19,401 research outputs found
Quantum frustration in organic Mott insulators: from spin liquids to unconventional superconductors
We review the interplay of frustration and strong electronic correlations in
quasi-two-dimensional organic charge transfer salts, such as k-(BEDT-TTF)_2X
and Et_nMe_{4-n}Pn[Pd(dmit)2]2. These two forces drive a range of exotic phases
including spin liquids, valence bond crystals, pseudogapped metals, and
unconventional superconductivity. Of particular interest is that in several
materials there is a direct transition as a function of pressure from a spin
liquid Mott insulating state to a superconducting state. Experiments on these
materials raise a number of profound questions about the quantum behaviour of
frustrated systems, particularly the intimate connection between spin liquids
and superconductivity. Insights into these questions have come from a wide
range of theoretical techniques including first principles electronic
structure, quantum many-body theory and quantum field theory. In this review we
introduce the basic ideas of the field by discussing a simple frustrated
Heisenberg model with four spins. We then describe the key experimental
results, emphasizing that for two materials, k-(BEDT-TTF)_2Cu_2(CN)_3 and
EtMe_3Sb[Pd(dmit)_2]_2, there is strong evidence for a spin liquid ground
state, and for EtMe_3P[Pd(dmit)_2]_2, a valence bond solid ground state. We
review theoretical attempts to explain these phenomena, arguing that this can
be captured by a Hubbard model on the anisotropic triangular lattice at half
filling, and that resonating valence bond wavefunctions can capture most of the
essential physics. We review evidence that this model can have a spin liquid
ground state for a range of parameters that are realistic for the relevant
materials. We conclude by summarising the progress made thus far and
identifying some of the key questions still to be answered.Comment: Major rewrite. New material added and many typos corrected. 67 pages,
41 figures. Thanks to those who commented on the previous versio
Symmetry of the superconducting order parameter in frustrated systems determined by the spatial anisotropy of spin correlations
We study the resonating valence bond (RVB) theory of the Hubbard-Heisenberg
model on the half-filled anisotropic triangular lattice. Varying the
frustration changes the wavevector of maximum spin correlation in the Mott
insulating phase. This, in turn, changes the symmetry of the superconducting
state, that occurs at the boundary of the Mott insulating phase. We propose
that this physics is realised in several families of quasi-two-dimensional
organic superconductors.Comment: To appear in Phys. Rev. Lett. - 5 pages, 4 fig
An examination of the types of leading questions used by investigative interviewers of children
Purpose – The purpose of this paper is to examine the nature of leading questions used by a representative sample of investigative interviewers of children. In particular, it examined whether these interviewers use the type of questions that are known to elicit reports of false activities or events among child samples.Design/methodology/approach – A total of 82 police officers who were authorized to conduct interviews with alleged child abuse victims conducted individual mock interviews with children aged 5-7 years. The focus of the interviews was an event that was staged in the children\u27s school a week earlier. Prior to the interview, each officer was provided with accurate and inaccurate information about the event, including details about an activity that did not occur. The officers\u27 task was to elicit as detailed and accurate account of the event as possible using the techniques they would “normally” use in the field.Findings – Although the officers refrained from using coercive interview techniques, two problematic types of questions were relatively common. These include: questions that presumed that an activity/detail occurred that had not been previously mentioned by the child; and questions that included highly specific details about an activity. Both of these techniques had featured in prior laboratory research on children\u27s false event narratives.Research limitations/implications – These results support the need for better training techniques for assisting officers to avoid the use of leading questions.Originality/value – While it is well established that investigative interviewers do sometimes use leading questions when interviewing children, this is the first study to specify the incidence of various types of leading questions.of leading questions.<br /
Interplay of frustration, magnetism, charge ordering, and covalency in a model of Na0.5CoO2
We investigate an effective Hamiltonian for Na0.5CoO2 that includes the
electrostatic potential due to the ordered Na ions and strong electronic
correlations. This model displays a subtle interplay between metallic and
insulating phases and between charge and magnetic order. For realistic
parameters, the model predicts an insulating phase with similarities to a
covalent insulator. We show that this interpretation gives a consistent
explanation of experiments on Na0.5CoO2, including the small degree of charge
ordering, the small charge gap, the large moment, and the optical conductivity.Comment: 5 pages, 4 figures. Text revised making more emphasis on model
properties. Figures compacte
Spin Fluctuations and the Pseudogap in Organic Superconductors
We show that there are strong similarities in the spin lattice relaxation of
non-magnetic organic charge transfer salts, and that these similarities can be
understood in terms of spin fluctuations. Further, we show that, in all of the
kappa-phase organic superconductors for which there is nuclear magnetic
resonance data, the energy scale for the spin fluctuations coincides with the
energy scale for the pseudogap. This suggests that the pseudogap is caused by
short-range spin correlations. In the weakly frustrated metals
k-(BEDT-TTF)_2Cu[N(CN)_2]Br, k-(BEDT-TTF)_2Cu(NCS)_2, and
k-(BEDT-TTF)_2Cu[N(CN)_2]Cl (under pressure) the pseudogap opens at the same
temperature as coherence emerges in the (intralayer) transport. We argue that
this is because the spin correlations are cut off by the loss of intralayer
coherence at high temperatures. We discuss what might happen to these two
energy scales at high pressures, where the electronic correlations are weaker.
