5,936 research outputs found
Role of Metastable States in Phase Ordering Dynamics
We show that the rate of separation of two phases of different densities
(e.g. gas and solid) can be radically altered by the presence of a metastable
intermediate phase (e.g. liquid). Within a Cahn-Hilliard theory we study the
growth in one dimension of a solid droplet from a supersaturated gas. A moving
interface between solid and gas phases (say) can, for sufficient (transient)
supersaturation, unbind into two interfaces separated by a slab of metastable
liquid phase. We investigate the criteria for unbinding, and show that it may
strongly impede the growth of the solid phase.Comment: 4 pages, Latex, Revtex, epsf. Updated two reference
Does gravity cause load-bearing bridges in colloidal and granular systems?
We study structures which can bear loads, "bridges", in particulate packings. To investigate the relationship between bridges and gravity, we experimentally determine bridge statistics in colloidal packings. We vary the effective magnitude and direction of gravity, volume fraction, and interactions, and find that the bridge size distributions depend only on the mean number of neighbors. We identify a universal distribution, in agreement with simulation results for granulars, suggesting that applied loads merely exploit preexisting bridges, which are inherent in dense packings
Polydispersity Effects in Colloid-Polymer Mixtures
We study phase separation and transient gelation in a mixture consisting of
polydisperse colloids and non-adsorbing polymers, where the ratio of the
average size of the polymer to that of the colloid is approximately 0.063.
Unlike what has been reported previously for mixtures with somewhat lower
colloid polydispersity, the addition of polymers does not expand the
fluid-solid coexistence region. Instead, we find a region of fluid-solid
coexistence which has an approximately constant width but an unexpected
re-entrant shape. We detect the presence of a metastable gas-liquid binodal,
which gives rise to two-stepped crystallization kinetics that can be
rationalized as the effect of fractionation. Finally, we find that the
separation into multiple coexisting solid phases at high colloid volume
fractions predicted by equilibrium statistical mechanics is kinetically
suppressed before the system reaches dynamical arrest.Comment: 11 pages, 5 figure
Diffusive Evolution of Stable and Metastable Phases II: Theory of Non-Equilibrium Behaviour in Colloid-Polymer Mixtures
By analytically solving some simple models of phase-ordering kinetics, we
suggest a mechanism for the onset of non-equilibrium behaviour in
colloid-polymer mixtures. These mixtures can function as models of atomic
systems; their physics therefore impinges on many areas of thermodynamics and
phase-ordering. An exact solution is found for the motion of a single, planar
interface separating a growing phase of uniform high density from a
supersaturated low density phase, whose diffusive depletion drives the
interfacial motion. In addition, an approximate solution is found for the
one-dimensional evolution of two interfaces, separated by a slab of a
metastable phase at intermediate density. The theory predicts a critical
supersaturation of the low-density phase, above which the two interfaces become
unbound and the metastable phase grows ad infinitum. The growth of the stable
phase is suppressed in this regime.Comment: 27 pages, Latex, eps
Criticality and phase separation in a two-dimensional binary colloidal fluid induced by the solvent critical behavior
We present an experimental and theoretical study of the phase behavior of a
binary mixture of colloids with opposite adsorption preferences in a critical
solvent. As a result of the attractive and repulsive critical Casimir forces,
the critical fluctuations of the solvent lead to a further critical point in
the colloidal system, i.e. to a critical colloidal-liquid--colloidal-liquid
demixing phase transition which is controlled by the solvent temperature. Our
experimental findings are in good agreement with calculations based on a simple
approximation for the free energy of the system.Comment: 5 pages, 5 figures, to be published in Europhysics Letter
Degenerations of LeBrun twistor spaces
We investigate various limits of the twistor spaces associated to the
self-dual metrics on n CP ^2, the connected sum of the complex projective
planes, constructed by C. LeBrun. In particular, we explicitly present the
following 3 kinds of degenerations whose limits of the metrics are: (a) LeBrun
metrics on (n-1) CP ^2$, (b) (Another) LeBrun metrics on the total space of the
line bundle O(-n) over CP ^1 (c) The hyper-Kaehler metrics on the small
resolution of rational double points of type A_{n-1}, constructed by Gibbons
and Hawking.Comment: 21 pages, 7 figures. V2: A new section added at the end of the
article. V3: Reference slightly update
Functional specialization of the yeast Rho1 GTP exchange factors
Rho GTPases are regulated in complex spatiotemporal patterns that may be dependent, in part at least, on the multiplicity of their GTP exchange factors (GEFs). Here, we examine the extent of and basis for functional specialization of the Rom2 and Tus1 GEFs that activate the yeast Rho1 GTPase, the ortholog of mammalian RhoA. First, we find that these GEFs selectively activate different Rho1-effector branches. Second, the synthetic genetic networks around ROM2 and TUS1 confirm very different global in vivo roles for these GEFs. Third, the GEFs are not functionally interchangeable: Tus1 cannot replace the essential role of Rom2, even when overexpressed. Fourth, we find that Rom2 and Tus1 localize differently: Rom2 to the growing bud surface and to the bud neck at cytokinesis; Tus1 only to the bud neck but in a distinct pattern. Finally, we find that these GEFs are dependent on different protein co-factors: Rom2 function and localization is largely dependent on Ack1, a SEL1 domain containing protein; Tus1 function and localization is largely dependent on the Tus1-interacting protein Ypl066w (which we name Rgl1). We have revealed a surprising level of diversity among the Rho1 GEFs that contributes another level of complexity to the spatiotemporal control of Rho1
Cellular solid behaviour of liquid crystal colloids. 1. Phase separation and morphology
We study the phase ordering colloids suspended in a thermotropic nematic
liquid crystal below the clearing point Tni and the resulting aggregated
structure. Small (150nm) PMMA particles are dispersed in a classical liquid
crystal matrix, 5CB or MBBA. With the help of confocal microscopy we show that
small colloid particles densely aggregate on thin interfaces surrounding large
volumes of clean nematic liquid, thus forming an open cellular structure, with
the characteristic size of 10-100 micron inversely proportional to the colloid
concentration. A simple theoretical model, based on the Landau mean-field
treatment, is developed to describe the continuous phase separation and the
mechanism of cellular structure formation.Comment: Latex 2e (EPJ style) EPS figures included (poor quality to comply
with space limitations
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