of more than 75,000 km2 for wider-ranging Rüppell's vultures. Vulture Safe Zones in Africa would generally need to be larger than existing protected areas, which would require widespread conservation activities outside of protected areas to be successful.North Carolina Zoo; Wildlife Conservation Society; Association of Zoos and Aquariums (AZA), AZA SAFE (Saving Animals From Extinction), Dallas Zoo, Disney Conservation Fund, Leiden Conservation Foundation, National Geographic Society, Taronga Conservation Society Australia, and The Mohamed bin Zayed Species Conservation Fund.https://www.elsevier.com/locate/biocon2024-03-16hj2022Mammal Research InstituteZoology and Entomolog