Radical Fluoroalkylation Reactions

Recent protocols and reactions for catalytic radical perfluoroalkylations will be described. The production of perfluoroalkyl radicals (RF = CnF2n+1, n ≥ 2), which effect both addition and substitution reactions on organic substrates, can be realized through a range of diverse methods such as the well-established visible-light transition-metal-mediated photocatalysis, organic-dye-photocatalyzed reactions, electron donor-acceptor complexes, and more recently frustrated Lewis pairs. Thus, perfluoroalkylation reactions of carbon-carbon multiple bonds, isocyanides, nitrones, hydrazones, β-keto esters, α-cyano arylacetates, sulfides, and (hetero)arenes will be described. Special emphasis will be placed on examples published after 2015, where higher fluorinated series of fluoroalkylating reagents are studied.Fil: Barata Vallejo, Sebastian. Universidad de Buenos Aires. Facultad de Farmacia y Bioquímica. Departamento de Química Orgánica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Cooke, María Victoria. Universidad de Buenos Aires. Facultad de Farmacia y Bioquímica. Departamento de Química Orgánica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Postigo, A.. Universidad de Buenos Aires. Facultad de Farmacia y Bioquímica. Departamento de Química Orgánica; Argentin

The GRB 030328 host: another case of a blue starburst galaxy

We present for the first time the detection of the GRB 030328 host galaxy in four optical bands equivalent to UBRI. The host galaxy spectral energy distribution is consistent with a low extinction (E(B-V) < 0.21) starburst galaxy. The restframe B-band magnitude of the host is M_B ~ -20.4Comment: 4 pages, 2 figures, accepted for publication in Il nuovo cimento (4th Workshop Gamma-Ray Bursts in the Afterglow Era, Rome, 18-22 October 2004

A young stellar environment for the superluminous supernova PTF12dam

The progenitors of super luminous supernovae (SLSNe) are still a mystery. Hydrogen-poor SLSN hosts are often highly star-forming dwarf galaxies and the majority belongs to the class of extreme emission line galaxies hosting young and highly star-forming stellar populations. Here we present a resolved long-slit study of the host of the hydrogen-poor SLSN PTF12dam probing the kpc environment of the SN site to determine the age of the progenitor. The galaxy is a "tadpole" with uniform properties and the SN occurred in a star-forming region in the head of the tadpole. The galaxy experienced a recent star-burst superimposed on an underlying old stellar population. We measure a very young stellar population at the SN site with an age of ~3 Myr and a metallicity of 12+log(O/H)=8.0 at the SN site but do not observe any WR features. The progenitor of PTF12dam must have been a massive star of at least 60 M_solar and one of the first stars exploding as a SN in this extremely young starburst.Comment: submitted to MNRAS letters. 5 pages, 3 figures, supplementary material: 2 figures, 2 table

Reliable channel-adapted error correction: Bacon-Shor code recovery from amplitude damping

We construct two simple error correction schemes adapted to amplitude damping noise for Bacon-Shor codes and investigate their prospects for fault-tolerant implementation. Both consist solely of Clifford gates and require far fewer qubits, relative to the standard method, to achieve correction to a desired order in the damping rate. The first, employing on

