Identification and characterization of the dominant thermal resistance in lithium-ion batteries using operando 3-omega sensors

Poor thermal transport within lithium-ion batteries fundamentally limits their performance, safety, and lifetime, in spite of external thermal management systems. All prior efforts to understand the origin of batteries' mysteriously high thermal resistance have been confined to ex situ measurements without understanding the impact of battery operation. Here, we develop a frequency-domain technique that employs sensors capable of measuring spatially resolved intrinsic thermal transport properties within a live battery while it is undergoing cycling. Our results reveal that the poor battery thermal transport is due to high thermal contact resistance between the separator and both electrode layers and worsens as a result of formation cycling, degrading total battery thermal transport by up to 70%. We develop a thermal model of these contact resistances to explain their origin. These contacts account for up to 65% of the total thermal resistance inside the battery, leading to far-reaching consequences for the thermal design of batteries. Our technique unlocks new thermal measurement capabilities for future battery research

Phonon transport at the nanoscale with applications to batteries and advanced thermal insulation

It has been almost three decades since Nanoscale Thermal Science and Engineering became a well-established research field. Various major breakthroughs in fundamental understanding of thermal transport (phonons, photons, and electrons) at the nanoscale have been achieved in these three decades; however, the impact of these fundamental insights has been primarily targeted toward microelectronics and thermoelectrics applications. In this paper we provide examples of other applications such as Lithium ion battery thermal management and building thermal insulation, where nanoscale thermal science has a significant role to play. We have used time domain thermoreflectance (TDTR) to measure thermal conductivity of Lithium ion battery cathode material. To understand the fundamentals of thermal transport in the cathode material we created a model cathode system as compared engineered samples using pulsed laser deposition technique. We also used 3-omega technique for the engineered system. We have also made highly insulating material using functionalized nanoparticles for building applications. Results show that surface functionalization has a huge impact on thermal conductivity of an assembly of nanoparticle

Analysis and Improvement of the Hot Disk Transient Plane Source Method for Low Thermal Conductivity Materials

The hot disk transient plane source (TPS) method is a widely used standard technique (ISO 22007-2) for the characterization of thermal properties of materials, especially the thermal conductivity, k. Despite its well-established reliability for a wide variety of common materials, the hot disk TPS method is also known to suffer from a substantial systematic errors when applied to low-k thermal insulation materials. Here, we present a combined numerical and experimental study on the influence of the geometry of hot disk sensor on measured value of low-k materials. We demonstrate that the error is strongly affected by the finite thickness and thermal mass of the sensor's insulation layer was well as the corresponding increase of the effective heater size beyond the radius of the embedded metal heater itself. We also numerically investigate the dependence of the error on the sample thermal properties, confirming that the errors are worse in low-k samples. A simple correction function is also provided, which converts the apparent (erroneous) result from a standard hot disk TPS measurement to a more accurate value. A standard polyimide sensor was also optimized using both wet and dry etching to provide more accurate measurement directly. Experimentally corrected value of k for Airloy x56 aerogel and a commercial silica aerogel using the numerical correction factor derived based on the standard TPS sensor is in excellent agreement with the directly measured value from the TPS sensor using the optimized polyimide sensor. Both of these methods can reduce the errors to less than 4% as compared to around 40% error of overestimation from raw values measured with the pristine sensor. Such results show that both the numerical correction to a pristine senor or an optimized sensor are capable of providing highly accurate value of thermal conductivity for such materials.Comment: 76 pages, 11 figure

Enhanced Charge Carrier Transport in 2D Perovskites by Incorporating Single-Walled Carbon Nanotubes or Graphene

Two-dimensional (2D) organic-inorganic (hybrid) perovskites are considered promising candidates to replace conventional three-dimensional (3D) perovskites for solar cell applications as they have good resistance against moisture and UV light. However, the use of 2D perovskite is associated with a significant decrease in power efficiency resulting from their low photogenerated charge carrier density and poor charge transport. To improve power efficiency in 2D perovskites, highly crystalline films (near-single-crystal quality) of 2D perovskite need to be synthesized where the alignment of the inorganic perovskite components is controlled to have vertical alignment with respect to the contacts to improve charge transport. In this work, we explored strategies to overcome this limitation by integrating 2D perovskite with single-walled carbon nanotubes or graphene to enable more efficient extraction of charge carriers toward electric contacts. Longer carrier lifetimes were achieved after the incorporation of the carbon nanostructures in the films, and at the cell level, power efficiency increased by 2-fold

Nanofluid-Based Direct Absorption Solar Collector

Solar energy is one of the best sources of renewable energy with minimal environmental impact. Direct absorption solar collectors have been proposed for a variety of applications such as water heating; however the efficiency of these collectors is limited by the absorption properties of the working fluid, which is very poor for typical fluids used in solar collectors. It has been shown that mixing nanoparticles in a liquid (nanofluid) has a dramatic effect on the liquid thermophysical properties such as thermal conductivity. Nanoparticles also offer the potential of improving the radiative properties of liquids, leading to an increase in the efficiency of direct absorption solar collectors. Here we report on the experimental results on solar collectors based on nanofluids made from a variety of nanoparticles (carbon nanotubes, graphite, and silver). We demonstrate efficiency improvements of up to 5% in solar thermal collectors by utilizing nanofluids as the absorption mechanism. In addition the experimental data were compared with a numerical model of a solar collector with direct absorption nanofluids. The experimental and numerical results demonstrate an initial rapid increase in efficiency with volume fraction, followed by a leveling off in efficiency as volume fraction continues to increase