In these weakly frustrated materials the data is well described by the chemical
pressure hypothesis (that anion substitution is equivalent to hydrostatic
pressure). However, we find important differences in the metallic state of
k-(BEDT-TTF)_2Cu_2(CN)_3, which is highly frustrated and displays a spin liquid
insulating phase. We also show that the characteristic temperature scale of the
spin fluctuations in (TMTSF)_2ClO_4 is the same as superconducting critical
temperature, which may be evidence that spin fluctuations mediate the
superconductivity in the Bechgaard salts.Comment: 7 pages, 4 figures; to appear in PR
Sensitivity of the photo-physical properties of organometallic complexes to small chemical changes
We investigate an effective model Hamiltonian for organometallic complexes
that are widely used in optoelectronic devices. The two most important
parameters in the model are , the effective exchange interaction between the
and orbitals of the ligands, and , the renormalized
energy gap between the highest occupied orbitals on the metal and on the
ligand. We find that the degree of metal-to-ligand charge transfer (MLCT)
character of the lowest triplet state is strongly dependent on the ratio
. is purely a property of the complex and can be
changed significantly by even small variations in the complex's chemistry, such
as replacing substituents on the ligands. We find that that small changes in
can cause large changes in the properties of the complex,
including the lifetime of the triplet state and the probability of injected
charges (electrons and holes) forming triplet excitations. These results give
some insight into the observed large changes in the photophysical properties of
organometallic complexes caused by small changes in the ligands.Comment: Accepted for publication in J. Chem. Phys. 14 pages, 9 figures,
Supplementary Info: 15 pages, 17 figure
First-principle density-functional calculation of the Raman spectra of BEDT-TTF
We present a first-principles density-functional calculation for the Raman
spectra of a neutral BEDT-TTF molecule. Our results are in excellent agreement
with experimental results. We show that a planar structure is not a stable
state of a neutral BEDT-TTF molecule. We consider three possible conformations
and discuss their relation to disorder in these systems.Comment: 3 pages, 2 figures, submitted to the proceedings of ISCOM 200
Advanced combined iodine dispenser and detector
A total weight of 1.23 kg (2.7 lb), a total volume of 1213 cu m (74 cu in), and an average power consumption of 5.5W was achieved in the advanced combined iodine dispenser/detector by integrating the detector with the iodine source, arranging all iodinator components within a compact package and lowering the parasitic power to the detector and electronics circuits. These achievements surpassed the design goals of 1.36 kg (3.0 lb), 1671 cu m (102 cu in) and 8W. The reliability and maintainability were improved by reducing the detector lamp power, using an interchangeable lamp concept, making the electronic circuit boards easily accessible, providing redundant water seals and improving the accessibility to the iodine accumulator for refilling. The system was designed to iodinate (to 5 ppm iodine) the fuel cell water generated during 27 seven-day orbiter missions (equivalent to 18,500 kg (40,700 lb) of water) before the unit must be recharged with iodine crystals
Comparison of the phase diagram of the half-filled layered organic superconductors with the phase diagram of the RVB theory of the Hubbard-Heisenberg model
We present an resonating valence bond (RVB) theory of superconductivity for
the Hubbard--Heisenberg model on an anisotropic triangular lattice. We show
that these calculations are consistent with the observed phase diagram of the
half-filled layered organic superconductors, such as the beta, beta', kappa and
lambda phases of (BEDT-TTF)_2X [bis(ethylenedithio)tetrathiafulvalene] and
(BETS)_2X [bis(ethylenedithio)tetraselenafulvalene]. We find a first order
transition from a Mott insulator to a d_{x^2-y^2} superconductor with a small
superfluid stiffness and a pseudogap with d_{x^2-y^2} symmetry. The
Mott--Hubbard transition can be driven either by increasing the on-site Coulomb
repulsion, U, or by changing the anisotropy of the two hopping integrals, t'/t.
Our results suggest that the ratio t'/t plays an important role in determining
the phase diagram of the organic superconductors.Comment: 4 pages, 3 figur
Triple redundant hydrogen sensor with in situ calibration
To meet sensing and calibration needs, an in situ calibration technique was developed. It is based on electrolytic generation of a hydrogen/air atmosphere within a hydrogen sensor. The hydrogen is generated from water vapor in the air, and being electrical in nature, the in situ calibration can be performed completely automatically in remote locations. Triply redundant sensor elements are integrated within a single, compact housing, and digital logic provides inter-sensor comparisons to warn of and identify malfunctioning sensor elements. An evaluation of this concept is presented
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