Practical applications of interactive voice technologies: Some accomplishments and prospects

A technology assessment of the application of computers and electronics to complex systems is presented. Three existing systems which utilize voice technology (speech recognition and speech generation) are described. Future directions in voice technology are also described

Modeling Broadband Ocean Acoustic Transmissions with Time-Varying Sea Surfaces

Solutions to ocean acoustic scattering problems are often formulated in the frequency domain, which implies that the surface is frozen in time. This may be reasonable for short duration signals but breaks down if the surface changes appreciably over the transmission time. Frequency domain solutions are also impractical for source-receiver ranges and frequency bands typical for applications such as acoustic communications (e.g. hundreds to thousands of meters, 1-50 kHz band). In addition, a driving factor in the performance of certain acoustic systems is the Doppler spread, which is often introduced from sea-surface movement. The time-varying nature of the sea surface adds complexity and often leads to a statistical description for the variations in received signals. A purely statistical description likely limits the insight that modeling generally provides. In this paper, time-domain modeling approaches to the sea-surface scattering problem are described. As a benchmark for comparison, the Helmholtz integral equation is used for solutions to static, time-harmonic rough surface problems. The integral equation approach is not practical for time-evolving rough surfaces and two alternatives are formulated. The first approach is relatively simple using ray theory. This is followed with a ray-based formulation of the Helmholtz integral equation with a time-domain Kirchhoff approximation

Cooperative Carbon Dioxide Adsorption in Alcoholamine- and Alkoxyalkylamine-Functionalized Metal-Organic Frameworks.

A series of structurally diverse alcoholamine- and alkoxyalkylamine-functionalized variants of the metal-organic framework Mg2 (dobpdc) are shown to adsorb CO2 selectively via cooperative chain-forming mechanisms. Solid-state NMR spectra and optimized structures obtained from van der Waals-corrected density functional theory calculations indicate that the adsorption profiles can be attributed to the formation of carbamic acid or ammonium carbamate chains that are stabilized by hydrogen bonding interactions within the framework pores. These findings significantly expand the scope of chemical functionalities that can be utilized to design cooperative CO2 adsorbents, providing further means of optimizing these powerful materials for energy-efficient CO2 separations