A spectroscopic look at the gravitationally lensed type Ia SN 2016geu at z=0.409

The spectacular success of type Ia supernovae (SNe Ia) in SN-cosmology is based on the assumption that their photometric and spectroscopic properties are invariant with redshift. However, this fundamental assumption needs to be tested with observations of high-z SNe Ia. To date, the majority of SNe Ia observed at moderate to large redshifts (0.4 < z < 1.0) are faint, and the resultant analyses are based on observations with modest signal-to-noise ratios that impart a degree of ambiguity in their determined properties. In rare cases however, the Universe offers a helping hand: to date a few SNe Ia have been observed that have had their luminosities magnified by intervening galaxies and galaxy clusters acting as gravitational lenses. In this paper we present long-slit spectroscopy of the lensed SNe Ia 2016geu, which occurred at a redshift of z=0.409, and was magnified by a factor of ~55 by a galaxy located at z=0.216. We compared our spectra, which were obtained a couple weeks to a couple months past peak light, with the spectroscopic properties of well-observed, nearby SNe Ia, finding that SN 2016geu's properties are commensurate with those of SNe Ia in the local universe. Based primarily on the velocity and strength of the Si II 6355 absorption feature, we find that SN 2016geu can be classified as a high-velocity, high-velocity gradient and "core-normal" SN Ia. The strength of various features (measured though their pseudo-equivalent widths) argue against SN 2016geu being a faint, broad-lined, cool or shallow-silicon SN Ia. We conclude that the spectroscopic properties of SN 2016geu imply that it is a normal SN Ia, and when taking previous results by other authors into consideration, there is very little, if any, evolution in the observational properties of SNe Ia up to z~0.4. [Abridged]Comment: 12 pages, 5 figures, 4 tables. Submitted to MNRAS. Comments welcome

Reliable channel-adapted error correction: Bacon-Shor code recovery from amplitude damping

We construct two simple error correction schemes adapted to amplitude damping noise for Bacon-Shor codes and investigate their prospects for fault-tolerant implementation. Both consist solely of Clifford gates and require far fewer qubits, relative to the standard method, to achieve exact correction to a desired order in the damping rate. The first, employing one-bit teleportation and single-qubit measurements, needs only one-fourth as many physical qubits, while the second, using just stabilizer measurements and Pauli corrections, needs only half. The improvements stem from the fact that damping events need only be detected, not corrected, and that effective phase errors arising due to undamped qubits occur at a lower rate than damping errors. For error correction that is itself subject to damping noise, we show that existing fault-tolerance methods can be employed for the latter scheme, while the former can be made to avoid potential catastrophic errors and can easily cope with damping faults in ancilla qubits

Confined photon modes with triangular symmetry in hexagonal microcavities in 2D photonic Crystals

We present theoretical and experimental studies of the size and thickness dependencies of the optical emission spectra from microcavities with hexagonal shape in films of two-dimensional photonic crystal. A semiclassical plane-wave model, which takes into account the electrodynamic properties of quasi-2D planar photonic microcavity, is developed to predict the eigenfrequencies of the confined photon modes as a function of both the hexagon-cavity size and the film thickness. Modes with two different symmetries, triangular and hexagonal, are critically analyzed. It is shown that the model of confined photon modes with triangular symmetry gives a better agreement between the predicted eigenmodes and the observed resonances.Comment: 14 pages, 6 figure

Active Transcriptional Repression by the Rb–E2F Complex Mediates G1 Arrest Triggered by p16INK4a, TGFβ, and Contact Inhibition

AbstractRb inhibits progression from G1 to S phase of the cell cycle. It associates with a number of cellular proteins; however, the nature of these interactions and their relative significance in cell cycle regulation are still unclear. We present evidence that Rb must normally interact with the E2F family of transcription factors to arrest cells in G1, and that this arrest results from active transcriptional repression by the Rb–E2F complex, not from inactivation of E2F. Thus, a major role of E2F in cell cycle regulation is assembly of this repressor complex. We demonstrate that active repression by Rb–E2F mediates the G1 arrest triggered by TGFβ, p16INK4a, and contact inhibition

Multi-wavelength analysis of the field of the dark burst GRB 031220

We have collected and analyzed data taken in different spectral bands (from X-ray to optical and infrared) of the field of GRB031220 and we present results of such multiband observations. Comparison between images taken at different epochs in the same filters did not reveal any strong variable source in the field of this burst. X-ray analysis shows that only two of the seven Chandra sources have a significant flux decrease and seem to be the most likely afterglow candidates. Both sources do not show the typical values of the R-K colour but they appear to be redder. However, only one source has an X-ray decay index (1.3 +/- 0.1) that is typical for observed afterglows. We assume that this source is the best afterglow candidate and we estimate a redshift of 1.90 +/- 0.30. Photometric analysis and redshift estimation for this object suggest that this GRB can be classified as a Dark Burst and that the obscuration is the result of dust extinction in the circum burst medium or inside the host galaxy.Comment: 7 pages, 5 figures, accepted for publication on A&