Multi-cyclic and isotopically diverse silicic magma generation in an arc volcano : Gorely Eruptive Center, Kamchatka, Russia

The Kamchatka Peninsula is home to some of the most frequent and prolific subduction-related volcanic activity in the world, with the largest number of caldera-forming eruptions per length of the volcanic arc. Among those, Gorely volcano has a topographically prominent Late Pleistocene caldera (13 km × 12 km, estimated to have produced >100 km3 of magma), which is now almost completely filled by a central cone. We report new 40Ar/39Ar ages and geochemical and isotopic data for newly recognized Mid-Pleistocene ignimbrite units of large but unknown volume sourced from the Gorely eruptive center, most of which were deposited in marginal glacial conditions. These ignimbrites have crystallinities of 9–24% and most are quartz-, amphibole-, and zircon-undersaturated. Additionally, we studied 32 eruptive units, including stratigraphically constrained Holocene tephra, and pre- and post-caldera lava sequences, to understand the petrogenetic and temporal evolution of this long-lived, multi-cyclic, arc volcano. Material erupted prior to the formation of the modern Gorely edifice, including the voluminous ignimbrites and eruptions of the ‘pra-Gorely’ stage, consist primarily of dacite and andesite, whereas sequences of the modern Gorely edifice are represented by basalt to basaltic andesite. MELTS and EC-AFC modeling shows that it is possible to obtain silicic compositions near those of the evolved ignimbrite compositions through 60–75% fractional crystallization at 1 kbar and nickel–nickel oxide (NNO) oxygen fugacity. However, our newly compiled major and trace element data for Gorely yield two separate bimodal peaks in a SiO2–frequency diagram, showing a prominent Daly Gap, with a deficiency in andesite. Trace element concentrations define two separate trends, one for more silicic and another for more mafic sequences. Additionally, δ18Omelt values reconstructed from coexisting plagioclase and clinopyroxene phenocrysts range from a low value of 4·85‰ to a normal value of 6·22‰. The low δ18O values range throughout the known lifespan of Gorely, with the lowest value being from the first known ignimbrite to erupt, indicating episodic but temporally decreasing crustal assimilation of previously hydrothermally altered material. 87Sr/86Sr and 143Nd/144Nd ratios show wide ranges from 0·70328 to 0·70351 and from 0·51303 to 0·51309 respectively, also suggesting incorporation of surrounding crust, although there are less clear trends throughout the lifespan of Gorely. The combination of light and diverse δ18O values with elevated 87Sr/86Sr and low 143Nd/144Nd ratios suggests contamination by older and isotopically diverse, low-δ18O country-rocks, such as the neighboring 11 Ma Akhomten granitic massif, which shows ranges in δ18O, 87Sr/86Sr, and 144Nd/143Nd values overlapping with the Gorely magmas. In addition, the presence of glomerocrysts and mafic enclaves in the majority of Gorely dacites indicates a period of crystal settling and subsequent intrusion of hot, primitive basalt that probably triggered eruption. Finally, elevated Nb concentrations relative to other Kamchatkan volcanoes suggest that Gorely magmas may involve an enriched component, probably caused by delamination of a lower crustal root. Our results argue for an incremental view of silicic magma generation at so-called ‘long-term eruptive centers’, in Kamchatka and worldwide, consisting of alternating episodes of magmatic and hydrothermal activity, and glacial advances and retreats. We demonstrate that large-volume, isotopically distinct, silicic magma can be generated rapidly between cone-building phases of volcanic activity through a combination of fractional crystallization, assimilation of older country rocks, and shallow assimilation of hydrothermally altered but otherwise petrochemically similar older intracaldera tuffs and intrusions. These transient shallow silicic magma chambers empty nearly completely in ignimbrite-forming eruptions after 103–105 years of assembly, partially triggered by glacial surface dynamics

TephraKam: geochemical database of glass compositions in tephra and welded tuffs from the Kamchatka volcanic arc (northwestern Pacific)

Tephra layers produced by volcanic eruptions are widely used for correlation and dating of various deposits and landforms, for synchronization of disparate paleoenvironmental archives, and for reconstruction of magma origin. Here we present our original database TephraKam, which includes chemical compositions of volcanic glass in tephra and welded tuffs from the Kamchatka volcanic arc. The database contains 7049 major element analyses obtained by electron microprobe and 738 trace element analyses obtained by laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) on 487 samples collected in proximity of their volcanic sources in all volcanic zones in Kamchatka. The samples characterize about 300 explosive eruptions, which occurred in Kamchatka from the Pliocene until historic times. Precise or estimated ages for all samples are based on published 39Ar/40Ar dates of rocks and 14C dates of host sediments, statistical age modelling and geologic relationships with dated units. All data in TephraKam is supported by information about source volcanoes and analytical details. Using the data, we present an overview of geochemical variations of Kamchatka volcanic glasses and discuss application of this data for precise identification of tephra layers, their source volcanoes, temporal and spatial geochemical variations of pyroclastic rocks in Kamchatka

