2,057 research outputs found
Inelastic incoherent neutron scattering study of the methyl rotation in various methyl halides
Gravitational wave recoil in Robinson-Trautman spacetimes
We consider the gravitational recoil due to non-reflection-symmetric
gravitational wave emission in the context of axisymmetric Robinson-Trautman
spacetimes. We show that regular initial data evolve generically into a final
configuration corresponding to a Schwarzschild black-hole moving with constant
speed. For the case of (reflection-)symmetric initial configurations, the mass
of the remnant black-hole and the total energy radiated away are completely
determined by the initial data, allowing us to obtain analytical expressions
for some recent numerical results that have been appeared in the literature.
Moreover, by using the Galerkin spectral method to analyze the non-linear
regime of the Robinson-Trautman equations, we show that the recoil velocity can
be estimated with good accuracy from some asymmetry measures (namely the first
odd moments) of the initial data. The extension for the non-axisymmetric case
and the implications of our results for realistic situations involving head-on
collision of two black holes are also discussed.Comment: 9 pages, 6 figures, final version to appear in PR
Synthesis of bis-quinoxaline derivatives using Tonsil clay as a catalyst
A convenient and efficient synthesis of new bis-quinoxaline is described, involving condensation of 1,2-diamines with 9-ethyl-3,6-di(1,2-dioxoethyl)carbazole in the presence of Tonsil clay, a readily available and inexpensive catalyst. The structures of all new products were identified by 1H-NMR, 13C-NMR and FT-IR spectral data and microanalysis. KEY WORDS: bis-Quinoxaline, bis-Glyoxal, Green chemistry, 1,2-Diamine, Tonsil clay Bull. Chem. Soc. Ethiop. 2016, 30(1), 129-136.DOI: http://dx.doi.org/10.4314/bcse.v30i1.1
Synthesis of 9H-Indeno [1, 2-b] Pyrazine and 11H-Indeno [1, 2-b] Quinoxaline Derivatives in One-step Reaction from 2-Bromo-4-chloro-1-indanone
The reaction of 2-bromo-4-chloro-1-indanone with 2,3-diaminomaleonitrile, benzene-1,2-diamine and 4-methylbenzene-1,2-diamine in glacial acetic acid gave 8-chloro-9H-indeno[1,2-b]pyrazine-2,3-dicarbonitrile, 1-chloro-11H-indeno[1,2-b]quinoxaline and 1-chloro-7-methyl-11H-indeno[1,2-b]quinoxaline, respectively, in good yield.Keywords: 2-bromo-4-chloro-1-indanone, diaminopyridine, indeno[1,2-b]quinoxaline, indeno[1,2-b]pyrazine, debrominatio
Fecundity of Blue Crab, Callinectes Sapidus, in Chesapeake Bay: Biological, Statistical and Management Considerations
Ovigerous blue crabs were collected from the mouth of Chesapeake Bay during the 1986 and 1987 spawning seasons. Mean carapace width was 14.7 cm; mean fecundity was 3.2×106 eggs. Fecundity was significantly related to carapace width, and did not vary significantly with developmental stage of the eggs. Mean fecundities were 2.6×106 eggs in 1986, and 4.0×106 eggs in 1987. An additive model with year and size effects described the observed fecundities reasonably well, was compact, and was easier to interpret than a multiplicative model. To fit a more general model without year effects, the authors took the mean of 1986 and 1987 results, and modeled fecundity as E=-2.25+0.38W, where E is predicted fecundity (106 eggs), and W is carapace width (cm)
Estimates of Spawning Stock Size of Blue Crab, Callinectes Sapidus, in Chesapeake Bay, 1986-1987
The 1986 spawning stock exhibited a single abundance peak, increasing from 1.0×105 individuals in early July to 9.3×106 in late July, maintaining high levels throughout the summer, and declining in the fall to 7.4×105 individuals. The 1987 spawning stock showed 2 peaks of abundance. The population reached the lesser peak, 1.0×106 individuals, in late July; the greater peak, 1.5×106, in late August. By late September, the population had declined to 6.5×105 individuals. The peak abundance of the 1987 female spawning stock was only 16% as great as the peak abundance in 1986; the 1987 spawning stock size in 1986. Variability of this magnitude calls for continued monitoring and watchful management, to prevent fishing pressure from exceeding the reproductive capacity of the stock
Mode-multiplexing deep-strong light-matter coupling
Dressing quantum states of matter with virtual photons can create exotic
effects ranging from vacuum-field modified transport to polaritonic chemistry,
and may drive strong squeezing or entanglement of light and matter modes. The
established paradigm of cavity quantum electrodynamics focuses on resonant
