Effects of surface crossing in chemical reactions - The H3/plus/ system

Potential energy surfaces for singlet states of H3/plus

Light-cone coordinates based at a geodesic world line

Continuing work initiated in an earlier publication [Phys. Rev. D 69, 084007 (2004)], we construct a system of light-cone coordinates based at a geodesic world line of an arbitrary curved spacetime. The construction involves (i) an advanced-time or a retarded-time coordinate that labels past or future light cones centered on the world line, (ii) a radial coordinate that is an affine parameter on the null generators of these light cones, and (iii) angular coordinates that are constant on each generator. The spacetime metric is calculated in the light-cone coordinates, and it is expressed as an expansion in powers of the radial coordinate in terms of the irreducible components of the Riemann tensor evaluated on the world line. The formalism is illustrated in two simple applications, the first involving a comoving world line of a spatially-flat cosmology, the other featuring an observer placed on the axis of symmetry of Melvin's magnetic universe.Comment: 11 pages, 1 figur

Feshbach Resonances and Limiting Thermodynamics of Strongly Correlated Nucleons

A finite temperature model of strongly correlated nucleons with underlying isospin symmetries is developed. The model can be used to study the role of bound states and Feshbach resonances on the thermal properties of a spin 1/2, isospin 1/2 system of protons and neutrons by varying the proton fraction. An analysis of features associated with a universal thermodynamic limit or unitary limit is given. In the limit of very large scattering length, the effective range to quantum thermal wavelength appears as a limiting scale in an interaction energy and equation of state.Comment: 8 pages, 4 figure

Local Projections of Low-Momentum Potentials

Nuclear interactions evolved via renormalization group methods to lower resolution become increasingly non-local (off-diagonal in coordinate space) as they are softened. This inhibits both the development of intuition about the interactions and their use with some methods for solving the quantum many-body problem. By applying "local projections", a softened interaction can be reduced to a local effective interaction plus a non-local residual interaction. At the two-body level, a local projection after similarity renormalization group (SRG) evolution manifests the elimination of short-range repulsive cores and the flow toward universal low-momentum interactions. The SRG residual interaction is found to be relatively weak at low energy, which motivates a perturbative treatment

A study of Feshbach resonances and the unitary limit in a model of strongly correlated nucleons

A model of strongly interacting and correlated hadrons is developed. The interaction used contains a long range attraction and short range repulsive hard core. Using this interaction and various limiting situations of it, a study of the effect of bound states and Feshbach resonances is given. The limiting situations are a pure square well interaction, a delta-shell potential and a pure hard core potential. The limit of a pure hard core potential are compared with results for a spinless Bose and Fermi gas. The limit of many partial waves for a pure hard core interaction is also considered and result in expressions involving the hard core volume. This feature arises from a scaling relation similar to that for hard sphere scattering with diffractive corrections. The role of underlying isospin symmetries associated with the strong interaction of protons and neutrons in this two component model is investigated. Properties are studied with varying proton fraction. An analytic expression for the Beth Uhlenbeck continuum integral is developed which closely approximates exact results based on the potential model considered. An analysis of features associated with a unitary limit is given. In the unitary limit of very large scattering length, the ratio of effective range to thermal wavelength appears as a limiting scale. Thermodynamic quantities such as the entropy and compressibility are also developed. The effective range corrections to the entropy vary as the cube of this ratio for low temperatures and are therefore considerably reduced compared to the corrections to the interaction energy which varies linearly with this ratio. Effective range corrections to the compressibility are also linear in the ratio.Comment: 39 pages, 15 figures, 2 table

A Research-Based Curriculum for Teaching the Photoelectric Effect

Physics faculty consider the photoelectric effect important, but many erroneously believe it is easy for students to understand. We have developed curriculum on this topic including an interactive computer simulation, interactive lectures with peer instruction, and conceptual and mathematical homework problems. Our curriculum addresses established student difficulties and is designed to achieve two learning goals, for students to be able to (1) correctly predict the results of photoelectric effect experiments, and (2) describe how these results lead to the photon model of light. We designed two exam questions to test these learning goals. Our instruction leads to better student mastery of the first goal than either traditional instruction or previous reformed instruction, with approximately 85% of students correctly predicting the results of changes to the experimental conditions. On the question designed to test the second goal, most students are able to correctly state both the observations made in the photoelectric effect experiment and the inferences that can be made from these observations, but are less successful in drawing a clear logical connection between the observations and inferences. This is likely a symptom of a more general lack of the reasoning skills to logically draw inferences from observations.Comment: submitted to American Journal of Physic

Evaluation of rations used in performance testing of bulls and steers

Cover title.Includes bibliographical references

Infrared Spectroscopic Detection of Biosignatures at Lake Tírez, Spain: Implications for Mars

The detection of potential biosignatures with mineral matrices is part of a multifaceted approach in the search for life on other planetary bodies. The 2020 ExoMars Rosalind Franklin rover includes within its payload three IR spectrometers in the form of ISEM (Infrared Spectrometer for ExoMars), MicrOmega, and Ma-MISS (Mars Multispectral Imager for Subsurface Studies). The use of this technique in the detection and characterization of biosignatures is of great value. Organic materials are often co-deposited in terrestrial evaporites and as such have been proposed as relevant analogs in the search for life on Mars. This study focuses on Ca-sulfates collected from the hypersaline Tírez Lake in Spain. Mid infrared and visible near infrared analysis of soils, salt crusts, and crystals with green and red layering indicative of microbial colonization of the samples was acquired from across the lake and identified the main mineral to be gypsum with inputs of carbonate and silica. Organic functional groups that could be attributed to amides and carboxylic acids were identified as well as chlorophyll; however, due to the strong mineralogical absorptions observed, these were hard to unambiguously discern. Taxonomical assignment demonstrated that the archaeal community within the samples was dominated by the halophilic extremophile Halobacteriaceae while the bacterial community was dominated by the class Nocardiaceae. The results of this research highlight that sulfates on Mars are a mixed blessing, acting as an effective host for organic matter preservation but also a material that masks the presence of organic functional groups when analyzed with spectroscopic tools similar to those due to fly on the 2020 ExoMars rover. A suite of complementary analytical techniques therefore should be used to support the spectral identification of any candidate extraterrestrial biosignatures

ESR spectra of PF_2 and SF_3 radicals

[No abstract