496 research outputs found
Brownian yet non-Gaussian diffusion in heterogeneous media: from superstatistics to homogenization
We discuss the situations under which Brownian yet non-Gaussian (BnG)
diffusion can be observed in the model of a particle's motion in a random
landscape of diffusion coefficients slowly varying in space. Our conclusion is
that such behavior is extremely unlikely in the situations when the particles,
introduced into the system at random at , are observed from the
preparation of the system on. However, it indeed may arise in the case when the
diffusion (as described in Ito interpretation) is observed under equilibrated
conditions. This paradigmatic situation can be translated into the model of the
diffusion coefficient fluctuating in time along a trajectory, i.e. into a kind
of the "diffusing diffusivity" model.Comment: 12 pages; 10 figure
Electronic structure study by means of X-ray spectroscopy and theoretical calculations of the "ferric star" single molecule magnet
The electronic structure of the single molecule magnet system
M[Fe(L)2]3*4CHCl3 (M=Fe,Cr; L=CH3N(CH2CH2O)2) has been studied using X-ray
photoelectron spectroscopy, X-ray absorption spectroscopy, soft X-ray emission
spectroscopy, and density functional calculations. There is good agreement
between theoretical calculations and experimental data. The valence band mainly
consists of three bands between 2 eV and 30 eV. Both theory and experiments
show that the top of the valence band is dominated by the hybridization between
Fe 3d and O 2p bands. From the shape of the Fe 2p spectra it is argued that Fe
in the molecule is most likely in the 2+ charge state. Its neighboring atoms
(O,N) exhibit a magnetic polarisation yielding effective spin S=5/2 per iron
atom, giving a high spin state molecule with a total S=5 effective spin for the
case of M = Fe.Comment: Fig.2 replaced as it will appear in J. Chem. Phy
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