Sector collapses and large landslides on Late Pleistocene–Holocene volcanoes in Kamchatka, Russia

On Kamchatka, detailed geologic and geomorphologic mapping of young volcanic terrains and observations on historical eruptions reveal that landslides of various scales, from small (0.001 km3) to catastrophic (up to 20–30 km3), are widespread. Moreover, these processes are among the most effective and most rapid geomorphic agents. Of 30 recently active Kamchatka volcanoes, at least 18 have experienced sector collapses, some of them repetitively. The largest sector collapses identified so far on Kamchatka volcanoes, with volumes of 20–30 km3 of resulting debris-avalanche deposits, occurred at Shiveluch and Avachinsky volcanoes in the Late Pleistocene. During the last 10,000 yr the most voluminous sector collapses have occurred on extinct Kamen' (4–6 km3) and active Kambalny (5–10 km3) volcanoes. The largest number of repetitive debris avalanches (> 10 during just the Holocene) has occurred at Shiveluch volcano. Landslides from the volcanoes cut by ring-faults of the large collapse calderas were ubiquitous. Large failures have happened on both mafic and silicic volcanoes, mostly related to volcanic activity. Orientation of collapse craters is controlled by local tectonic stress fields rather than regional fault systems. Specific features of some debris avalanche deposits are toreva blocks — huge almost intact fragments of volcanic edifices involved in the failure; some have been erroneously mapped as individual volcanoes. One of the largest toreva blocks is Mt. Monastyr' — a ∼ 2 km3 piece of Avachinsky Somma involved in a major sector collapse 30–40 ka BP. Long-term forecast of sector collapses on Kliuchevskoi, Koriaksky, Young Cone of Avachinsky and some other volcanoes highlights the importance of closer studies of their structure and stability

Kizimen volcano, Kamchatka — A future Mount St. Helens?

We studied the tectonic setting, morphology, geologic structure, history of eruptive activity and evolution of the composition of the erupted material of Kizimen volcano, Kamchatka, from the moment of its origination 11–12 thousand years ago to the present time. Four cycles, each 2–3.5 thousand years long, were distinguished that characterize the activity of the volcano. All of the largest eruptions were dated, and their parameters determined. We also estimated the volume and the mass of the erupted products, the volcanic intensity of eruption of material during periods of high activity, and the amount of material the volcano ejected at different stages of its formation. It has been shown that the evolution of the composition of the rocks erupted (from dacite to basaltic andesite) takes place as a result of mixing of dacitic and basaltic magma. It is suggested that future eruptions that may take place at Kizimen may be similar to those at Bandai (1888) and Mount St. Helens (1980) volcanoes

Distal tephrochronology in volcanic regions: Challenges and insights from Kamchatkan lake sediments

Kamchatka is one of the world's most active volcanic regions and has hosted many explosive eruptions during the Holocene. These eruptions had the potential to disperse tephra over wide areas, forming time-synchronous markers wherever those tephras are found. Recent research in Kamchatka has begun to focus on the geochemical analysis of individual glass shards in order to characterise tephra layers. We have applied this approach to the study of visible tephras from three lakes - one in central and two in northern Kamchatka - with the aim of identifying key tephras and potential issues in the application of distal (>100 km from an active volcano) tephra in volcanically complex regions. In total, 23 tephras from 22 tephra beds have been geochemically analysed, representing products from at least four volcanic systems in Kamchatka. We demonstrate that distal lake sediments in the region can yield reliable tephrostratigraphies, capturing tephra from eruptions that have the greatest potential to disperse volcanic ash beyond the region. We draw attention to issues relating to correlating and distinguishing key marker horizons from the highly active Shiveluch Volcano, namely the need to ensure inter-lab comparability of geochemical data and good chronological control of the proximal and distal tephras. Importantly, we have also extended the known distribution of two key tephra isochrons from the Ksudach volcano. Our work contributes valuable glass geochemical on data several key marker beds that will facilitate future tephra and palaeoenvironmental research within and beyond Kamchatka. (C) 2015 Elsevier B.V. All rights reserved

