The Atomic and Electronic Structure of Liquid N- Methylformamide as Determined from Diffraction Experiments

The structure of liquid N-methylformamide (NMF) has been investigated using synchrotron radiation at 77 and 95 keV. The use of high energy photons has several advantages, in this case especially the large accessible momentum transfer range, the low absorption and the direct comparability with neutron diffraction. The range of momentum transfer covered is 0.6 \AA$^{-1} <$ Q $<$24.0 \AA$^{-1}$. Neutron diffraction data on the same sample in the same momentum transfer range have been published previously. In that study two differently isotope - substituted species were investigated. In order to compare neutron and photon diffraction data properly Reverse Monte Carlo (RMC-) simulations have been performed. Some modifications had to be added to the standard RMC- code introducing different constraints for inter- and intramolecular distances as these distances partly overlap in liquid NMF. RMC- simulations having only the neutron data as input were carried out in order to test the quality of the X-ray data. The photon structure factor calculated from the RMC- configurations is found to agree well with the present experimental data, while it deviates considerably from earlier X-ray work using low energy photons (17 keV). Finally we discuss whether the different interaction mechanisms of neutrons and photons can be used to directly access the electronic structure in the liquid. Evidence is presented that the elastic self scattering part of liquid NMF is changed with respect to the independent atom approximation. This modification can be accounted for by a simple charged atoms model.Comment: Accepted for publication in Molecular Physics, LaTex file, 12 pages, figures not include

Envisat - taking the measure of North Atlantic storms

Envisat carries a number of sensors able to provide quantitative information on raining clouds: AATSR delivers information on cloud microphysics (particle size, temperature etc.), MWR-2 gives columnar totals for liquid and vapour forms of water, and RA-2 yields rain rate and wind speed. This paper examines the complementarity of these sensors, with a focussed study on significant rain events in the N. Atlantic, covering both coherent large storms and fronts with smaller scale structure. The difference in liquid water estimates from the infra-red and passive systems appears to be related to the temperature and sizes of drops being detected

Longwall shearer tracking system

A tracking system for measuring and recording the movements of a longwall shearer vehicle includes an optical tracking assembly carried at one end of a desired vehicle path and a retroreflector assembly carried by the vehicle. Continuous horizontal and vertical light beams are alternately transmitted by means of a rotating Dove prism to the reflector assembly. A vertically reciprocating reflector interrupts the continuous light beams and converts these to discrete horizontal and vertical light beam images transmitted at spaced intervals along the path. A second rotating Dove prism rotates the vertical images to convert them to a second series of horizontal images while the first mentioned horizontal images are left unrotated and horizontal. The images are recorded on a film

Isolated Photons in Deep Inelastic Scattering

Photon radiation at large transverse momenta at colliders is a detailed probe of hard interaction dynamics. The isolated photon production cross section in deep inelastic scattering was measured recently by the ZEUS experiment, and found to be considerably larger than theoretical predictions obtained with widely used event generators. To investigate this discrepancy, we perform a dedicated parton-level calculation of this observable, including contributions from fragmentation and large-angle radiation. Our results are in good agreement with all aspects of the experimental measurement.Comment: 4 pages, 3 figure

Detecting groundwater discharge dynamics from point-to-catchment scale in a lowland stream : Combining hydraulic and tracer methods

Acknowledgements. We would like to thank members of the Northern Rivers Institute, Aberdeen University, for helpful discussions of data. We also thank Lars Rasmussen, Jolanta Kazmierczak and Charlotte Ditlevsen for help in the field. This study is part of the Hydrology Observatory, HOBE (http://www.hobe.dk), funded by the Villum Foundation and was as well funded by the Aarhus University Research Foundation.Peer reviewedPublisher PD