13,183 research outputs found
Structure/permeability relationships of silicon-containing polyimides
The permeability to H2, O2, N2, CO2 and CH4 of three silicone-polyimide random copolymers and two polyimides containing silicon atoms in their backbone chains, was determined at 35.0 C and at pressures up to about 120 psig (approximately 8.2 atm). The copolymers contained different amounts of BPADA-m-PDA and amine-terminated poly (dimethyl siloxane) and also had different numbers of siloxane linkages in their silicone component. The polyimides containing silicon atoms (silicon-modified polyimides) were SiDA-4,4'-ODA and SiDA-p-PDA. The gas permeability and selectivity of the copolymers are more similar to those of their silicone component than of the polyimide component. By contrast, the permeability and selectivity of the silicon-modified polyimides are more similar to those of their parent polyimides, PMDA-4,4'-ODA and SiDA-p-PDA. The substitution of SiDA for the PMDA moiety in a polyimide appears to result in a significant increase in gas permeability, without a correspondingly large decrease in selectivity. The potential usefulness of the above polymers and copolymers as gas separation membranes is discussed
Molecular Realism in Default Models for Information Theories of Hydrophobic Effects
This letter considers several physical arguments about contributions to
hydrophobic hydration of inert gases, constructs default models to test them
within information theories, and gives information theory predictions using
those default models with moment information drawn from simulation of liquid
water. Tested physical features include: packing or steric effects, the role of
attractive forces that lower the solvent pressure, and the roughly tetrahedral
coordination of water molecules in liquid water. Packing effects (hard sphere
default model) and packing effects plus attractive forces (Lennard-Jones
default model) are ineffective in improving the prediction of hydrophobic
hydration free energies of inert gases over the previously used Gibbs and flat
default models. However, a conceptually simple cluster Poisson model that
incorporates tetrahedral coordination structure in the default model is one of
the better performers for these predictions. These results provide a partial
rationalization of the remarkable performance of the flat default model with
two moments in previous applications. The cluster Poisson default model thus
will be the subject of further refinement.Comment: 5 pages including 3 figure
Tsunamis, Viscosity and the HBT Puzzle
The equation of state and bulk and shear viscosities are shown to be able to
affect the transverse dynamics of a central heavy ion collision. The net
entropy, along with the femtoscopic radii are shown to be affected at the
10-20% level by both shear and bulk viscosity. The degree to which these
effects help build a tsunami-like pulse is also discussed.Comment: Contribution to SQM 2007 in Levoca, Slovaki
Final state interactions in two-particle interferometry
We reconsider the influence of two-particle final state interactions (FSI) on
two-particle Bose-Einstein interferometry. We concentrate in particular on the
problem of particle emission at different times. Assuming chaoticity of the
source, we derive a new general expression for the symmetrized two-particle
cross section. We discuss the approximations needed to derive from the general
result the Koonin-Pratt formula. Introducing a less stringent version of the
so-called smoothness approximation we also derive a more accurate formula. It
can be implemented into classical event generators and allows to calculate FSI
corrected two-particle correlation functions via modified Bose-Einstein
"weights".Comment: 12 pages RevTeX, 2 ps-figures included, submitted to Phys. Rev.
Towards the 3D-Imaging of Sources
Geometric details of a nuclear reaction zone, at the time of particle
emission, can be restored from low relative-velocity particle-correlations,
following imaging. Some of the source details get erased and are a potential
cause of problems in the imaging, in the form of instabilities. These can be
coped with by following the method of discretized optimization for the restored
sources. So far it has been possible to produce 1-dimensional emission source
images, corresponding to the reactions averaged over all possible spatial
directions. Currently, efforts are in progress to restore angular details.Comment: Talk given at the Int. Workshop on Hot and Dense Matter in
Relativistic Heavy Ion Collisions, March 24-27, 2004, Budapest; 10 pages, 6
figure
Isospin Fluctuations from a Thermally Equilibrated Hadron Gas
Partition functions, multiplicity distributions, and isospin fluctuations are
calculated for canonical ensembles in which additive quantum numbers as well as
total isospin are strictly conserved. When properly accounting for
Bose-Einstein symmetrization, the multiplicity distributions of neutral pions
in a pion gas are significantly broader as compared to the non-degenerate case.
Inclusion of resonances compensates for this broadening effect. Recursion
relations are derived which allow calculation of exact results with modest
computer time.Comment: 10 pages, 5 figure
The Quark-Gluon Plasma in a Finite Volume
The statistical mechanics of quarks and gluons are investigated within the
context of the canonical ensemble. Recursive techniques are developed which
enforce the exact conservation of baryon number, total isospin, electric
charge, strangeness, and color. Bose and Fermi-Dirac statistics are also
accounted for to all orders. The energy, entropy and particle number densities
are shown to be significantly reduced for volumes less than 5 cubic fm.Comment: 8 pages, 3 figure
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