5 research outputs found
Facile production of nanocomposites of carbon nanotubes and polycaprolactone with high aspect ratios with potential applications in drug delivery
Facile route to polymer carbon nanotube nanocomposites.</p
CCDC 1006811: Experimental Crystal Structure Determination
An entry from the Cambridge Structural Database, the worldâs repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available from the CCDC and typically includes 3D coordinates, cell parameters, space group, experimental conditions and quality measures
Chemical and structural stability of zirconium-based metal-organic frameworks with large three-dimensional pores by linker engineering
The synthesis of metalâorganic frameworks with large three-dimensional channels that are permanently porous and chemically stable offers new opportunities in areas such as catalysis and separation. Two linkers (L1=4,4â˛,4â˛â˛,4â˛â˛â˛-([1,1â˛-biphenyl]-3,3â˛,5,5â˛-tetrayltetrakis(ethyne-2,1-diyl)) tetrabenzoic acid, L2=4,4â˛,4â˛â˛,4â˛â˛â˛-(pyrene-1,3,6,8-tetrayltetrakis(ethyne-2,1-diyl))tetrabenzoic acid) were used that have equivalent connectivity and dimensions but quite distinct torsional flexibility. With these, a solid solution material, [Zr6O4(OH)4(L1)2.6(L2)0.4]â
(solvent)x, was formed that has three-dimensional crystalline permanent porosity with a surface area of over 4000â
m2âgâ1Â that persists after immersion in water. These properties are not accessible for the isostructural phases made from the separate single linkers. Â </p
CCDC 1006810: Experimental Crystal Structure Determination
An entry from the Cambridge Structural Database, the worldâs repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available from the CCDC and typically includes 3D coordinates, cell parameters, space group, experimental conditions and quality measures