Geochemical characterization of marker tephra layers from major Holocene eruptions, Kamchatka Peninsula, Russia

Kamchatka Peninsula is one of the most active volcanic regions in the world. Many Holocene explosive eruptions have resulted in widespread dispersal of tephra-fall deposits. The largest layers have been mapped and dated by the 14C method. The tephra provide valuable stratigraphic markers that constrain the age of many geological events (e.g. volcanic eruptions, palaeotsunamis, faulting, and so on). This is the first systematic attempt to use electron microprobe (EMP) analyses of glass to characterize individual tephra deposits in Kamchatka. Eighty-nine glass samples erupted from 11 volcanoes, representing 27 well-identified Holocene key-marker tephra layers, were analysed. The glass is rhyolitic in 21 tephra, dacitic in two, and multimodal in three. Two tephra are mixed with glass compositions ranging from andesite/dacite to rhyolite. Tephra from the 11 eruptive centres are distinguished by their glass K2O, CaO, and FeO contents. In some cases, individual tephra from volcanoes with multiple eruptions cannot be differentiated. Trace element compositions of 64 representative bulk tephra samples erupted from 10 volcanoes were analysed by instrumental neutron activation analysis (INAA) as a pilot study to further refine the geochemical haracteristics; tephra from these volcanoes can be characterized using Cr and Th contents and La/Yb ratios. Unidentified tephra collected at the islands of Karaginsky (3), Bering (11), and Attu (5) as well as Uka Bay (1) were correlated to known eruptions. Glass compositions and trace element data from bulk tephra samples show that the Karaginsky Island and Uka Bay tephra were all erupted from the Shiveluch volcano. The 11 Bering Island tephra are correlated to Kamchatka eruptions. Five tephra from Attu Island in the Aleutians are tentatively correlated with eruptions from the Avachinsky and Shiveluch volcanoes

Radiocarbon Dating of Large Holocene Volcanic Events Within South Kamchatka (Russian Far East)

From the 19th International Radiocarbon Conference held in Keble College, Oxford, England, April 3-7, 2006.Radiocarbon dating is widely used when studying recent volcanic activity in the Kamchatka Peninsula due to the abundance of organic matter that is associated with the volcanic deposits. Here, we present the results of 14C dating of major volcanic events within the active South Kamchatka volcanic zone. South Kamchatka includes 8 recently active volcanic centers (stratovolcanoes, calderas, and large craters) that have been erupting during the Holocene. Their tephras represent useful markers for both the southern part of the peninsula and the Northern Kurile Islands. Since these marker tephra layers facilitate stratigraphic and tephrochronological studies in this area, it was important to determine their ages. We have obtained 73 new individual 14C dates on paleosol, peat, charcoal, and wood associated with the marker tephra layers, then complemented these data with 37 earlier published dates and analyzed the resulting data set. We selected the reliable dates and then obtained average 14C ages of marker tephra layers. The details of these procedures, as well as brief descriptions of South Kamchatka Holocene eruptions and their tephra beds, are presented in the paper.The Radiocarbon archives are made available by Radiocarbon and the University of Arizona Libraries. Contact [email protected] for further information.Migrated from OJS platform February 202

Active tectonics and geomorphology of the Kamchatsky Bay coast in Kamchatka

Kamchatsky Bay is the northernmost bay at the Pacific Kamchatka coast. It is located at the junction between the Kamchatka segment of the Pacific subduction zone and the dextral transform fault of the western Aleutians. The combination of the subduction and collision processes in this region results in the unique set of tectonic controls influencing its geological and geomorphological evolution. The Kamchatka River estuarine area is located on the northern coast of Kamchatsky Bay. The modern Kamchatka River valley, its estuary, and an aggradation marine terrace some 30 km long and up to 5 km wide were formed in this area during the Holocene. A vast area in the rear part of the terrace and in the Stolbovskaya lowlands is now occupied by the peats deposited directly above lacustrine-lagoonal and fluvial facies. These aggradational landforms record traces of tsunamis and vertical coseismic deformations associated with great subduction earthquakes, as well as strike-slip and thrust faulting associated with the collision. The results indicate that the average recurrence interval for major tsunamis in the Kamchatsky Bay is 300 years. The recurrence interval on individual fault zones associated with the collision between the western Aleutian and Kamchatka arcs is a few thousand years for earthquakes of magnitude between 7 and 7.5. For the entire region, the recurrence interval for major crustal earthquakes associated with motions along faults may be equal to a few hundred years, which is comparable with that for subduction-zone earthquakes