Vapor Generation in a Nanoparticle Liquid Suspension Using a Focused, Continuous Laser

This letter discusses experimentation with optically induced phase change in nanoparticle liquid suspensions-commonly termed nanofluids. Four different types of nanofluids at five concentrations were exposed to a similar to 120 mW, 532 nm laser beam to determine the minimum laser flux needed to create vapor. Laser irradiance was varied between 0-770 W cm(-2). While the experiments were simple, they involved many complex, interrelated physical phenomena, including: subcooled boiling, thermal driven particle/bubble motion, nanoparticle radiative absorption/scattering, and nanoparticle clumping. Such phenomena could enable novel solar collectors in which the working fluid directly absorbs energy and undergoes phase change in a single step. c 2009 American Institute of Physics. [doi: 10.1063/1.3250174

Applicability of Nanofluids in High Flux Solar Collectors

Concentrated solar energy has become the input for an increasing number of experimental and commercial thermal systems over the past 10-15 years [M. Thirugnanasambandam et al., Renewable Sustainable Energy Rev. 14 (2010)]. Recent papers have indicated that the addition of nanoparticles to conventional working fluids (i.e., nanofluids) can improve heat transfer and solar collection [H. Tyagi et al., J. Sol. Energy Eng. 131, 4 (2009); P. E. Phelan et al., Annu. Rev. Heat Transfer 14 (2005)]. This work indicates that power tower solar collectors could benefit from the potential efficiency improvements that arise from using a nanofluid working fluid. A notional design of this type of nanofluid receiver is presented. Using this design, we show a theoretical nanofluid enhancement in efficiency of up to 10% as compared to surface-based collectors when solar concentration ratios are in the range of 100-1000. Furthermore, our analysis shows that graphite nanofluids with volume fractions on the order of 0.001% or less are suitable for 10-100 MW(e) power plants. Experiments on a laboratory-scale nanofluid dish receiver suggest that up to 10% increase in efficiency is possible (relative to a conventional fluid)-if operating conditions are chosen carefully. Lastly, we use these findings to compare the energy and revenue generated in a conventional solar thermal plant to a nanofluid-based one. It is found that a 100 MW(e) capacity solar thermal power tower operating in a solar resource similar to Tucson, AZ, could generate similar to$ 3.5 million more per year by incorporating a nanofluid receiver. (C) 2011 American Institute of Physics. [doi: 10.1063/1.3571565

Simulation of dimensionality effects in thermal transport

The discovery of nanostructures and the development of growth and fabrication techniques of one- and two-dimensional materials provide the possibility to probe experimentally heat transport in low-dimensional systems. Nevertheless measuring the thermal conductivity of these systems is extremely challenging and subject to large uncertainties, thus hindering the chance for a direct comparison between experiments and statistical physics models. Atomistic simulations of realistic nanostructures provide the ideal bridge between abstract models and experiments. After briefly introducing the state of the art of heat transport measurement in nanostructures, and numerical techniques to simulate realistic systems at atomistic level, we review the contribution of lattice dynamics and molecular dynamics simulation to understanding nanoscale thermal transport in systems with reduced dimensionality. We focus on the effect of dimensionality in determining the phononic properties of carbon and semiconducting nanostructures, specifically considering the cases of carbon nanotubes, graphene and of silicon nanowires and ultra-thin membranes, underlying analogies and differences with abstract lattice models.Comment: 30 pages, 21 figures. Review paper, to appear in the Springer Lecture Notes in Physics volume "Thermal transport in low dimensions: from statistical physics to nanoscale heat transfer" (S. Lepri ed.

Modeling of subcontinuum thermal transport across semiconductor-gas interfaces

A physically rigorous computational algorithm is developed and applied to calculate subcontinuum thermal transport in structures containing semiconductor-gas interfaces. The solution is based on a finite volume discretization of the Boltzmann equation for gas molecules (in the gas phase) and phonons (in the semiconductor). A partial equilibrium is assumed between gas molecules and phonons at the interface of the two media, and the degree of this equilibrium is determined by the accommodation coefficients of gas molecules and phonons on either side of the interface. Energy balance is imposed to obtain a value of the interface temperature. The classic problem of temperature drop across a solid-gas interface is investigated with a simultaneous treatment of solid and gas phase properties for the first time. A range of transport regimes is studied, varying from ballistic phonon transport and free molecular flow to continuum heat transfer in both gas and solid. A reduced-order model is developed that captures the thermal resistance of the gas-solid interface. The formulation is then applied to the problem of combined gas-solid heat transfer in a two-dimensional nanoporous bed and the overall thermal resistance of the bed is characterized in terms of the governing parameters. These two examples exemplify the broad utility of the model in practical nanoscale heat transfer applications