13,416 research outputs found
Monomers for thermosetting and toughening epoxy resins
Eight glycidyl amines were prepared by alkylating the parent amine with epichlorohydrin to form chlorohydrin, followed by cyclization with aqueous NaOH. Three of these compounds contained propargyl groups with postcuring studies. A procedure for quantitatively estimating the epoxy content of these glycidyl amines was employed for purity determination. Two diamond carbonates and several model propargly compounds were prepared. The synthesis of three new diamines, two which contain propargyloxy groups, and another with a sec-butyl group is in progress. These materials are at the dinitro stage ready for the final hydrogenation step. Four aromatic diamines were synthesized for mutagenic testing purposes. One of these compounds rapidly decomposes on exposure to air
Fabrication process of a high temperature polymer matrix engine duct
The process that was used in the molding of an advanced composite outer by-pass duct planned for the F404 engine is discussed. This duct was developed as a potential replacement for the existing titanium duct in order to reduce both the weight and cost of the duct. The composite duct is now going into the manufacturing technology portion of the program. The duct is fabricated using graphite cloth impregnated with the PMR-15 matrix system
Balancing Local Order and Long-Ranged Interactions in the Molecular Theory of Liquid Water
A molecular theory of liquid water is identified and studied on the basis of
computer simulation of the TIP3P model of liquid water. This theory would be
exact for models of liquid water in which the intermolecular interactions
vanish outside a finite spatial range, and therefore provides a precise
analysis tool for investigating the effects of longer-ranged intermolecular
interactions. We show how local order can be introduced through quasi-chemical
theory. Long-ranged interactions are characterized generally by a conditional
distribution of binding energies, and this formulation is interpreted as a
regularization of the primitive statistical thermodynamic problem. These
binding-energy distributions for liquid water are observed to be unimodal. The
gaussian approximation proposed is remarkably successful in predicting the
Gibbs free energy and the molar entropy of liquid water, as judged by
comparison with numerically exact results. The remaining discrepancies are
subtle quantitative problems that do have significant consequences for the
thermodynamic properties that distinguish water from many other liquids. The
basic subtlety of liquid water is found then in the competition of several
effects which must be quantitatively balanced for realistic results.Comment: 8 pages, 6 figure
Investigation of the effects of short chain processing additives on polymers
The effects of low level concentrations of several short chain processing additives on the properties of the 4,4'-bis(3,4-dicarboxyphenoxy) diphenylsulfide dianhydride (BDSDA)/4,4'-diaminodiphenyl ether (ODA)/1,3'-diaminobenzene (m-phenylene diamine) (MPA) (422) copolyimide were investigated. It was noted that 5 percent MPD/phthalic anhydride (PA) is more effective than 5 percent ODA/PA and BDSDA/aniline (AN) in strengthening the host material. However, the introduction of 10 percent BDSDA/AN produces disproportionately high effects on free volume and free electron density in the host copolyimide
Structure/permeability relationships of silicon-containing polyimides
The permeability to H2, O2, N2, CO2 and CH4 of three silicone-polyimide random copolymers and two polyimides containing silicon atoms in their backbone chains, was determined at 35.0 C and at pressures up to about 120 psig (approximately 8.2 atm). The copolymers contained different amounts of BPADA-m-PDA and amine-terminated poly (dimethyl siloxane) and also had different numbers of siloxane linkages in their silicone component. The polyimides containing silicon atoms (silicon-modified polyimides) were SiDA-4,4'-ODA and SiDA-p-PDA. The gas permeability and selectivity of the copolymers are more similar to those of their silicone component than of the polyimide component. By contrast, the permeability and selectivity of the silicon-modified polyimides are more similar to those of their parent polyimides, PMDA-4,4'-ODA and SiDA-p-PDA. The substitution of SiDA for the PMDA moiety in a polyimide appears to result in a significant increase in gas permeability, without a correspondingly large decrease in selectivity. The potential usefulness of the above polymers and copolymers as gas separation membranes is discussed
Hydration and mobility of HO-(aq)
The hydroxide anion plays an essential role in many chemical and biochemical
reactions. But a molecular-scale description of its hydration state, and hence
also its transport, in water is currently controversial. The statistical
mechanical quasi-chemical theory of solutions suggests that HO[H2O]3- is the
predominant species in the aqueous phase under standard conditions. This result
is in close agreement with recent spectroscopic studies on hydroxide water
clusters, and with the available thermodynamic hydration free energies. In
contrast, a recent ab initio molecular dynamics simulation has suggested that
HO[H_2O]4- is the only dominant aqueous solution species. We apply adiabatic ab
initio molecular dynamics simulations, and find good agreement with both the
quasi-chemical theoretical predictions and experimental results. The present
results suggest a picture that is simpler, more traditional, but with
additional subtlety. These coordination structures are labile but the
tri-coordinate species is the prominent case. This conclusion is unaltered with
changes in the electronic density functional. No evidence is found for
rate-determining activated inter-conversion of a HO[H2O]4- trap structure to
HO[H2O]3-, mediating hydroxide transport. The view of HO- diffusion as the
hopping of a proton hole has substantial validity, the rate depending largely
on the dynamic disorder of the water hydrogen-bond network.Comment: 7 pages, 5 figures, additional results include
XMM-Newton detection of two clusters of galaxies with strong SPT Sunyaev-Zel'dovich effect signatures
We report on the discovery of two galaxy clusters, SPT-CL J2332-5358 and
SPT-CL J2342-5411, in X-rays. These clusters were also independently detected
through their Sunyaev-Zel'dovich effect by the South Pole Telescope, and
confirmed in the optical band by the Blanco Cosmology Survey. They are thus the
first clusters detected under survey conditions by all major cluster search
approaches. The X-ray detection is made within the frame of the XMM-BCS cluster
survey utilizing a novel XMM-Newton mosaic mode of observations. The present
study makes the first scientific use of this operation mode. We estimate the
X-ray spectroscopic temperature of SPT-CL J2332-5358 (at redshift z=0.32) to T
= 9.3 (+3.3/-1.9) keV, implying a high mass, M_{500} = 8.8 +/- 3.8 \times
10^{14} M_{sun}. For SPT-CL J2342-5411, at z=1.08, the available X-ray data
doesn't allow us to directly estimate the temperature with good confidence.
However, using our measured luminosity and scaling relations we estimate that T
= 4.5 +/- 1.3 keV and M_{500} = 1.9 +/- 0.8 \times 10^{14} M_{sun}. We find a
good agreement between the X-ray masses and those estimated from the
Sunyaev-Zel'dovich effect.Comment: Submitted to A&A, 8 pages, 5 figures, 1 tabl
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