light-matter interaction to maximize the coupling strength
, defined as the ratio of the vacuum Rabi
frequency and the carrier frequency of light. Yet, the finite oscillator
strength of a single electronic excitation sets a natural limit to
. Here, we demonstrate a new regime of
record-strong light-matter interaction which exploits the cooperative dipole
moments of multiple, highly non-resonant magnetoplasmon modes specifically
tailored by our metasurface. This multi-mode coupling creates an ultrabroadband
spectrum of over 20 polaritons spanning 6 optical octaves, vacuum ground state
populations exceeding 1 virtual excitation quantum for electronic and optical
modes, and record coupling strengths equivalent to
. The extreme interaction drives
strongly subcycle exchange of vacuum energy between multiple bosonic modes akin
to high-order nonlinearities otherwise reserved to strong-field physics, and
entangles previously orthogonal electronic excitations solely via vacuum
fluctuations of the common cavity mode. This offers avenues towards tailoring
phase transitions by coupling otherwise non-interacting modes, merely by
shaping the dielectric environment
A stochastic flow rule for granular materials
There have been many attempts to derive continuum models for dense granular
flow, but a general theory is still lacking. Here, we start with Mohr-Coulomb
plasticity for quasi-2D granular materials to calculate (average) stresses and
slip planes, but we propose a "stochastic flow rule" (SFR) to replace the
principle of coaxiality in classical plasticity. The SFR takes into account two
crucial features of granular materials - discreteness and randomness - via
diffusing "spots" of local fluidization, which act as carriers of plasticity.
We postulate that spots perform random walks biased along slip-lines with a
drift direction determined by the stress imbalance upon a local switch from
static to dynamic friction. In the continuum limit (based on a Fokker-Planck
equation for the spot concentration), this simple model is able to predict a
variety of granular flow profiles in flat-bottom silos, annular Couette cells,
flowing heaps, and plate-dragging experiments -- with essentially no fitting
parameters -- although it is only expected to function where material is at
incipient failure and slip-lines are inadmissible. For special cases of
admissible slip-lines, such as plate dragging under a heavy load or flow down
an inclined plane, we postulate a transition to rate-dependent Bagnold
rheology, where flow occurs by sliding shear planes. With different yield
criteria, the SFR provides a general framework for multiscale modeling of
plasticity in amorphous materials, cycling between continuum limit-state stress
calculations, meso-scale spot random walks, and microscopic particle
relaxation
Methods of olfactory ensheathing cell harvesting from the olfactory mucosa in dogs
Olfactory ensheathing cells are thought to support regeneration and remyelination of damaged axons when transplanted into spinal cord injuries. Following transplantation, improved locomotion has been detected in many laboratory models and in dogs with naturally-occurring spinal cord injury; safety trials in humans have also been completed. For widespread clinical implementation, it will be necessary to derive large numbers of these cells from an accessible and, preferably, autologous, source making olfactory mucosa a good candidate. Here, we compared the yield of olfactory ensheathing cells from the olfactory mucosa using 3 different techniques: rhinotomy, frontal sinus keyhole approach and rhinoscopy. From canine clinical cases with spinal cord injury, 27 biopsies were obtained by rhinotomy, 7 by a keyhole approach and 1 with rhinoscopy. Biopsy via rhinoscopy was also tested in 13 cadavers and 7 living normal dogs. After 21 days of cell culture, the proportions and populations of p75-positive (presumed to be olfactory ensheathing) cells obtained by the keyhole approach and rhinoscopy were similar (~4.5 x 106 p75-positive cells; ~70% of the total cell population), but fewer were obtained by frontal sinus rhinotomy. Cerebrospinal fluid rhinorrhea was observed in one dog and emphysema in 3 dogs following rhinotomy. Blepharitis occurred in one dog after the keyhole approach. All three biopsy methods appear to be safe for harvesting a suitable number of olfactory ensheathing cells from the olfactory mucosa for transplantation within the spinal cord but each technique has specific advantages and drawbacks
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